Photosensitized Transformation of Hydrogen Peroxide in Dissolved Organic Matter Solutions under Simulated Solar Irradiation.

Hydrogen peroxide plays an important role in photochemical processes in aquatic environments. However, whether it can be transformed by photoexcited chromophoric dissolved organic matter (CDOM) remains unclear. Therefore, this study examined the photosensitized degradation of HO in CDOM-enriched solutions under simulated solar irradiation.

Microheterogeneous Distribution of Hydroxyl Radicals in Illuminated Dissolved Organic Matter Solutions.

Hydroxyl radicals (OH) are important reactive species that are photochemically generated through solar irradiation of chromophoric dissolved organic matter (CDOM) in surface waters. However, the spatial distribution within the complex three-dimensional structure of CDOM has not been examined. In this study, we used a series of hydrophobic chlorinated paraffins as chemical probes to elucidate the microheterogeneous distribution of OH in illuminated CDOM solutions.

Phototransformation of an emerging cyanotoxin (Aerucyclamide A) in simulated natural waters.

Aerucyclamide A (ACA) is an emerging cyanopeptide toxin produced by cyanobacteria, and its transformation pathway has rarely been reported. In the present study, ACA was purified from cyanobacterial extracts, and photodegradation processes were investigated in dissolved organic matter (DOM) solutions. Under simulated solar irradiation, the photodegradation of ACA was dominated by OH oxidation, accounting for ~72% of the indirect photodegradation.

Characterization of EDTA-cross-linked β-cyclodextrin grafted onto Fe-Al hydroxides as an efficient adsorbent for methylene blue.

The synthesis process of Fe-Al hydroxides coated with ethylenediaminetetraacetic acid (EDTA)-cross-linked β-cyclodextrin polymer (FA-ECD) and its utilization in the adsorption of methylene blue (MB) were investigated. The FA-ECD before and after adsorption was characterized by scanning electron microscopy (SEM), Brunauer-Emmet-Teller (BET) analysis, Fourier-transform infrared (FTIR) spectroscopy, thermogravimetric (TG) analysis, and X-ray diffraction (XRD). In addition, the EDTA and β-cyclodextrin contents were determined quantitatively.