Publications by authors named "H Yabu"

To realize highly sensitive immunoassays, high optical density probes conjugated with antibodies for target antigens have been demanded in order to increase the visibility of antigen-antibody complex formation. We herein demonstrate the development of an immunoassay system using magnetic and fluorescent Janus particles as probes in conjunction with an antibody-immobilized microfluidic device. The concentration of the detection limit at which there was a significant difference between SARS-CoV-2 and human coronavirus 229E antigens was 3.

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Rechargeable Ca batteries offer the advantages of high energy density, low cost, and earth-abundant constituents, presenting a viable alternative to lithium-ion batteries. However, using polymer electrolytes in practical Ca batteries is not often reported, despite its potential to prevent leakage and preserve battery flexibility. Herein, a Ca(BH)-based gel-polymer electrolyte (GPE) is prepared from Ca(BH) and poly(tetrahydrofuran) (pTHF) and tested its performance in Ca batteries.

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In this report, we demonstrate that high-capacity hybrid supercapacitors can be realized by utilizing iron azaphthalocyanine (FeAzPc-4N) adsorbed activated carbons (ACs) as an electrode due to the combination of the electric double layer of activated carbon surfaces and redox reactions of FeAzPc-4N molecules. By increasing the mixing ratio of FeAzPc-4N with ACs, a maximum capacity of 907 F/g is achieved, also enabling rapid charging and discharging at 20 A/g. The revelation of the capacitor electrode's durability through 20 000 cycles of charging and discharging is realized, and the capacitor cell had sufficient output power to illuminate LEDs.

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This study delves into the formation of nanoscale polyhedral block copolymer particles (PBCPs) exhibiting cubic, octahedral, and variant geometries. These structures represent a pioneering class that has never been fabricated previously. PBCP features distinct variations in curvature on the outer surface, aligning with the edges and corners of polyhedral shapes.

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Article Synopsis
  • Molecular metal-nitrogen-carbon (M-N-C) catalysts, especially metal-doped azaphthalocyanine (AzPc) catalysts, show great promise for enhancing the oxygen reduction reaction (ORR) efficiency in fuel cells, particularly due to their unique structural properties when interacting with carbon substrates.
  • Understanding the relationship between structure and performance is complex, necessitating advanced microkinetic modeling and experimental validation to link these features effectively, especially considering variations in pH levels.
  • The study employs this microkinetic modeling to analyze the ORR performance of carbon-supported Fe-AzPcs, revealing that assessing charge transfer at the Fe site can help identify suitable functional groups to improve ORR efficiency at different pH environments.
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