Publications by authors named "Guowei Gao"

Accurate and rapid aflatoxin B1 (AFB1) detection is essential for ensuring the safety of food supplies. In this paper, we introduce a distance-readout paper-based microfluidic chip (DPMC) that offers a sensitive and reliable method for the detection of AFB1. The DPMC comprises a DNA hydrogel sensitive valve and a paper-based capillary channel.

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The practical development of Li-O batteries is often hindered by poor cycling stability, which arises from volatile liquid electrolytes, an unstable anode/electrolyte interface, and sluggish reaction kinetics related to LiO. In this study, we design a long-life quasi-solid-state Li-O battery by integrating a gel polymer electrolyte (GPE) with a tetramethylpiperidinyloxy (TEMPO) redox mediator anchored in a poly(2,2,6,6-tetramethylpiperidinyloxy-4-methacrylate) (PTMA) cathode. During cycling, the GPE stabilizes the lithium/electrolyte interface and retains the electrolyte, while the TEMPO moieties anchored in the PTMA cathode effectively enhance the catalytic selectivity for LiO formation and decomposition.

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Article Synopsis
  • Optical and synthetic aperture radar (SAR) images have different intensity characteristics that make traditional SIFT-based algorithms struggle with accurately matching them during image registration.
  • To address this, a new algorithm called OS-PSO is introduced, which utilizes a modified operator to improve consistency between the images and constructs a Harris scale space for better key-point identification and localization.
  • The algorithm shows enhanced performance by using advanced matching techniques and has been successfully tested on various satellite images, proving effective in complex environments compared to existing methods.
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Current issues with neuromorphic visual-tactile perception include limited training network representation and inadequate cross-modal fusion. To address these two issues, we proposed a dual network called visual-tactile spiking graph neural network (VT-SGN) that combines graph neural networks and spiking neural networks to jointly utilize the neuromorphic visual and tactile source data. First, the neuromorphic visual-tactile data were expanded spatiotemporally to create a taxel-based tactile graph in the spatial domain, enabling the complete exploitation of the irregular spatial structure properties of tactile information.

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In this paper, we developed a paper-based fluorescent sensor using functional composite materials composed of graphene quantum dots (GQDs) coated with molecularly imprinted polymers (MIPs) for the selective detection of tetracycline (TC) in water. GQDs, as eco-friendly fluorophores, were chemically grafted onto the surface of paper fibers. MIPs, serving as the recognition element, were then wrapped around the GQDs via precipitation polymerization using 3-aminopropyltriethoxysilane (APTES) as the functional monomer.

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Magnesium metal batteries (MMBs), recognized as promising contenders for post-lithium battery technologies, face challenges such as uneven magnesium (Mg) plating and stripping behaviors, leading to uncontrollable dendrite growth and irreversible structural damage. Herein, we have developed a Mg foil featuring prominently exposed (002) facets and an architecture of nanosheet arrays (termed (002)-Mg), created through a one-step acid etching method. Specifically, the prominent exposure of Mg (002) facets, known for their inherently low surface and adsorption energies with Mg atoms, not only facilitates smooth nucleation and dense deposition but also significantly mitigates side reactions on the Mg anode.

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Three-dimensional (3D) porous graphene-based materials have displayed attractive electrochemical catalysis and sensing performances, benefiting from their high porosity, large surface area, and excellent electrical conductivity. In this work, a novel electrochemical sensor based on 3D porous reduced graphene (3DPrGO) and ion-imprinted polymer (IIP) was developed for trace cadmium ion (Cd(II)) detection in water. The 3DPrGO was synthesized in situ at a glassy carbon electrode (GCE) surface using a polystyrene (PS) colloidal crystal template and the electrodeposition method.

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A novel multi-functional microfluidic paper-based analytical device (μPAD) integrated with ion imprinted polymers (IIPs) was proposed for specific, portable and low-cost detection of cadmium (Cd(II)) in water. The IIP was grafted on paper and integrated into the μPAD for separation of Cd(II) through multi-layer design. The paper-based screen printed carbon electrode (pSPCE) modified with reduced graphene oxide was fabricated and combined with the μPAD for electrochemical sensing of the separated Cd(II).

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In response to the requirements of large-scale space in-orbit assembly and the special environment of low gravity in space, this paper proposes a small robot structure with the integration of assembly, connection, and vibration reduction functionalities. Each robot consists of a body and three composite mechanical arms-legs, which can dock and transfer assembly units with the transport spacecraft unit, and also crawl along the edge truss of the assembly unit to a designated location to complete in-orbit assembly while ensuring precision. A theoretical model of robot motion was established for simulation studies, and in the research process, the vibration of the assembly unit was studied, and preliminary adjustments were made to address the vibration issue.

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In this paper, we describe a simple and practical way to prepare hydrogel membranes in a conical channel (pipette tip). We used a pipette to create a gas pressure difference on both sides of the gel precursor, which drove the gel precursor to move in the pipette tip. During movement, the shape of the hydrogel precursor gradually becomes thinner as the radius of the tapered channel becomes larger.

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A highly enantioselective γ-addition-driven cascade of β,γ-unsaturated carbonyl compounds by bifunctional ion-pair catalysis has been developed. With this protocol, a range of functionalized chiral 1,3-dioxolochroman derivatives were prepared in high yields with superior stereoselectivities (>99% and >20:1 ). The utility of this method was demonstrated by one-pot synthesis, scaled-up preparation, and facile transformation.

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Article Synopsis
  • - The study focuses on LINC00337, a long noncoding RNA, and its role in the development of lung adenocarcinoma, revealing it as a potential oncogene.
  • - Researchers conducted various experiments to determine the effects of LINC00337 on cell behaviors such as migration, invasion, and proliferation, finding that silencing it led to increased apoptosis and inhibited cancer cell activities.
  • - LINC00337 influences the expression of miR-1285-3p and YTHDF1, suggesting a mechanism where LINC00337 promotes cancer progression by regulating these two molecules.
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Lithium-sulfur (Li-S) batteries have been widely considered as the next-generation energy storage system but hindered by the soluble polysulfide intermediate-induced shuttle effect. Doping heteroatoms was confirmed to enhance the affinity of polysulfide and the carbon host, release the shuttle effect, and improve the battery performance. To enhance the Lewis acidity and reinforce the interaction between polysulfide and the carbon skeleton, a novel covalent triazine framework (CTFO) was designed and fabricated by copolymerizing 2,4,6-triphenoxy--triazine and 2,4,6-trichloro-1,3,5-triazine through Friedel-Crafts alkylation.

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Article Synopsis
  • - LncRNA MIR31HG acts as an oncogene in glioblastoma (GBM), promoting cell proliferation and preventing apoptosis, with its high expression detected through RT-qPCR analysis.
  • - The transcription factor STAT1 was found to upregulate MIR31HG, playing a critical role in its contribution to tumor growth in GBM.
  • - MIR31HG activates the Wnt/β-catenin signaling pathway by enhancing the nuclear translocation of β-catenin, and its depletion can be mitigated by LiCl treatment, suggesting potential therapeutic implications.
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A supramolecular strategy for detecting the concentration of polyamines has been established through competitive/synergetic complexation among polyamines, CB[7], γ-CD, and pyrene derivatives, which allows for convenient, rapid, and high throughput spectral/visual detection of the concentration of urinary polyamines based on the switching on/off of the pyrene excimer fluorescence.

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Distance-based detection methods with a quantitative readout are of great significance to point-of-care testing (POCT), are low-cost and user-friendly, and can be integrated into portable analytical devices. Here, we submit a visual quantitative distance-based sensor by capillary force alteration in a capillary tube. This sensor converts the wettability alteration caused by the target molecules into a capillary rise height signal.

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Unprecedented interheteromacrocyclic hosts charge transfer (CT) crystals were generated by cooling organic solutions containing -dimethoxybenzene-constituted pillar[5]arene () and -benzoquinone-constituted pillar[5]quinone (). Despite the weak CT interaction known between -dimethoxybenzene and -benzoquinone and the lack of formation of CT complexes between and in the solution phase, CT cocrystals between and were formed with solvent molecules included into the hosts' cavities. Such a cocrystallization arises from an elegant synergy between the CT interaction and solvent-binding-promoted crystallization.

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A novel electrochemical sensor based on electropolymerized ion imprinted poly (o-phenylenediamine) PoPD/electrochemical reduced graphene (ERGO) composite on glass carbon electrode (GCE) was fabricated for selective and sensitive determination of trace Cd(II) in water. ERGO was first deposited on the surface of GCE by electrochemical cyclic voltammetry (CV) scanning to enhance the electron transport activity at electrode surface. The ion imprinted polymer (IIP) of imprinted PoPD was then in situ electropolymerized on ERGO via CV scanning with oPD as functional monomer and Cd(II) ions as template, following removal of the template using electrochemical peroxidation method.

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The large random errors in Micro-Electro-Mechanical System (MEMS) gyros are one of the major factors that affect the precision of inertial navigation systems. Based on the indoor inertial navigation system, an improved wavelet threshold de-noising method was proposed and combined with a gradient radial basis function (RBF) neural network to better compensate errors. We analyzed the random errors in an MEMS gyroscope by using Allan variance, and introduced the traditional wavelet threshold methods.

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Reaction of chiral amines with benzaldehydes 3,5-disubstituted by two pyrenes or perylenes afforded corresponding double winged chiral imines, which aggregated to show significantly enhanced circular dichroism spectra at the transition bands of the chromophores in the mixture solutions of DMF and H2O.

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We have developed a novel mediated biochemical oxygen demand (BOD) biosensor based on immobilized () on three-dimensional (3D) porous graphene-polypyrrole (rGO-PPy) composite. The 3D porous rGO-PPy composite was prepared using hydrothermal method following with electropolymerization. Then the 3D porous rGO-PPy composite was used as a support for immobilizing negatively charged denoted as rGO-PPy- through coordination and electrostatic interaction.

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This study aims to investigate CNE1 and CNE2 cell proliferation and apoptosis of nasopharyngeal cancer (NPC) and X-linked inhibitor of apoptosis protein (XIAP) expression in NPC patients after radiotherapy. Quantitative real-time quantitative polymerase chain reaction (qRT-PCR) and Western Blot detected XIAP and XIAP-associated factor1 (XAF1) messenger RNA (mRNA) and protein expression of CNE1 and CNE2 in NPC cells irradiated by γ-ray; MTT and flow cytometry assays detected CNE2 cells proliferation and apoptotic rate, respectively. With a retrospective analysis of 109 NPC patients in Xinxiang Central Hospital, immunohistochemistry (IHC) method detected XIAP expression, followed by a 5-year clinical analysis of the prognosis relevance after radiotherapy.

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The electrophysiological properties of potassium ion channels are regarded as a basic index for determining the functional differentiation of neural stem cells. In this study, neural stem cells from the hippocampus of newborn rats were induced to differentiate with neurotrophic growth factor, and the electrophysiological properties of the voltage-gated potassium ion channels were observed. Immunofluorescence staining showed that the rapidly proliferating neural stem cells formed spheres in vitro that expressed high levels of nestin.

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The water-mediated neutral hydrolysis mechanism of carbonyl sulfide (OCS) has been re-examined using the hybrid supramolecule/continuum models with n = 2-8 explicit water cluster at the level of MP2(fc)(CPCM)/6-311++G(d,p)//MP2(fc)(CPCM)/6-31+G(d). Present calculations indicate that the potential energy surface in water solution is different from the one in the gas-phase, and only stepwise mechanism is observed in aqueous solution, i.e.

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