Sci Total Environ
January 2024
Since its rediscovery in 2014, layered black phosphorus (BP) has received extensive attention as a new two-dimensional semiconductor. BP is a promising material with properties of a large surface-to-volume ratio, wide light absorption range, tunable band gap, and high charge carrier mobility. These unique characteristics of BP make it a promising contender for various applications, particularly in the realm of environmental applications.
View Article and Find Full Text PDFThe polymorphism of phosphorus-based materials has garnered much research interest, and the variable chemical bonding structures give rise to a variety of micro and nanostructures. Among the different types of materials containing phosphorus, elemental phosphorus materials (EPMs) constitute the foundation for the synthesis of related compounds. EPMs are experiencing a renaissance in the post-graphene era, thanks to recent advancements in the scaling-down of black phosphorus, amorphous red phosphorus, violet phosphorus, and fibrous phosphorus and consequently, diverse classes of low-dimensional sheets, ribbons, and dots of EPMs with intriguing properties have been produced.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2023
Nanostructured materials with tunable structures and functionality are of interest in diverse areas. Herein, metal ions are coordinated with quinones through metal-acetylacetone coordination bonds to generate a class of structurally tunable, universally adhesive, hydrophilic, and pH-degradable materials. A library of metal-quinone networks (MQNs) is produced from five model quinone ligands paired with nine metal ions, leading to the assembly of particles, tubes, capsules, and films.
View Article and Find Full Text PDF