C dicarboxylic acid signatures indicate temporal shifts in catchment sediment sources in response to extreme winter rainfall.

Unlabelled: Rainfall and land-use interactions drive temporal shifts in suspended sediment sources, yet the magnitude of such changes remains poorly understood due to the lack of land-use specific source tracers. We investigated α,ω-dicarboxylic fatty acid root-specific biomarkers, as diagnostic tracers for apportioning sources of time-integrated suspended sediment samples collected from a grassland dominated agricultural catchment in the southwest of England during the wet winter period. Applying fatty acids-specific stable carbon isotope analysis and a Bayesian isotope mixing model, we show that stream banks contributed most of the sediment in the early winter, i.

Comparison of sediment biomarker signatures generated using time-integrated and discrete suspended sediment samples.

Sediment source fingerprinting using biomarker properties has led to new insights in our understanding of land use contributions to time-integrated suspended sediment samples at catchment scale. A time-integrated mass-flux sampler (TIMS; also known as the 'Phillips' sampler), a cost-effective approach for suspended sediment collection in situ. Such samplers are widely being used to collect sediment samples for source fingerprinting purposes, including studies using biomarkers as opposed to more conventional tracer properties.

Hydro-chemical responses at different scales in a rural catchment, UK, and implications for managing the unintended consequences of agriculture.

Diffuse pollutant transfers from agricultural land often constitute the bulk of annual loads in catchments and storm events dominate these fluxes. There remains a lack of understanding of how pollutants move through catchments at different scales. This is critical if the mismatch between the scales used to implement on-farm management strategies, compared to those used for assessment of environmental quality, is to be addressed.

Prolonged heavy rainfall and land use drive catchment sediment source dynamics: Appraisal using multiple biotracers.

Excessive sediment loss degrades freshwater quality and is prone to further elevation and variable source contributions due to the combined effect of extreme rainfall and differing land uses. To quantify erosion and sediment source responses across scales, this study integrated work at both field and catchment scale for two hydrologically contrasting winters (2018-19 and 2019-20). Sediment load was estimated at the field scale (grassland-arable conversion system).

Diffuse water pollution during recent extreme wet-weather in the UK: Environmental damage costs and insight into the future?

Periods of extreme wet-weather elevate agricultural diffuse water pollutant loads and climate projections for the UK suggest wetter winters. Within this context, we monitored nitrate and suspended sediment loss using a field and landscape scale platform in SW England during the recent extreme wet-weather of 2019-2020. We compared the recent extreme wet-weather period to both the climatic baseline (1981-2010) and projected near- (2041-2060) and far- (2071-2090) future climates, using the 95th percentiles of conventional rainfall indices generated for climate scenarios downscaled by the LARS-WG weather generator from the 19 global climate models in the CMIP5 ensemble for the RCP8.