Arch Dis Child Educ Pract Ed
September 2024
Scand J Trauma Resusc Emerg Med
August 2024
The stable ferrocene-based N-heterocyclic silylenes fc[(N{B})Si] (A; fc=1,1'-ferrocenylene, {B}=(HCNDipp)B, Dipp=2,6-diisopropylphenyl) and fc[(NDipp)Si] (B) are compared in a study focussing on their reactivity towards a range of small to moderately sized molecular substrates, viz. P, S, Se, MesN (Mes=mesityl), RC≡CH, and RC≡CR (R=Ph, SiMe). The Dipp-substituted congener B exhibits a more pronounced ambiphilicity and is sterically less congested than its 1,3,2-diazaborolyl-substituted relative A, in line with the higher reactivity of the former.
View Article and Find Full Text PDFArch Dis Child Educ Pract Ed
November 2024
As the third case in the acute safeguarding essentials in modern-day paediatrics series, this article focuses on sexual relationships, consent and confidentiality. Using the scenario of a 15-year-old girl presenting to the emergency department with a positive pregnancy test, it begins with a guide to taking a psychosocial history in young people followed by discussion about some of the legality surrounding sexual relationships in adolescents, issues around consent and considerations for confidentiality in this age group.
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