The fluorescence intensity ratio (FIR) approach, which relies on thermally coupled levels (TCLs), is significantly important for optical thermometry at room temperature and above, but was found to be impractical for low temperature sensing due to limited population density (thermal) or lack of spectrum at extremely low temperatures. Herein, we report a wide temperature range (12-673 K) sensing capability of the PbZrTiO:Er/Yb (C1:PZT) phosphor utilising the bandwidth of Stark sublevel split near-infrared (NIR) emission bands as one sensing parameter and FIR as another. Motivated by our previous studies on upconversion (UC) and the promising thermometry performance of the C1:PZT phosphor for real time nanothermometer monitoring (using visible TCLs), this work extends to the same thermometry application using UC-NIR emission as TCLs.
View Article and Find Full Text PDFThe luminescent properties of europium (Eu) doped BaAlO phosphors were strongly influenced by post-annealing temperatures for blue-green persistent luminescence and latent fingerprints (LFPs). The X-ray powder diffraction patterns of the BaAlO: 1 mol% Eu nanophosphor, annealed between 1000 and 1300 °C, indicated a hexagonal ferroelectric phase. The X-ray photoelectron spectroscopy (XPS) revealed that the Ba atoms occupied two different sites in the BaAlO.
View Article and Find Full Text PDFTo investigate the impact of PO anionic groups, the trivalent europium ion-doped calcium molybdate (CaMoO-PO:xEu, where x = 0.5, 1.0, 1.
View Article and Find Full Text PDFA polymer based nanocomposite (NC) material embedded with highly luminescent nanopowders could be promising for replacing traditional luminescent materials from a technological point of view. In this study, we have successfully obtained YPO: Sm /Polymer nanocomposite phosphor films by embedding YPO: Sm luminescent nanoparticles (NPs) for orange-light emitting diode (LED) applications. These luminescent NPs were synthesized using the sol gel method in different polymer matrices i.
View Article and Find Full Text PDF