Water Vapor, Clouds, and Saturation in the Tropical Tropopause Layer.

The goal of this investigation is to understand the mechanism behind the observed high relative humidity with respect to ice (RHi) in the tropical region between ~14 km (150 hPa) and the tropopause, often referred to as the tropical tropopause layer (TTL). As shown by satellite, aircraft and balloon observations, high (>80%) RHi regions are widespread within the TTL. Regions with the highest RHi are co-located with extensive cirrus.

Recent divergences in stratospheric water vapor measurements by frost point hygrometers and the Aura Microwave Limb Sounder.

Balloon-borne frost point hygrometers (FPs) and the Aura Microwave Limb Sounder (MLS) provide high-quality vertical profile measurements of water vapor in the upper troposphere and lower stratosphere (UTLS). A previous comparison of stratospheric water vapor measurements by FPs and MLS over three sites - Boulder, Colorado (40.0° N); Hilo, Hawaii (19.

The Stratospheric Water and Ozone Satellite Homogenized (SWOOSH) database: a long-term database for climate studies.

In this paper, we describe the construction of the Stratospheric Water and Ozone Satellite Homogenized (SWOOSH) database, which includes vertically resolved ozone and water vapor data from a subset of the limb profiling satellite instruments operating since the 1980s. The primary SWOOSH products are zonal-mean monthly-mean time series of water vapor and ozone mixing ratio on pressure levels (12 levels per decade from 316 to 1 hPa). The SWOOSH pressure level products are provided on several independent zonal-mean grids (2.

Heterogeneous reaction probabilities, solubilities, and the physical state of cold volcanic aerosols.

On 19 January 1992, heterogeneous loss of HNO(3), ClNO(3), and HCl was observed in part of the Mount Pinatubo volcanic cloud that had cooled as a result of forced ascent. Portions of the volcanic cloud froze near 191 kelvin. The reaction probability of ClNO(3) and the solubility of HNO(3) were close to laboratory measurements on liquid sulfuric acid.