-Poly[[di-phenyl-tin(IV)]-di-μ-iso-thio-cyanato]: an unprecedented layered coordination polymer resulting from bridging κ : thio-cyanato ligands.

In the title compound, di-phenyl-tin(IV) diiso-thio-cyanate, [Sn(NCS)(CH)] or PhSn(NCS), comparatively long tin-nitro-gen and short tin-sulfur bonds prove that the ambidentate iso-thio-cyanate ion acts as a bridge between two neighboring, octa-hedrally coordinated tin atoms. As a result, the mol-ecules lose their individuality in favor of a layered coordination polymer that represents a new type of mol-ecular inter-actions in the structural chemistry of diorganotin(IV) dihalides/pseudohalides. The tin atom is located on a center of inversion.

Bis(azido-κ )bis-(2,2'-di-pyridyl-amine-κ , )iron(II) monohydrate.

In the hydrated title complex, [Fe(dpa)(N)]·HO (dpa is 2,2'-di-pyridyl-amine, CHN), the Fe ion is coordinated in a distorted octa-hedral manner by two neutral, chelating dpa ligands and two anionic, monodentate azide (N ) ions in a -configuration. Distortion results from different Fe-N bond lengths [2.1397 (13)-2.

Baroreflex activation therapy through electrical carotid sinus stimulation.

An imbalance between cardiovascular parasympathetic and sympathetic activity towards sympathetic predominance has been implicated in the pathogenesis of treatment-resistant arterial hypertension and heart failure. Arterial baroreceptors control efferent cardiovascular autonomic activity and have, therefore, been recognized as potential treatment targets. Baroreflex activation therapy through electrical carotid sinus stimulation is a device-based approach to modulate cardiovascular autonomic activity.

Insights into the Theranostic Activity of Nonoxido V: Lysosome-Targeted Anticancer Metallodrugs.

Developing new anticancer agents can be useful, with the ability to diagnose and treat cancer worldwide. Previously, we focused on examining the effects of nonoxidovanadium(IV) complexes on insulin mimetic and cytotoxicity activity. In this study, in addition to the cytotoxic activity, we evaluated their bioimaging properties.