High-Performance Integrated rGO-[Polymeric Ionic Liquid] [Heteropolyanions] for Catalytic Degradation of Azo Dyes.

Polymeric ionic liquid (such as poly[ViEtIm]Br)-modified reduced graphene oxide (rGO), rGO-poly[ViEtIm]Br, was nominated as an open carrier to construct a degradation platform. The large specific surface of rGO together with the anion-exchange property of poly[ViEtIm]Br terminals led to the wide growth of heteropolyanions (like [PWO], [PMoO], and [SiWO]), thus assembling the integrated catalyst rGO-poly[ViEtIm][heteropolyanions]. The grafted poly[ViEtIm]Br provided an anchor point to interlink the polar heteropolyanions and the nonpolar rGO substrate, endowing this graphene-based catalyst with excellent dispersibility.

Ionic liquid-based liposome for selective SERS detection.

An ionic liquid (IL)-based liposome was utilized as a substrate to construct a SERS platform. The isotropy of the IL outer surface together with its ion-exchange property led to the array-like growth of Au nanoparticles (NPs), generating hot-spots and resulting in anionic probes being present on the hot-spot regions. The simultaneous strategy of enrichment and localization endowed the platform with ability to detect trace amounts of anionic probes.

Application of expanded graphite-based materials for rechargeable batteries beyond lithium-ions.

New types of rechargeable batteries other than lithium-ions, including sodium/potassium/zinc/magnesium/calcium/aluminum-ion batteries and non-aqueous batteries, are rapidly advancing towards large-scale energy storage applications. A major challenge for these burgeoning batteries is the absence of appropriate electrode materials, which gravely hinders their further development. Expanded graphite (EG)-based electrode materials have been proposed for these emerging batteries due to their low cost, non-toxic, rich-layered structure and adjustable layer spacing.

Meso-Cellular Silicate Foam-Modified Reduced Graphene Oxide with a Sandwich Structure for Enzymatic Immobilization and Bioelectrocatalysis.

An integrated composite of meso-cellular silicate foam (MCF)-modified reduced graphene oxide (MCF@rGO) was designed and synthesized based on polyethylene oxide-polypropylene oxide-polyethylene oxide (P123)-modified rGO (P123-rGO). As the polymeric template for the fabrication of mesoporous silicates, modified P123 greatly improved the affinity between the nanosheet and the in situ formed MCFs, resulting in the formation of thin layers of MCFs on both sides of rGO. Therefore, the MCFs@rGO formed exhibited a unique sandwich structure with an inner skeleton of rGO and two outer layers of MCFs.

Temperature-Responsive Electrocatalysis Based on Poly(N-Isopropylacrylamide)-Modified Graphene Oxide (PNIPAm-GO).

Poly(N-isopropylacrylamide)-modified graphene oxide (PNIPAm-GO), which is a type of thermally responsive GO, was designed and synthesized through a covalent "grafting-from" strategy. The as-prepared modified nanosheets integrated the individual advantages of two components, such as the thermal sensitivity of the PNIPAm terminal as well as the conductivity and the open 2D structure of the GO substrate. PNIPAm-GO was able to perform the reversible regulation of hydrophilicity/hydrophobicity in aqueous solution upon variations in the temperature.

Thermally responsive reduced graphene oxide with designable secondary functionality.

Both dual responsive and thermal responsive reduced graphene oxide (rGO) with a strategically inbuilt function have been successfully synthesized by utilizing non-covalent modified poly(NIPAm-co-ViEtImBr) combined with anion exchange.

Catalytic Emulsion Based on Janus Nanosheets for Ultra-Deep Desulfurization.

Catalytic Janus nanosheets were synthesized by using an anion-exchange reaction between heteropolyacids (HPAs) and the modified ionic-liquid (IL) moieties of Janus nanosheets. Their morphology and surface properties were characterized by using SEM, energy-dispersive spectroscopy (EDS), FTIR spectroscopy, and X-ray photoelectron spectroscopy (XPS) studies. Because of their inherent Janus structure, the nanosheets exhibited good amphipathic character with ILs and oil to form a stable ILs-in-oil emulsion.