Thermal interface materials play a pivotal role in efficiently transferring heat from heating devices to thermal management components, thereby reducing the risk of component degradation due to overheating. In this study, we propose a strategy for enhancing the out-of-plane thermal conductivity (TC) of composite materials by fabricating a three-dimensional (3D) thermal network within a polydimethylsiloxane (PDMS) matrix. Specifically, the composite material was designed to incorporate a dense thermal network comprising hexagonal boron nitride nanosheets (BNNSs) and nanodiamonds (NDs).
View Article and Find Full Text PDFThe growing use of high-power and integrated electronic devices has created a need for thermal conductive adhesives (TCAs) with high thermal conductivity (TC) to manage heat dissipation at the interface. However, TCAs are often limited by contact thermal resistance at the interface between materials. In this study, we synthesized MXene@Ag composites through a direct reduction process.
View Article and Find Full Text PDFCopper metal catalyst seeds have recently triggered much research interest for the development of low-cost and high-performance metallic catalysts with industrial applications. Herein, we present metallic Cu catalyst seeds deposited by an atomic layer deposition method on polymer substrates. The atomic layer deposited Cu (ALD-Cu) can ideally substitute noble metals Ag, Au, and Pd to catalyze Cu electroless deposition.
View Article and Find Full Text PDFEnvironmental protection mandates have spurred the widespread adoption of lead-free glass in electronic material adhesion. Glass powder, crucial for solar silver paste, notably affects the ohmic contact at the Ag-Si interface of crystalline silicon solar cells. This study examines how TeO content influences the high-temperature flowability and wettability of lead-free BiO-TeO-based glass powder, alongside the interplay between the glass's thermal properties and interface contact.
View Article and Find Full Text PDFSilver powder, as the primary component of solar silver paste, significantly influences various aspects of the paste's performance, including printing, sintering, and conductivity. This study reveals that, beyond the shape and size of the silver powders, their microstructure is a critical factor influencing the performance of both silver powders and silver pastes in solar cell applications. The growth process leads to the formation of either polycrystalline aggregated silver powder or crystal growth silver powder.
View Article and Find Full Text PDFLow-temperature lead-free silver pastes deserve thorough investigation for sustainable development and application of MgTiO ceramics in electronic devices. In this study, a series of BiO-BO-ZnO-SiO-AlO-CaO glasses with suitable softening temperatures were prepared via melt quenching using a type of micrometer silver powder formed by silver nanoparticle aggregates. The composite pastes containing silver powder, BiO glass powder and an organic vehicle were then screen-printed.
View Article and Find Full Text PDFSince dual-metal single-atom catalyst (CoZnN/C) has been experimentally synthesized by atomically arching CoZn on N-doped carbon nanofibers and exhibited potential electrocatalysis activity towards oxygen reduction reaction (ORR), we perform first-principles calculations to identify the highly active sites at different defects by comparing the four-step ORR processes on the constructed four CoZnN models on graphene. The corresponding N-edge effect, dopant effect, and C-edge ring-closing effect are evaluated with the ORR evolution on different bonding environments, including pristine CoZnN (OH), nanoribbon (NR) along zigzag direction, substitution of carbon/oxygen (C/O substitution), and C-edge ring-closing configurations. OH-ligand is shown to significantly improve the ORR activities for all the considered structures.
View Article and Find Full Text PDFHeat dissipation is a critical issue in high-performance electronics, which needs to be solved, and an electronic paste is a good choice to solve this issue. In this paper, silver nanoparticles/multi-walled carbon nanotube (Ag-NPs/MWCNT) composites were prepared by the chemical process for the modification of electronic pastes. The micromorphology and spectral analysis of the as-prepared Ag-NPs/MWCNT composites indicated that Ag-NPs were uniformly distributed on the MWCNT surfaces with high distribution densities; the average size of Ag-NPs was estimated to be 8.
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