Influence of high energy γ-irradiation on some binuclear transition metal complexes of pentadentate ligand: Spectral, thermal, modelling, X-ray diffraction, morphological and solid electrical conductivity.

New binuclear Co(II) (1), Ni(II) (2) and Cu(II) (3) complexes of N,N'-(2,2'-azanediylbis(ethane-2,1-diyl))bis(2-aminobenzamide) have been synthesized and fully characterized by various chemical and spectral techniques. The synthesized complexes were irradiated by Co gamma rays to dose value of 100 kGy (hereafter referred to as 1a,2a,3a). Molar conductance, spectral, thermal, magnetic moment measurements, powder X-ray diffraction and solid electrical conductivity measurements were investigated before and after exposure to irradiation.

Influences of γ-ray irradiation on physico-chemical, structural, X-ray diffraction, thermal and antimicrobial activity of some γ-irradiated N',N'''-((Z)-ethane-1,2-diylidine)bis(2-aminobenzohydrazide) metal complexes.

A series of Co(II), Ni(II), Cu(II), Th(IV) and UO(II) complexes have been synthesized from reaction of nitrogen based ligand (L) i.e. N',N'''-((Z)-ethane-1,2-diylidine)bis(2-aminobenzohydrazide)(L) with their salts.

Controlled morphology and dimensionality evolution of NiPd bimetallic nanostructures.

Controlling the morphology of noble metal-based nanostructures is a powerful strategy for optimizing their catalytic performance. Here, we report a one-pot aqueous synthesis of versatile NiPd nanostructures at room temperature without employing organic solvents or surfactants. The synthesis can be tuned to form zero-dimensional (0D) architectures, such as core-shell and hollow nanoparticles (NPs), as well as nanostructures with higher dimensionality, such as extended nanowire networks and three-dimensional (3D) nanodendrites.

New 15-membered tetraaza (N4) macrocyclic ligand and its transition metal complexes: spectral, magnetic, thermal and anticancer activity.

Novel tetraamidemacrocyclic 15-membered ligand [L] i.e. naphthyl-dibenzo[1,5,9,12]tetraazacyclopentadecine-6,10,11,15-tetraoneand its transition metal complexes with Fe(II), Co(II), Ni(II), Cu(II), Ru(III) and Pd(II) have been synthesized and characterized by elemental analysis, spectral, thermal as well as magnetic and molar conductivity measurements.

Transition metal complexes of a new 15-membered [N5] penta-azamacrocyclic ligand with their spectral and anticancer studies.

Novel penta-azamacrocyclic 15-membered [N5] ligand [L] i.e. 1,5,8,12-tetetraaza-3,4: 9,10-dibenzo-6-ethyl-7-methyl-1,12-(2,6-pyrido)cyclopentadecan-5,7 diene-2,11-dione and its transition metal complexes with Co(II), Ni(II), Cu(II), Ru(III) and Pd(II) have been synthesized and structurally characterized by elemental analysis, spectral, thermal as well as magnetic and molar conductivity measurements.

Coordination behavior of tetraaza [N₄] ligand towards Co(II), Ni(II), Cu(II), Cu(I) and Pd(II) complexes: synthesis, spectroscopic characterization and anticancer activity.

Novel eight Co(II), Ni(II), Cu(II), Cu(I) and Pd(II) complexes with [N(4)] ligand (L) i.e. 2-amino-N-{2-[(2-aminobenzoyl)amino]ethyl}benzamide have been synthesized and structurally characterized by elemental analysis, spectral, thermal (TG/DTG), magnetic, and molar conductivity measurements.

Structural studies and anticancer activity of a novel (N6O4) macrocyclic ligand and its Cu(II) complexes.

A novel (N6O4) macrocyclic ligand (L) and its Cu(II) complexes have been prepared and characterized by elemental analysis, spectral, thermal (TG/DTG), magnetic, and conductivity measurements. Quantum chemical calculations have also been carried out at B3LYP/6-31+G(d,p) to study the structure of the ligand and one of its complexes. The results show a novel macrocyclic ligand with potential amide oxygen atom, amide and amine nitrogen atoms available for coordination.