The necessity for high operational temperatures presents a considerable obstacle to the commercial viability of solid oxide fuel cells (SOFCs). The introduction of active co-dopant ions to polycrystalline solid structures can directly impact the physiochemical and electrical properties of the resulting composites including crystallite size, lattice parameters, ionic and electronic conductivity, sinterability, and mechanical strength. This study proposes cobalt-iron-substituted gadolinium-doped ceria (CoFeGDC) as an innovative, nickel-free anode composite for developing ceramic fuel cells.
View Article and Find Full Text PDFEngineering the interfacial interaction between the active metal element and support material is a promising strategy for improving the performance of catalysts toward CO methanation. Herein, the Ni-doped rare-earth metal-based A-site substituted perovskite-type oxide catalysts (Ni/AMnO; A = Sm, La, Nd, Ce, Pr) were synthesized by auto-combustion method, thoroughly characterized, and evaluated for CO methanation reaction. The XRD analysis confirmed the perovskite structure and the formation of nano-size particles with crystallite sizes ranging from 18 to 47 nm.
View Article and Find Full Text PDFThe membrane bioreactor (MBR) is an efficient technology for the treatment of municipal and industrial wastewater for the last two decades. It is a single stage process with smaller footprints and a higher removal efficiency of organic compounds compared with the conventional activated sludge process. However, the major drawback of the MBR is membrane biofouling which decreases the life span of the membrane and automatically increases the operational cost.
View Article and Find Full Text PDFBiomass gasification streams typically contain a mixture of CO, H, CH, and CO as the majority components and frequently require conditioning for downstream processes. Herein, we investigate the catalytic upgrading of surrogate biomass gasifiers through the generation of syngas. Seeking a bifunctional system capable of converting CO and CH to CO, a reverse water gas shift (RWGS) catalyst based on Fe/MgAlO was decorated with an increasing content of Ni metal and evaluated for producing syngas using different feedstock compositions.
View Article and Find Full Text PDFProfitability studies are needed to establish the potential pathways required for viable biomethane production in the Brandenburg region of Germany. This work study the profitability of a potential biomethane production plant in the eastern German region of Brandenburg, through a specific practical scenario with data collected from a regional biogas plant located in Alteno (Schradenbiogas GmbH & Co. KG).
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