Publications by Gyaneshwar Kumar Rao

Publications by authors named "Gyaneshwar Kumar Rao"

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Electrocatalytic reduction of CO to CO and HCO with Zn(II) complexes displaying cooperative ligand reduction.

Patrick Berro Somayeh Norouziyanlakvan Gyaneshwar Kumar Rao Bulat Gabidullin Darrin Richeson

Chem Commun (Camb)

September 2021

Air-stable zinc(II) pyridyl phosphine complexes, [Zn(κ-2,6-{PhPNMe}(NCH))Br] (1) and [Zn(κ-2-{PhPNMe}(NCH))Br] (2) are reported and 1 was capable of electrocatalytic reduction of CO at -2.3 V Fc to yield CO/HCOH in mixed water/acetonitrile solutions. DFT computations support a proposed mechanism involving electron transfer reactions from a species with the anionic PNP ligand ("L/Zn(II)").

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