Background: Only 2% to 6% aneurysmal bone cyst (ABC) involve the cranial region, and even fewer show sphenoid and orbital involvement. The spheno-orbital ABC is prone misdiagnosis and can result in intraoperative bleeding and residual lesions. The study was to summarize the clinical and therapeutic characteristics of patients with spheno-orbital ABC in children.
View Article and Find Full Text PDFObservational studies have suggested a bidirectional relationship between idiopathic normal pressure hydrocephalus (iNPH) and Alzheimer's disease (AD). However, the causal association between these two neurodegenerative disorders remains unclear. This study aimed to explore the causal relationship between iNPH and AD using a two-sample bidirectional Mendelian randomization (MR) method.
View Article and Find Full Text PDFObjective: Most patients with microprolactinomas require lifetime treatment with a dopamine agonist. Many patients in our center have sought endoscopic transsphenoidal surgery as an alternative therapy.
Methods: This study was a retrospective cohort analysis of 42 patients with microprolactinoma who underwent endoscopic transsphenoidal surgery between January 2010 and December 2023 performed by experienced neurosurgeons in our center.
Biomass-derived carbon for supercapacitors faces the challenge of achieving hierarchical porous carbon with graphitic structure and specific heteroatoms through a single-stage thermal process that minimises resource input. Herein, molten base carbonisation and activation is proposed. The process utilises the inherent moisture of Moso bamboo shoots, coupled with a low amount of KOH, to form potassium organic salts before drying.
View Article and Find Full Text PDFLiCO is the most tenacious parasitic solid-state product in lithium-air batteries (LABs). Developing suitable redox mediators (RMs) is an efficient way to address the LiCO issue, but only a few RMs have been investigated to date, and their mechanism of action also remains elusive. Herein, we investigate the effects of the central metal ion in binuclear metal phthalocyanines on the catalysis of LiCO decomposition, namely binuclear cobalt phthalocyanine (bi-CoPc) and binuclear cobalt manganese phthalocyanine (bi-CoMnPc).
View Article and Find Full Text PDFBackground: The ventriculoperitoneal (VP) shunt is widely acknowledged as a treatment option for managing intracranial hypertension resulting from non-human immunodeficiency virus (HIV) cryptococcal meningitis (CM). Nonetheless, there is currently no consensus on the appropriate surgical indications for this procedure. Therefore, it is crucial to conduct a preoperative evaluation of patient characteristics and predict the outcome of the VP shunt to guide clinical treatment effectively.
View Article and Find Full Text PDFWith its substantial theoretical capacity, silicon (Si) is a prospective anode material for high-energy-density lithium-ion batteries (LIBs). However, the challenges of a substantial volume expansion and inferior conductivity in Si-based anodes restrict the electrochemical stability. To address this, a yolk-shell-structured Si-carbon composite, featuring adjustable void sizes, was synthesized using tin (Sn) as a template.
View Article and Find Full Text PDFObjective: For unilateral Dodge Class Ⅰ optic pathway glioma (OPG-uDCⅠ) without neurofibromatosis type 1, unilateral isolated optic nerve gliomas before the optic chiasm have been confirmed to possibly cause visual deterioration and poor prognosis. For this type of highly selective localized tumor, we explored surgery as the only treatment method. This article retrospectively analyzed and summarized the clinical data of this case series, with the aim of exploring the main technical details and clinical prognosis.
View Article and Find Full Text PDFA sulfur doping strategy has been frequently used to improve the sodium storage specific capacity and rate capacity of hard carbon. However, some hard carbon materials have difficulty in preventing the shuttling effect of electrochemical products of sulfur molecules stored in the porous structure of hard carbon, resulting in the poor cycling stability of electrode materials. Here, a multifunctional coating is introduced to comprehensively improve the sodium storage performance of a sulfur-containing carbon-based anode.
View Article and Find Full Text PDFPotassium-ion batteries (PIBs) have aroused a large amount of interest recently due to the plentiful potassium resource, which may show cost benefits over lithium-ion batteries (LIBs). However, the huge volume expansion induced by the intercalation of large-sized potassium ions and the intrinsic sluggish kinetics of the anode hamper the application of PIBs. Herein, by rational design, nano-roses assembled from petals with a MoS/monolayer carbon (C-MoS) sandwiched structure were successfully synthesized.
View Article and Find Full Text PDFIn this paper, a Si@EG composite was prepared by liquid phase mixing and the elevated temperature solid phase method, while polyaniline was synthesized by the in situ chemical polymerization of aniline monomer to coat the surface of nano-silicon and exfoliated graphite composites (Si@EG). Pyrolytic polyaniline (p-PANI) coating prevents the agglomeration of silicon nanoparticles, forming a good conductive network that effectively alleviates the volume expansion effect of silicon electrodes. SEM, TEM, XRD, Raman, TGA and BET were used to observe the morphology and analyze the structure of the samples.
View Article and Find Full Text PDFAlthough silicon is being researched as one of the most promising anode materials for future generation lithium-ion batteries owing to its greater theoretical capacity (3579 mAh g), its practical applicability is hampered by its worse rate properties and poor cycle performance. Herein, a silicon/graphite/amorphous carbon (Si/G/C) anode composite material has been successfully prepared by a facile spray-drying method followed by heating treatment, exhibiting excellent electrochemical performance compared with silicon/amorphous carbon (Si/C) in lithium-ion batteries. At 0.
View Article and Find Full Text PDFElite upland rice cultivars have the advantages of less water requirement along with high yield but are usually susceptible to various diseases. Rice blast caused by is the most devastating disease in rice. Identification of new sources of resistance and the introgression of major resistance genes into elite cultivars are required for sustainable rice production.
View Article and Find Full Text PDFSynergistic effect of soft carbon and hard carbon has been proven to be useful for obtaining excellent anode materials for potassium ion battery, which is determined by the mixing degree of precursors. Inspired by the formation of proteins in biology, peptide bonds are used to connect the precursors of the two sort of carbon to prepare soft-hard hybrid carbons with stronger synergistic effects. The hard carbon domain with nanometer size is so highly distributed in the soft carbon that the synergistic effect between two sorts of carbon is significantly enhanced.
View Article and Find Full Text PDFBackground: Purely suprasellar and some complex intra-suprasellar Rathke cleft cysts (RCCs) are commonly treated via extended endonasal endoscopic approach or traditional transcranial approach. The feasibility of the trans-eyebrow supraorbital keyhole approach (TSKA) for RCCs was evaluated in this retrospective study.
Methods: A cohort of 16 patients (11 females and 5 males) with RCC was surgically treated via TSKA between January 2013 and November 2021.
Aim: To perform an accurate primary repair of temporal bone defects.
Material And Methods: The temporal bone defect models were performed in beagles. Extended estimated patches of the defects were predesigned by 3D reconstruction software and molded from polyether ether ketone (PEEK) using a lathe.
Although K is readily inserted into graphite, the volume expansion of graphite of up to 60% upon the formation of KC, together with its slow diffusion kinetics, prevent graphite from being used as an anode for potassium-ion batteries (PIBs). Soft carbon with low crystallinity and an incompact carbon structure can overcome these shortcomings of graphite. Here, ultra-thin two-dimensional (2D) wrinkled soft carbon sheets (USCs) are demonstrated to have high specific capacity, excellent rate capability, and outstanding reversibility.
View Article and Find Full Text PDFTraumatic brain injury (TBI) is a major global burden of health. As an accepted inflammatory mediator, high mobility group box 1 (HMGB1) is found to be effective in facilitating neurogenesis and axonal regeneration. SH3RF2 (also known as POSHER), an E3 ligase SH3 domain-containing ring finger 2, belongs to the SH3RF family of proteins.
View Article and Find Full Text PDFA highly densified electrode material is desirable to achieve large volumetric capacity. However, pores acting as ion transport channels are critical for high utilization of active material. Achieving a balance between high volume density and pore utilization remains a challenge particularly for hollow materials.
View Article and Find Full Text PDFLithium-ion capacitors (LICs) have attracted much attention considering their efficient combination of high energy density and high-power density. However, to meet the increasing requirements of energy storage devices and the flexible portable electronic equipment, it is still challenging to develop flexible LIC anodes with high specific capacity and excellent rate capability. Herein, we propose a delicate bottom-up strategy to integrate unique Schiff-base-type polymers into desirable one-dimensional (1D) polymeric structures.
View Article and Find Full Text PDFNumerous studies have reported that the enhancement of rate capability of carbonaceous anode by heteroatom doping is due to the increased diffusion-controlled capacity induced by expanding interlayer spacing. However, percentage of diffusion-controlled capacity is less than 30% as scan rate is larger than 1 mV s , suggesting there is inaccuracy in recognizing principle of improving rate capability of carbonaceous anode. In this paper, it is found that the heteroatom doping has little impact on interlayer spacing of carbon in bulk phase, meaning that diffusion-controlled capacity is hard to be enhanced by doping.
View Article and Find Full Text PDFDiacylglycerol (DAG) is commonly used as fat substitute in food manufacture due to its functional properties, but DAG has poor emulsification and oxidation stability, which limits its wide application in food industry. In this work, fluorescence quenching data and thermodynamic parameters were analyzed to investigate the interaction mechanism between l-theanine (L-Th) and β-lactoglobulin (β-LG). DAG emulsion was prepared by using β-lactoglobulin-theanine (β-LG-Th) as surface stabilizer, and its emulsification and oxidation stability were evaluated.
View Article and Find Full Text PDFMetallic lithium (Li) has been regarded as an ideal candidate for anode materials in next-generation high-energy-density batteries. However, a ubiquitous spongy Li deposition results in low reversibility, huge interfacial impedance, and even safety issues, hindering its practical application. Herein, we proposed a bifunctional electrolyte (BiFE) to avoid the spongy Li deposition, in which lithium nitrate (LiNO) facilitates a uniform granular Li nucleation via forming a kinetically favorable solid electrolyte interphase and silicon dioxide (SiO) adsorbs anions to stabilize the electric field distribution near the electrode surface.
View Article and Find Full Text PDF