Hyperspectral imaging is a critical tool for gathering spatial-spectral information in various scientific research fields. As a result of improvements in spectral reconstruction algorithms, significant progress has been made in reconstructing hyperspectral images from commonly acquired RGB images. However, due to the limited input, reconstructing spectral information from RGB images is ill-posed.
View Article and Find Full Text PDFSuppressing the electron-hole recombination rate of catalyst legitimately is one of the effective strategies to improve photocatalytic hydrogen evolution. Herein, carbon-coated metal oxide, ZnFeO@C (ZFO@C), nanoparticles were synthesized and employed to couple with quadrupedal CdZnS (CZS) via an ordinary ultrasonic self-assembly method combined with calcination to form a novel ZFO@C/CZS catalyst with step-scheme (S-scheme) heterojunction. The photocatalytic hydrogen evolution reaction (HER) was conducted to verify the enhanced photoactivity of ZFO@C/CZS.
View Article and Find Full Text PDFArmchair X-N nanoribbons (X-ANNRs) and zigzag X-N nanoribbons (X-ZNNRs) were calculated using first-principles calculations. Ferromagnets (FM) were found to be the most stable among the initial magnetic structures. Furthermore, nanoribbons were found to be thermodynamically stable through molecular dynamics simulations.
View Article and Find Full Text PDFHyperspectral imaging attempts to determine distinctive information in spatial and spectral domain of a target. Over the past few years, hyperspectral imaging systems have developed towards lighter and faster. In phase-coded hyperspectral imaging systems, a better coding aperture design can improve the spectral accuracy relatively.
View Article and Find Full Text PDFIn telescopic systems consisting of Alvarez lenses, chromatic aberrations vary with the magnifications and the fields of view. Computational imaging has developed rapidly in recent years, therefore we propose a method of optimizing the DOE and the post-processing neural network in 2 stages for achromatic aberrations. We apply the iterative algorithm and the gradient descent method to optimize the DOE, respectively, and then adopt U-Net to further optimize the results.
View Article and Find Full Text PDFThe electronic structure of g-CN/CN-2D nanoribbons was investigated by first-principles calculations. As a splice structure, we first computed the three magnetic coupled states of g-CN/CN-2D nanoribbons. After self-consistent calculations, both the antiferromagnetic and paramagnetic coupling states become ferromagnetic coupling states.
View Article and Find Full Text PDFDiffractive optical elements play a crucial role in the miniaturization of the optical systems, especially in correcting achromatic aberration. Considering the rapidity and validity of the design method, we propose a fast method for designing broadband achromatic diffractive optical elements. Based on the direct binary search algorithm, some improvements have been made including the selection of the initial height map to mitigate the uncertainty, the reduction of the variations to accelerate the optimization and the increase of sampling rate to deal with the large operation bandwidth.
View Article and Find Full Text PDFPhotocatalytic water splitting, using solar energy to obtain hydrogen, is an ideal technology for producing new energy. In the process of photocatalysis, the improvement of the catalytic performance of the catalysts used is a matter of great concern to scientists. So far, there are many problems preventing improvements in photocatalytic performance.
View Article and Find Full Text PDFIn the present study, an n-ZnO nanorods (NRs)/p-degenerated diamond tunneling diode was investigated with regards to its temperature-dependent negative differential resistance (NDR) properties and carrier tunneling injection behaviors. The fabricated heterojunction demonstrated NDR phenomena at 20 and 80°C. However, these effects disappeared followed by the occurrence of rectification characteristics at 120°C.
View Article and Find Full Text PDFIn this paper, acquisition of the valence Compton profile of few-layer graphene using electron energy-loss spectroscopy at large scattering angle is reported. The experimental Compton profile is compared with the corresponding theoretical profile, calculated using the full-potential linearized augmented plane wave method based on the local-density approximation. Good agreement exists between the theoretical calculation and experiment.
View Article and Find Full Text PDFValence Compton profiles (CPs) of multiwall (MWCNTs) and single-wall carbon nanotubes (SWCNTs) were obtained by recording electron energy-loss spectra at large momentum transfer in the transmission electron microscope, a technique known as electron Compton scattering from solids (ECOSS). The experimental MWCNT/SWCNT results were compared with that of graphite. Differences between the valence CPs of MWCNTs and SWCNTs were observed, and the SWCNT CPs indicate a greater delocalization of the ground-state charge density compared to graphite.
View Article and Find Full Text PDFThe electron momentum density and sp/sp ratio of carbon materials in the thermal transformation of detonation nanodiamonds (ND) into carbon nano-onions are systematically studied by electron energy-loss spectroscopy (EELS). Electron energy-loss near-edge structures of the carbon K-ionization in the electron energy-loss spectroscopy are measured to determine the sp content of the ND-derived samples. We use the method developed by Titantah and Lamoen, which is based on the ability to isolate the π spectrum and has been shown to give reliable and accurate results.
View Article and Find Full Text PDFThe electronic structure of the graphitic carbon nitride (g-CN) under strain was obtained using the hybrid density functional HSE06 with a larger computational workload. The g-CN could withstand 12% of the applied tensile strain. The electronic structure of g-CN could be changed effectively under the tensile force.
View Article and Find Full Text PDFA heterojunction of n-ZnO nanowire (NW)/p-B-doped diamond (BDD) was fabricated. The rectifying behavior was observed with the turn on voltage of a low value (0.8 V).
View Article and Find Full Text PDFPhotocatalytic water splitting is a new technology for the conversion and utilization of solar energy and has a potential prospect. One important aspect of enhancing the photocatalytic efficiency is how to improve the electron-hole separation. Up to now, there is still no ideal strategy to improve the electron-hole separation.
View Article and Find Full Text PDFPhys Chem Chem Phys
February 2015
Polymeric graphitic carbon nitride materials exhibit exotic properties superior to graphene which are promising for applications in energy conversion, environment protection, and spintronics devices. We propose a two-dimensional (2D) framework of graphene-like carbon nitride composing of C9N7 units connected by nitrogen atoms. From first-principles, we demonstrate that this 2D carbon nitride has a spin-polarized ground state and exhibits metallic electronic properties, in contrast to commonly studied graphitic carbon nitrides which are nonmagnetic semiconductors.
View Article and Find Full Text PDF