Type I Porous Liquids with Super-Low Viscosities: the Construction through a Rather Simple One-Step Covalent Linkage Strategy and Its Facile Regulation by a Mixed-Ligand Strategy.

Porous liquids (PLs) are a novel class of flowing liquid systems that possess accessible permanent porosity, exhibiting great prospects in gas capture and separation. Nevertheless, the further development of PLs lies in the facile synthesis and regulation of PLs with low viscosities. Herein, a novel strategy of preparing type I PLs with super-low viscosity is proposed through a simple one-step covalent linkage reaction using UiO-66-NH as the pore generator and monoglycidyl ether terminated polydimethylsiloxane (E-PDMS) as the sterically hindered solvent, respectively.

Molecular-Squeeze Triggers Guest Desorption from Sponge-Like Macrocycle Crystals.

Desorption in conventional porous sorbents often employ external forces including inert gas blowing, heating, vacuum treatment to trigger guest release. We here report an unprecedented molecular-squeeze triggered guest release behavior from sponge-like macrocycle crystals. The crystals function as typical sponge to include guest molecules within their microscopic voids that are adaptively formed, thus acting as adsorbents for toluene/pyridine separations.

Iodine Boosted Fluoro-Organic Borate Electrolytes Enabling Fluent Ion-Conductive Solid Electrolyte Interphase for High-Performance Magnesium Metal Batteries.

Rechargeable magnesium batteries are regarded as a promising multi-valent battery system for low-cost and sustainable energy storage applications. Boron-based organic magnesium salts with terminal substituent fluorinated anions (Mg[B(OR)], R=fluorinated alkyl) have exhibited impressive electrochemical stability and oxidative stability. Nevertheless, their deployment is hindered by the complicated synthesis routes and the surface passivation of Mg metal anode.

Completely Inorganic Deep Eutectic Solvents for Efficient and Recyclable Liquid-Liquid Interface Catalysis.

Organic acid-based deep eutectic solvents (DESs) as catalysts always suffer from weak stability and low recyclability due to the accumulation of organic oxidative products in the DES phase. Herein, a completely inorganic deep eutectic solvent (IDES) ZnCl/PA with zinc chloride (ZnCl) and phosphoric acid (PA) as precursors is constructed to realize liquid-liquid interface catalysis for desulfurization of fuel and product self-separation for the first time. Owing to the inorganic nature, the organic oxidative products are accumulated at the interface between the IDES and fuel rather than the IDES phase.

Rational Design of Porous Ionic Liquids for Coupling Natural Gas Purification with Waste Gas Conversion.

Removal of trace impurities for natural gas purification coupled with waste gas conversion is highly desired in industry. We here report a type of porous ionic liquids (PILs) that can realize the continuous flow separation of CH /CO /H S and the conversion of the captured H S to useful products. The PILs are synthesized through a step-by-step surface modification of ionic liquids (ILs) onto UiO-66-OH nanocrystals.

Global dissection of the recombination landscape in soybean using a high-density 600K SoySNP array.

Recombination is crucial for crop breeding because it can break linkage drag and generate novel allele combinations. However, the high-resolution recombination landscape and its driving forces in soybean are largely unknown. Here, we constructed eight recombinant inbred line (RIL) populations and genotyped individual lines using the high-density 600K SoySNP array, which yielded a high-resolution recombination map with 5636 recombination sites at a resolution of 1.

Detecting QTL and Candidate Genes for Plant Height in Soybean Linkage Analysis and GWAS.

Soybean is an important global crop for edible protein and oil, and plant height is a main breeding goal which is closely related to its plant shape and yield. In this research, a high-density genetic linkage map was constructed by 1996 SNP-bin markers on the basis of a recombinant inbred line population derived from Dongnong L13 × Henong 60. A total of 33 QTL related to plant height were identified, of which five were repeatedly detected in multiple environments.

QTL for Main Stem Node Number and Its Response to Plant Densities in 144 Soybean FW-RILs.

Although the main stem node number of soybean [ (L.) Merr. ] is an important yield-related trait, there have been limited studies on the effect of plant density on the identification of quantitative trait loci (QTL) for main stem node number (MSNN).

Preparation of Activated Carbon Doped with Graphene Oxide Porous Materials and Their High Gas Adsorption Performance.

It is still a great challenge to develop a new porous carbon adsorbent with excellent separation performance and to recover low-concentration CH in coal mine gas. This work provides a new idea for the study of CH adsorption on activated carbon (AC) composites. Composite materials with microporous structures were prepared from coconut-shell activated carbon (CAC) doped with graphene oxide (GO) by a chemical activation process in this paper.

A Novel Strategy to Enhance the Performance of CO Adsorption Separation: Grafting Hyper-cross-linked Polyimide onto Composites of UiO-66-NH and GO.

Graphene oxide (GO) is widely used to improve the pore structure, dispersion capacity, adsorption selectivity, resistance to acids and bases, and thermal stability of metal-organic frameworks (MOFs). However, it remains a daunting challenge to enhance selectivity simply by modifying the pore surface polarity and producing a suitable pore structure for CO molecules through a combination of GO with MOFs. Herein, we demonstrate a novel porous hyper-cross-linked polyimide-UiO-graphene composite adsorbent for CO capture via in situ chemical knitting and condensation reactions.

Mapping QTL/QTN and mining candidate genes for plant height and its response to planting densities in soybean [ (L.) Merr.] through a FW-RIL population.

Unlabelled: Plant height (PH) determines the morphology and seed yield of soybean, so it is an important breeding target, which is controlled by multiple genes and affected by plant density. In this research, it was used about a four-way recombinant inbred lines (FW-RIL) with 144 families constructed by double cross (Kenfeng 14 × Kenfeng 15) × (Heinong 48 × Kenfeng 19) as experimental materials, with the purpose to map QTL/QTN associated with PH under densities of 2.2×10 plant/ha (D1) and 3×10 plant/ha (D2) in five environments.

Fine mapping QTL and mining genes for protein content in soybean by the combination of linkage and association analysis.

Soybean is one main source of dietary protein; therefore, improving protein content is an important objective in breeding programs. There is a significant negative correlation between protein and oil content, which influenced mapping quantitative trait locus (QTL) and quantitative trait nucleotides for these two traits. In this study, a linkage map was created with 2232 single-nucleotide polymorphism markers for the four-way recombinant inbred line (FW-RIL) population derived from the cross (Kenfeng 14 × Kenfeng 15) × (Heinong 48 × Kenfeng 19), and then conditional and unconditional QTL analyses were carried out by inclusive complete interval mapping based on the phenotypic data of protein and oil content collected in 10 different environments.

Transforming Metal-Organic Frameworks into Porous Liquids via a Covalent Linkage Strategy for CO Capture.

Porous liquids (PLs), an emerging kind of liquid materials with permanent porosity, have attracted increasing attention in gas capture. However, directly turning metal-organic frameworks (MOFs) into PLs via a covalent linkage surface engineering strategy has not been reported. Additionally, challenges including reducing the cost and simplifying the preparation process are daunting.

Identification of QTNs Controlling 100-Seed Weight in Soybean Using Multilocus Genome-Wide Association Studies.

Hundred-seed weight (HSW) is an important measure of yield and a useful indicator to monitor the inheritance of quantitative traits affected by genotype and environmental conditions. To identify quantitative trait nucleotides (QTNs) and mine genes useful for breeding high-yielding and high-quality soybean () cultivars, we conducted a multilocus genome-wide association study (GWAS) on HSW of soybean based on phenotypic data from 20 different environments and genotypic data for 109,676 single-nucleotide polymorphisms (SNPs) in 144 four-way recombinant inbred lines. Using five multilocus GWAS methods, we identified 118 QTNs controlling HSW.

Quantitative Trait Locus Analysis of Protein and Oil Content in Response to Planting Density in Soybean ( [L.] Merri.) Seeds Based on SNP Linkage Mapping.

Soybean varieties suitable for high planting density allow greater yields. However, the seed protein and oil contents, which determine the value of this crop, can be influenced by planting density. Thus, it is important to understand the genetic basis of the responses of different soybean genotypes to planting density.

Evaluation and management of fungal-infected carrot seeds.

Carrot (Daucus carota L.), which is one of the 10 most important vegetable crops worldwide, is an edible root vegetable desired for its taste as well as its medicinal uses. However, a fungus isolated from carrot seeds was observed to substantially decrease the germination rate.

Linkage Analysis and Multi-Locus Genome-Wide Association Studies Identify QTNs Controlling Soybean Plant Height.

Plant height is an important target for soybean breeding. It is a typical quantitative trait controlled by multiple genes and is susceptible to environmental influences. Here, we carried out phenotypic analysis of 156 recombinant inbred lines derived from "Dongnong L13" and "Henong 60" in nine environments at four locations over 6 years using interval mapping and inclusive composite interval mapping methods.

Mapping developmental QTL for plant height in soybean [Glycine max (L.) Merr.] using a four-way recombinant inbred line population.

Plant height (PH) is an important trait in soybean, as taller plants may have higher yields but may also be at risk for lodging. Many genes act jointly to influence PH throughout development. To map the quantitative trait loci (QTL) controlling PH, we used the unconditional variable method (UVM) and conditional variable method (CVM) to analyze PH data for a four-way recombinant inbred line (FW-RIL) population derived from the cross of (Kenfeng14 × Kenfeng15) × (Heinong48 × Kenfeng19).

Bio-Inspired Representation Learning for Visual Attention Prediction.

Visual attention prediction (VAP) is a significant and imperative issue in the field of computer vision. Most of the existing VAP methods are based on deep learning. However, they do not fully take advantage of the low-level contrast features while generating the visual attention map.

Identification of QTNs Controlling Seed Protein Content in Soybean Using Multi-Locus Genome-Wide Association Studies.

Protein content (PC), an important trait in soybean () breeding, is controlled by multiple genes with relatively small effects. To identify the quantitative trait nucleotides (QTNs) controlling PC, we conducted a multi-locus genome-wide association study (GWAS) for PC in 144 four-way recombinant inbred lines (FW-RILs). All the FW-RILs were phenotyped for PC in 20 environments, including four locations over 4 years with different experimental treatments.

Identification of QTLs related to the vertical distribution and seed-set of pod number in soybean [Glycine max (L.) Merri].

Pod number is an important factor that influences yield in soybean. Here, we used two associated recombinant inbred line (RIL) soybean populations, RIL3613 (containing 134 lines derived from Dongnong L13 × Heihe 36) and RIL6013 (composed of 156 individuals from Dongnong L13 × Henong 60), to identify quantitative trait loci (QTLs) regulating the vertical distribution and quantity of seeds and seed pods. The numbers of pods were quantified in the upper, middle, and lower sections of the plant, as well as in the plants as a whole, and QTLs regulating these spatial traits were mapped using an inclusive complete interval mapping method.

Electroplating lithium transition metal oxides.

Materials synthesis often provides opportunities for innovation. We demonstrate a general low-temperature (260°C) molten salt electrodeposition approach to directly electroplate the important lithium-ion (Li-ion) battery cathode materials LiCoO, LiMnO, and Al-doped LiCoO. The crystallinities and electrochemical capacities of the electroplated oxides are comparable to those of the powders synthesized at much higher temperatures (700° to 1000°C).

High Volumetric Capacity Three-Dimensionally Sphere-Caged Secondary Battery Anodes.

High volumetric energy density secondary batteries are important for many applications, which has led to considerable efforts to replace the low volumetric capacity graphite-based anode common to most Li-ion batteries with a higher energy density anode. Because most high capacity anode materials expand significantly during charging, such anodes must contain sufficient porosity in the discharged state to enable the expansion, yet not excess porosity, which lowers the overall energy density. Here, we present a high volumetric capacity anode consisting of a three-dimensional (3D) nanocomposite formed in only a few steps which includes both a 3D structured Sn scaffold and a hollow Sn sphere within each cavity where all the free Sn surfaces are coated with carbon.

High Full-Electrode Basis Capacity Template-Free 3D Nanocomposite Secondary Battery Anodes.

A high full-electrode basis capacity secondary battery anode consisting of a template-free 3D nanostructured Fe3O4/C composite is presented. On a full electrode basis, the nanocomposite exhibits attractive electrochemical performance including a volumetric capacity of 1064 mAh cm(-3), which significantly exceeds both the practical (≈300 mAh cm(-3)) and theoretical (837 mAh cm(-3)) capacity of a commercial graphite-based anode.