Publications by authors named "Hai Chang"

Introduction: In China, the proportion of the elderly population is gradually increasing, followed by the increasing medical demands of elderly patients. Hip fracture is a common fracture in the elderly. The elderly are prone to serious postoperative complications, resulting in failure to restore normal hip function, which seriously affects patients' quality of life and further increases their mortality rate.

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We report a highly enantioselective intermolecular C-H bond silylation catalyzed by a phosphoramidite-ligated iridium catalyst. Under reagent-controlled protocols, propargylsilanes resulting from C(sp)-H functionalization, as well the regioisomeric and synthetically versatile allenylsilanes, could be obtained with excellent levels of enantioselectivity and good to excellent control of propargyl/allenyl selectivity. In the case of unsymmetrical dialkyl acetylenes, good to excellent selectivity for functionalization at the less-hindered site was also observed.

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Maintaining sufficient uniformity and stability of a ceramic slurry throughout the printing cycle is key to ensuring the performance of ceramic parts in ceramic-slurry stereolithography. In this study, a stable three-dimensional network structure was introduced into a slurry to achieve slurry uniformity and stability based on rheology theory. The effects of the particle size, solid loading, dispersant content, and gelling agent content on the stability of the three-dimensional network structure in the slurry were analyzed.

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To improve the crystal quality of 4,8-bis(2,4,6-trinitrophenyl)difurazolo [3,4-b:3',4'-e] pyrazine (TNBP), the solubility of TNBP in organic solvents (six pure and four mixed solvents) was determined by the laser monitoring technique from 293.15 to 353.15 K.

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The initial interaction mechanism is very important for the design and safety of nano-scale composite energetic materials composed of ammonium dinitramide (ADN) and nitrocellulose (NC). The thermal behaviors of ADN, NC and an NC/ADN mixture under different conditions were studied by using differential scanning calorimetry (DSC) with sealed crucibles, an accelerating rate calorimeter (ARC), a self-developed gas pressure measurement instrument and a DSC-thermogravimetry (TG)-quadrupole mass spectroscopy (MS)-Fourier transform infrared spectroscopy (FTIR) combined technique. The results show that the exothermic peak temperature of the NC/ADN mixture shifted forward greatly in both open and closed circumstances compared to those of NC or ADN.

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Nanoscale composite energetic materials (CEMs) based on oxidizer and fuel have potential advantages in energy adjustment and regulation through oxygen balance (OB) change. The micro- and nanosized fibers based on nano nitrocellulose (NC)-ammonium dinitramide (ADN) were prepared by the electrospinning technique, and the morphology, thermal stability, combustion behaviors, and mechanical sensitivity of the fibers were characterized by means of scanning electron microscope (SEM), transmission electron microscopy (TEM), differential scanning calorimetry (DSC), gas pressure measurement of thermostatic decomposition, laser ignition, and sensitivity tests. The results showed that the prepared fibers with fluffy 3D macrostructure were constructed by the overlap of micro/nanofibers with the energetic particles embedded in the NC matrix.

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The components in polymer-bonded explosive X, including cyclotetramethylene-tetranitramine, paraffin, and polytetrafluoroethylene, were determined using near-infrared (NIR) spectroscopy. Using partial least squares as the multivariate calibration method, quantitative calibration models for components in X were verified internally and externally. The possible combinations of eight general spectral pretreatment methods and different bands of the scanning spectral region (12,500-4000 cm) were established.

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The dynamic mechanical behaviors of Hydroxyl-terminated polybutadiene (HTPB) propellant was studied by a split Hopkinson pressure bar apparatus (SHPB) at strain rates ranging from 10 to 10 s. The obtained stress-strain curves indicated that the mechanical features, such as ultimate stress and strain energy, were strongly dependent on the strain rate. The real time deformation and fracture evolution of HTPB propellant were captured by a high-speed digital camera accompanied with an SHPB setup.

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This study aims to elucidate the effects of soil particle composition and fractal dimension on soil physical and chemical properties following sand-binding revegetation within straw checkerboard in south-eastern Tengger Desert. Three afforested plantations in the year of 2016 (i.e.

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Nano-structures of [Zn(L)(atpt)] (1) (L=1,2-bis(2-methylbenzimidazol-1-ylmethyl)benzene and Hatpt=2-aminoterephthalic acid) were obtained by hydrothermal and sonochemical approaches, characterized by scanning electron microscopy (SEM), IR, powder X-ray diffraction (PXRD), and elemental analysis. CP 1 features a 2D (4,4) network with the point symbol {4.6}, the 3D supramolecular architecture in CP 1 is controlled through π⋯π stacking interactions.

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A nanoparticle of cobalt(II) coordination polymer (CP), [Co(L)(npht)] (1) (Hnpht=4-nitrophthalic acid, L=1,3-bis(5,6-dimethylbenzimidazol-1-ylmethyl)benzene) and its nanocomposite (Ag/CP 1) were obtained by the sonochemical approach and characterized by IR, elemental analysis, thermogravimetric analyses (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and X-ray powder diffraction (XRPD). CP 1 shows a 1D double chain containing two different helical chains, which is further extended into a two-dimensional supramolecular framework by C-H⋯O hydrogen bonding interactions. The photoluminescence properties and photocatalytic properties of the nanoparticles of CP 1 and Ag/CP 1 on the degradation of methylene blue (MB) were investigated, Ag/CP 1 exhibited excellent photocatalytic activity under UV and visible light, which can be attributed to the strong interactions between Ag nanorods and CP 1, which lead to electron-hole pair separation between Ag nanorods and CP 1.

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Background: Differentiation of cardiac fibroblasts (CFs) into myofibroblasts is a critical event in the initiation of myocardial fibrosis (MF). Previous studies have shown that arginine vasopressin (AVP) facilitates MF. However, the effects of AVP on CFs-myofibroblasts transformation, and its possible mechanisms are still unknown.

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Objective: To observe the effect of medicated bath plus acupoint massage on limbs (B-M treatment) in treating diabetic peripheral neuropathy (DPN).

Methods: Eighty-two patients were divided into two groups, the control group (n=40) and the treated group (n=42), they were treated by conventional treatment but with B-M treatment applied to the latter additionally, the course to both groups was 12 weeks. The curative effects obtained were compared after treatment.

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