The epidermal cells of insects are polarized epithelial cells that play a pivotal role in the insect's molting process. Sinuous, a pivotal structural protein involved in the formation of septate junctions among epithelial cells, is essential for its physiological function. In this study, to determine whether sinuous participates in the regulation of insect molting, we identified the sinuous gene, , in , which encodes a protein belonging to the claudin family and shares 62.
View Article and Find Full Text PDFFeO is barely taken into account as an electrocatalyst for oxygen reduction reaction (ORR), an important reaction for metal-air batteries and fuel cells, due to its sluggish catalytic kinetics and poor electron conductivity. Herein, how strain engineering can be employed to regulate the local electronic structure of FeO for high ORR activity is reported. Compressively strained FeO shells with 2.
View Article and Find Full Text PDFUnder the background of "carbon neutral", lithium-ion batteries (LIB) have been widely used in portable electronic devices and large-scale energy storage systems, but the current commercial electrolyte is mainly liquid organic compounds, which have serious safety risks. In this paper, a bilayer heterogeneous composite solid-state electrolyte (PLPE) was constructed with the 3D LiX zeolite nanofiber (LiX-NF) layer and in-situ interfacial layer, which greatly extends the life span of lithium metal batteries (LMB). LiX-NF not only offers a continuous fast path for Li, but also zeolite's Lewis acid-base interaction can immobilize large anions, which significantly improves the electrochemical performance of the electrolyte.
View Article and Find Full Text PDFFushi-tarazu factor 1 (FTZ-F1) is a class of transcription factors belonging to the nuclear receptor superfamily and an important molting regulator in insects; however, its detailed function in the molting process of is still unclear. This study identified two FTZ-F1 transcripts ( and ) in . The classical domains of FTZ-F1 were present in their protein sequences and distinguished based on their variable N-terminal domains.
View Article and Find Full Text PDFLiPF-based carbonate electrolytes have been extensively employed in commercial Li-ion batteries, but they face numerous interfacial stability challenges while applicating in high-energy-density lithium-metal batteries (LMBs). Herein, this work proposes N-succinimidyl trifluoroacetate (NST) as a multifunctional electrolyte additive to address these challenges. NST additive could optimize Li solvation structure and eliminate HF/HO in the electrolyte, and preferentially be decomposed on the Ni-rich cathode (LiNiCoMnO, NCM811) to generate LiF/LiN-rich cathode-electrolyte interphase (CEI) with high conductivity.
View Article and Find Full Text PDFUpcycling harmful algal blooms (HABs) into short-chain organic matters (SCOMs) presents a significantly underexplored opportunity for addressing environmental concerns and achieving circular economy. But there are challenges of low HABs harvesting and SCOMs conversion efficiencies. To address these issues, a novel cellulose-based flocculant derived from abundant agricultural waste (wheat straw) was developed.
View Article and Find Full Text PDFBackground: The endoscopic nasojejunal (NJ) placement plays a pivotal role in the nutritional support of critically ill patients. However, the conventional endoscopy-guided tube insertion method presents issues of excessive procedural duration. We have enhanced the traditional endoscopy-guided catheter placement method, enabling a faster and more convenient catheter insertion.
View Article and Find Full Text PDFBackground: The cap 'n' collar (Cnc) belongs to the Basic Leucine Zipper (bZIP) transcription factor super family. Cap 'n' collar isoform C (CncC) is highly conserved in the animal kingdom. CncC contributes to the regulation of growth, development, and aging and takes part in the maintenance of homeostasis and the defense against endogenous and environmental stress.
View Article and Find Full Text PDFCytochrome P450 monooxygenases (P450s) are a superfamily of multifunctional heme-containing proteins and could function as odorant-degrading enzymes (ODEs) in insect olfactory systems. In our previous study, we identified a P450 gene from the antennal transcriptome of Locusta migratoria, LmCYP6MU1, which could be induced by a variety of volatiles. However, the regulatory mechanisms of this gene in response to volatiles remain unknown.
View Article and Find Full Text PDFCommercial Li-ion batteries use LiPF-based carbonate electrolytes extensively, but there are many challenges associated with them, like dendritic Li growth and electrolyte decomposition, while supporting the aggressive chemical and electrochemical reactivity of lithium metal batteries (LMBs). This work proposes 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFM) as a multifunctional electrolyte additive, constructing protective solid-/cathode-electrolyte interphases (SEI/CEI) on the surfaces for both lithium metal anode (LMA) and Ni-rich cathode to solve these challenges simultaneously. The highly fluorinated group (-CF) of the HFM molecule contributes to the construction of SEI/CEI films rich in LiF that offer excellent electronic insulation, high mechanical strength, and surface energy.
View Article and Find Full Text PDFThe systematical understanding of metal-dependent activity in electrocatalyzing oxygen reduction reaction (ORR), a vital reaction with sluggish kinetics for zinc-air batteries, remains quite unclear. An atomic and spatial engineering modulating ORR activity over hollow carbon quasi-sphere (HCS) confined in a series of single M-N (M = Cu, Mn, Ni) sites is reported here. Based on the theoretical prediction and experimental validation, Cu-N site with the lowest overpotential shows a better ORR kinetics than Mn-N and Ni-N .
View Article and Find Full Text PDFPrecocene I is a juvenile hormone antagonist that needs to be activated via oxidative biotransformation catalyzed by cytochrome P450 (CYP). NADPH-cytochrome P450 reductase (CPR) supplies CYP with electrons in the oxidation-reduction process; however, its functional role in the activation of precocene I remains unexplored. Here, the representative characteristics of CPRs were analyzed in the CPR gene of Locusta migratoria (LmCPR), the result of model docking indicated that the hydrogen bonds were formed between reduced nicotinamide adenine dinucleotide phosphate (NADPH), flavin adenine dinucleotide (FAD), flavin mononucleotide (FMN) and NADPH-, FAD-, FMN-domains of LmCPR, respectively.
View Article and Find Full Text PDFCytochrome P450 monooxygenases (P450s) are a large superfamily of heme-thiolate proteins and play a vital role in the biosynthesis and inactivation of endogenous substances as well as the detoxification of exogenous substances. They also function as odor-degrading enzymes (ODEs) in insect olfactory sensory systems. In the present study, a P450 gene was obtained from the antennae of Locusta migratoria and named as CYP6FD5.
View Article and Find Full Text PDFThe energy density of solid-state lithium batteries (SSLBs) has been primarily limited by the low ionic conductivity of solid electrolyte and poor interface compatibility between electrolyte and electrodes. Herein, a multifunctional composite solid polymer electrolyte (CSPE) based on polyethylene oxide (PEO) embedded with zeolitic imidazolate framework-8 deposited on carboxymethyl cellulose (ZIF@CMC) is reported. The ZIF@CMC interpenetrated in PEO matrix creates a continuous Li conductive network by combining Zn in ZIF with the unsaturated group in PEO to boost the Li transport through the PEO chain segment.
View Article and Find Full Text PDFTo explore the influence of predictive nursing combined with emotional therapy on the rehabilitation effect and psychological state of patients with brain injury after the operation and to analyze its application value to patients with brain injury after the operation. . 70 postoperative patients with brain injury who went to our hospital for diagnosis and treatment were selected as the key figures of this experiment, including 31 female patients and 39 male patients.
View Article and Find Full Text PDFTo evaluate the correlation of neutrophil-lymphocyte ratio (NLR), platelet-lymphocyte ratio (PLR), and mean platelet volume (MPV) with parameters related to gout activity. The general data of the patients and healthy controls (HCs), including complete blood count, C-reactive protein (CRP), erythrocyte sedimentation rate (ESR), serum uric acid (SUA), and the presence of tophi were retrospectively analyzed. NLR, MPV, and PLR were calculated in patients with intercritical gout and gout flares.
View Article and Find Full Text PDFRechargeable lithium metal batteries (LMBs) with high energy densities can be achieved by coupling a lithium metal anode (LMA) and a LiNiCoMnO (NCM811) cathode. Nevertheless, Li dendrite growth on the LMA surface and structural collapse of the NCM811 material, closely tied with the fragile cathode-/solid-electrolyte interphases (CEI/SEI) and corrosive hydrogen fluoride (HF), seriously deteriorate their performances. Herein, trimethylsilyl trifluoroacetate (TMSTFA) as a multifunctional electrolyte additive is proposed for regulation of the CEI/SEI films and elimination of HF.
View Article and Find Full Text PDFGlobally eruptive harmful algal blooms (HABs) have caused numerous negative effects on aquatic ecosystem and human health. Conversion of HABs into biohythane via dark fermentation (DF) is a promising approach to simultaneously cope with environmental and energy issues, but low HABs harvesting efficiency and biohythane productivity severely hinder its application. Here we designed a gradient electro-processing strategy for efficient HABs harvesting and disruption, which had intrinsic advantages of no secondary pollution and high economic feasibility.
View Article and Find Full Text PDFHarmful algal blooms (HABs) are growing threats that cause tens of billion dollars economic loss annually. Aiming at efficient disposal of HABs, a cheap and eco-friendly cationic straw was developed by etherification of wheat straw, which replaced hydroxyl groups on cellulose by quaternary ammonium groups. It endowed the cationic straw with high positive charge and achieved 93.
View Article and Find Full Text PDFObjective: To analyze the prognostic impact of staged nursing interventions on the treatment of patients with chronic obstructive pulmonary diseases (COPD) combined with type II respiratory failure.
Methods: 120 patients with COPD combined with type II respiratory failure admitted to our hospital between January 2021 and January 2022 were divided into a control group and a study group, with 60 patients in each group. The control group received conventional strategy interventions, and the study group received staged nursing interventions.
Wave-absorbing materials are developing in the direction of "light weight, wide frequency band, thin layer and high strength", and it is difficult to achieve the synergy between wave-absorbing performance and mechanical properties when graphene absorbent is compounded with a single resin matrix. In this paper, based on the preparation of a new composite absorbing wire with a graphene (GR)/spherical graphite (SG) double absorbent and polylactic acid (PLA)/thermoplastic polyurethane (TPU) double matrix, we proposed a new method to prepare samples for testing the electromagnetic parameters and tensile strength by fused deposition modeling (FDM). Furthermore, the effect of SG/GR ratio on the microwave absorbing properties and mechanical properties of PLA/TPU composites was specifically studied.
View Article and Find Full Text PDFIn this study, we obtained four alternative splicing transcripts of intracellular copper/zinc superoxide dismutase 1 (icCuZnSOD1) in Oxya chinensis. OcicCuZnSOD1a has all common characteristics of CuZnSOD family and is a canonical CuZnSOD. OcicCuZnSOD1b is missing a Zn binding site.
View Article and Find Full Text PDFBackground: Balloon dilation is a commonly used minimally invasive endourological treatment of ureteral stricture, but the postoperative recurrence rate is relatively high. And factors contributing to recurrence after treatment are poorly understood. Herein, we sought to develop a novel clinical nomogram to predict ureteral stricture-free survival in patients suffering from ureter stricture and performed balloon dilation.
View Article and Find Full Text PDFAnisotropic 3D nanostructures exhibit excellent electrocatalytic activity and stability due to their heterogeneous elemental distribution and unsymmetrical configuration. However, it is still a huge challenge to combine anisotropically distributed elements and anisotropic morphologies within one 3D nanostructure. Herein, 3D Au@Pt-Pd hemispherical nanostructures (Au@Pt-Pd H-Ss) are fabricated as highly efficient electrocatalysts for oxidation reaction, which present heterogenous element distribution and anisotropic morphology.
View Article and Find Full Text PDFHalloween genes are involved in the biosynthesis of the molting hormone, which plays a key role in insect ecdysis, development, metamorphosis, and reproduction. Our previous work identified five Halloween genes from Locusta migratoria, but their functions are currently unknown. In this study, the sequences of these five Halloween genes were analyzed and characterized.
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