Effects of poly- and monodisperse surfactants on 14C-epoxiconazole diffusion in isolated cuticles of Prunus laurocerasus.

Background: Surfactants are known to enhance the foliar uptake of agrochemicals. It was the aim of this study to compare the enhancing effect of three polydisperse surfactants (Brij 30, Plurafac LF300 and Wettol LF700) and five monodisperse alcohol ethoxylates (C12 E3, C12 E4, C12 E5, C12 E6 and C12 E8) on (14)C-epoxiconazole diffusion in cuticles isolated from cherry laurel (Prunus laurocerasus L.).

Highly concentrated emulsified microemulsions as solvent-free plant protection formulations.

Effective plant protection agents are readily available and well implemented in industry. However, delivery to the plant and application on the leaf are processes that still need to be optimized. Up to now plant protection formulations represent either emulsion or suspension concentrates that often contain environmentally harmful organic solvents and/or adjuvants.

Interfacial characteristics of heterogeneous layers of linear polyvinylamine and branched polyethyleneimine or polyethyleneimine grafted with C12-C22 alkyl chains.

We investigated the characteristics of heterogeneous layers composed of linear hydrolyzed polyvinylamine and branched polyethyleneimine adsorbed at silica/water interfaces. The studies also included heterogeneous layers where branched polyethyleneimine was replaced by polyethyleneimine modified by grafting with C12-C22 alkyl chains. Surface area exclusion chromatography was used to determine the interfacial relaxation and surface affinity of the polymer molecules within homogeneous layers.

Relaxation phenomena of polyethyleneimine molecules within saturated homogeneous and heterogeneous layers adsorbed at a silica/water interface.

Surface area exclusion chromatography was used to investigate the adsorption characteristics of the highly branched polyethyleneimine (PEI) molecule and of a related molecule resulting from the grafting of PEI with C12 to C22 alkyl chains. The interfacial relaxation and surface affinity of the two polymers was determined in homogeneous and heterogeneous layers. The presence of hydrophobic moieties within the branched morphology of the grafted PEI molecule was found to modify the adsorption histogram as compared to bare PEI and to lead to greater interfacial stability.

Destabilization of polystyrene latex particles induced by adsorption of polyvinylamine: mass, size and structure characteristics of the growing aggregates.

The obviously visible aggregation of suspended colloidal particles resulting from the addition of polyvinylamine to the aqueous dispersion of polystyrene latex particles bearing surface sulfate groups set in with a delay of 24 h. The aggregation mechanisms and the fractal dimension of the aggregates were derived from the variations with time of the weight and number averaged masses of the aggregates as well as of the weight averaged harmonic mean diameter of the size distribution. Since the establishment of starved layers was determined to be relatively fast and to leave the liquid phase free of polymer, the delay for the obvious destabilization was attributed to the reconformation of adsorbed macromolecules that was expected to be extremely slow.