Developing High Energy Density Li-S Batteries via Pore-Structure Regulation of Porous Carbon Based Electrocatalyst.

The mesopores and macropores within porous carbon materials help increase the surface for the depostion of solid-state products, reduce the LiS film thickness, enhance electron and mass transport, and accelerate the reaction kinetics. However, an excessive amount of mesopores and macropores can lead to increased electrolyte consumption, particularly at high sulfur loadings, where excessive electrolyte usage hampers the enhancement of practical energy density in lithium-sulfur (Li-S) batteries. A rational pore structure can minimize the amount of electrolyte to fill the pores, thereby reducing electrolyte consumption while achieving rapid reaction kinetics and a high gravimetric energy density.

Multiscale Defective Interfaces for Realizing Na-CO Batteries With Ultralong Lifespan.

Despite their favorable high energy density and potential for CO recycling, Na-CO batteries have been held back by limitations in cycling capability, stemming from the sluggish CO reduction/evolution reaction (CORR/COER) kinetics at CO cathode and unmanageable deposition/stripping of metallic Na at the anode upon cycling. Herein, a "two-in-one" electrode with multiscale defective FeCu interfaces (CP@FeCu) is presented, which is capable of improving the CORR/COER kinetics of CO-breathing cathode, while modulating sodium deposition behavior. Experimental and theoretical investigations reveal multiscale defective FeCu interfaces are responsible for the enhancement of sodiophilicity and catalytic properties.

Recent Advances in Developing High-Performance Anode for Potassium-Ion Batteries based on Nitrogen-Doped Carbon Materials.

Owing to the low potential (vs K/K), good cycling stability, and sustainability, carbon-based materials stand out as one of the optimal anode materials for potassium-ion batteries (PIBs). However, achieving high-rate performance and excellent capacity with the current carbon-based materials is challenging because of the sluggish reaction kinetics and the low capacity of carbon-based anodes. The doping of nitrogen proves to be an effective way to improve the rate performance and capacity of carbon-based materials as PIB anode.

ZnInSe nanoparticles photocatalyst for efficient solar fuel production.

Selecting a suitable photocatalyst to establish the Z-scheme heterojunction which is accompanied by effective photogenerated hole and electron separation, is one of the advantageous strategies for efficient photocatalytic solar energy conversion. Therefore, we prepared a ZnInSe nanoparticles photocatalyst to build a double Z-scheme heterojunction with mixed-phase TiO nanofibers, boosting photocatalytic solar fuel preparation. The result of X-ray photoelectron spectroscopy confirmed the existence of interfacial chemical bonds and internal electric fields.

Photo-Assisted Rechargeable Metal Batteries: Principles, Progress, and Perspectives.

The utilization of diverse energy storage devices is imperative in the contemporary society. Taking advantage of solar power, a significant environmentally friendly and sustainable energy resource, holds great appeal for future storage of energy because it can solve the dilemma of fossil energy depletion and the resulting environmental problems once and for all. Recently, photo-assisted energy storage devices, especially photo-assisted rechargeable metal batteries, are rapidly developed owing to the ability to efficiently convert and store solar energy and the simple configuration, as well as the fact that conventional Li/Zn-ion batteries are widely commercialized.

A Universal Electronic Structure Modulation Strategy: Is Strong Adsorption Always Correlated with High Catalysis?

Unveiling the inherent link between polysulfide adsorption and catalytic activity is key to achieving optimal performance in Lithium-sulfur (Li-S) batteries. Current research on the sulfur reaction process mainly relies on the strong adsorption of catalysts to confine lithium polysulfides (LiPSs) to the cathode side, effectively suppressing the shuttle effect of polysulfides. However, is strong adsorption always correlated with high catalysis? The inherent relationship between adsorption and catalytic activity remains unclear, limiting the in-depth exploration and rational design of catalysts.

Multi-functional integrated design of a copper foam-based cathode for high-performance lithium-oxygen batteries.

Lithium-oxygen batteries (LOBs) with extraordinarily high energy density are some of the most captivating energy storage devices. Designing an efficient catalyst system that can minimize the energy barriers and address the oxidant intermediate and side-product issues is the major challenge regarding LOBs. Herein, we have developed a new type of integrated cathode of Cu foam-supported hierarchical nanowires decorated with highly catalytic Au nanoparticles which achieves a good combination of a gas diffusion electrode and a catalyst electrode, contributing to the synchronous multiphase transport of ions, oxygen, and electrons as well as improving the cathode reaction kinetics effectively.

Recent Progress of Vertical Graphene: Preparation, Structure Engineering, and Emerging Energy Applications.

Vertical graphene (VG) nanosheets have garnered significant attention in the field of electrochemical energy applications, such as supercapacitors, electro-catalysis, and metal-ion batteries. The distinctive structures of VG, including vertically oriented morphology, exposed, and extended edges, and separated few-layer graphene nanosheets, have endowed VG with superior electrode reaction kinetics and mass/electron transportation compared to other graphene-based nanostructures. Therefore, gaining insight into the structure-activity relationship of VG and VG-based materials is crucial for enhancing device performance and expanding their applications in the energy field.

Rational design of one-dimensional skin-core multilayer structure for electrospun carbon nanofibers with bicontinuous electron/ion transport toward high-performance supercapacitors.

The fast transport of electrons and ions within electrodes is crucial to the final electrochemical properties. Herein, we have developed a unique ultra-long one-dimensional (1D) skin-core multilayer structure based on electrospun carbon nanofibers mainly through a facile Stöber method combined with resorcinol-formaldehyde resin, which not only achieves bicontinuous electron/ion transport during the charge/discharge process, but also provides large surface area for ion adsorption. Particularly, controlling the number of active layers as well as regulating the active sites in layer both can obviously improve capacitive properties.

Electrospinning Photocatalysis Meet In Situ Irradiated XPS: Recent Mechanisms Advances and Challenges.

Producing solar fuels over photocatalysts under light irradiation is a considerable way to alleviate energy crises and environmental pollution. To develop the yields of solar fuels, photocatalysts with broad light absorption, fast charge carrier migration, and abundant reaction sites need to be designed. Electrospun 1D nanofibers with large specific areas and high porosity have been widely used in the efficient production of solar fuels.

Metallic Powder Promotes Nitridation Kinetics for Facile Synthesis of (Oxy)Nitride Photocatalysts.

Nitrogen-containing semiconductors (including metal nitrides, metal oxynitrides, and nitrogen-doped metal oxides) have been widely researched for their application in energy conversion and environmental purification because of their unique characteristics; however, their synthesis generally encounters significant challenges owing to sluggish nitridation kinetics. Herein, a metallic-powder-assisted nitridation method is developed that effectively promotes the kinetics of nitrogen insertion into oxide precursors and exhibits good generality. By employing metallic powders with low work functions as electronic modulators, a series of oxynitrides (i.

In Situ 1D Carbon Chain-Mail Catalyst Assembly for Stable Lithium-Sulfur Full Batteries.

The main obstacles for the commercial application of Lithium-Sulfur (Li-S) full batteries are the large volume change during charging/discharging process, the shuttle effect of lithium polysulfide (LiPS), sluggish redox kinetics, and the indisciplinable dendritic Li growth. Especially the overused of metal Li leads to the low utilization of active Li, which seriously drags down the actual energy density of Li-S batteries. Herein, an efficient design of dual-functional CoSe electrocatalyst encapsulated in carbon chain-mail (CoSe@CCM) is employed as the host both for the cathode and anode regulation simultaneously.

Visible-light-responsive Photocatalyst Based on Nitrogen-doped Bulk Oxide YTaO N for Z-scheme Overall Water Splitting.

Nitrogen doping into oxide has been proved to be an effective strategy to extend visible-light utilization of oxides with layered or channeled structure, but it is shortage for the bulk oxides free of layered or channeled structure. Here, we report a novel nitrogen-doped bulk oxide (denoted as YTaO N ) with good visible light response. As benefited from the strong hybridization of N 2p and O 2p electronic state according to the density functional theory (DFT) calculations, the band gap (3.

Revealing the Selective Bifunctional Electrocatalytic Sites via In Situ Irradiated X-Ray Photoelectron Spectroscopy for Lithium-Sulfur Battery.

The electrocatalysts are widely applied in lithium-sulfur (Li-S) batteries to selectively accelerate the redox kinetics behavior of Li S, in which bifunctional active sites are established, thereby improving the electrochemical performance of the battery. Considering that the Li-S battery is a complex closed "black box" system, the internal redox reaction routes and active sites cannot be directly observed and monitored especially due to the distribution of potential active-site structures and their dynamic reconstruction. Empirical evidence demonstrates that traditional electrochemical test methods and theoretical calculations only probe the net result of multi-factors on an average and whole scale.

Fundamental Understanding of Nonaqueous and Hybrid Na-CO Batteries: Challenges and Perspectives.

Alkali metal-CO batteries, which combine CO recycling with energy conversion and storage, are a promising way to address the energy crisis and global warming. Unfortunately, the limited cycle life, poor reversibility, and low energy efficiency of these batteries have hindered their commercialization. Li-CO battery systems have been intensively researched in these aspects over the past few years, however, the exploration of Na-CO batteries is still in its infancy.

Detecting and Quantifying Wavelength-Dependent Electrons Transfer in Heterostructure Catalyst via In Situ Irradiation XPS.

The identity of charge transfer process at the heterogeneous interface plays an important role in improving the stability, activity, and selectivity of heterojunction catalysts. And, in situ irradiation X-ray photoelectron spectroscopy (XPS) coupled with UV light optical fiber measurement setup is developed to monitor and observe the photoelectron transfer process between heterojunction. However, the in-depth relationship of binding energy and irradiation light wavelength is missing based on the fact that the incident light is formed by coupling light with different wavelengths.

Carbon Dots Mediated In Situ Confined Growth of Bi Clusters on g-C N Nanomeshes for Boosting Plasma-Assisted Photoreduction of CO.

Synthesis of high-efficiency, cost-effective, and stable photocatalysts has long been a priority for sustainable photocatalytic CO reduction reactions (CRR), given its importance in achieving carbon neutrality goals under the new development philosophy. Fundamentally, the sluggish interface charge transportation and poor selectivity of products remain a challenge in the CRR progress. Herein, this work unveils a synergistic effect between high-density monodispersed Bi/carbon dots (CDs) and ultrathin graphite phase carbon nitride (g-C N ) nanomeshes for plasma-assisted photocatalytic CRR.

Combined Plant Growth-Promoting Bacteria Inoculants Were More Beneficial than Single Agents for Plant Growth and Cd Phytoextraction of L. during Field Application.

Single or combined plant growth-promoting bacteria (PGPB) strains were widely applied as microbial agents in cadmium (Cd) phytoextraction since they could promote plant growth and facilitate Cd uptake. However, the distinct functional effects between single and combined inoculants have not yet been elucidated. In this study, a field experiment was conducted with single, double and triple inoculants to clarify their divergent impacts on plant growth, Cd uptake and accumulation at different growth stages of L.

In Situ Monitored (N, O)-Doping of Flexible Vertical Graphene Films with High-Flux Plasma Enhanced Chemical Vapor Deposition for Remarkable Metal-Free Redox Catalysis Essential to Alkaline Zinc-Air Batteries.

Rechargeable zinc-air batteries (ZABs) have attracted great interests for emerging energy applications. Nevertheless, one of the major bottlenecks lies in the fabrication of bifunctional catalysts with high electrochemical activity, high stability, low cost, and free of precious and rare metals. Herein, a high-performance metal-free bifunctional catalyst is synthesized in a single step by regulating radicals within the recently invented high-flux plasma enhanced chemical vapor deposition (HPECVD) system equipped with in situ plasma diagnostics.

Self-aligned stitching growth of centimeter-scale quasi-single-crystalline hexagonal boron nitride monolayers on liquid copper.

Two-dimensional hexagonal boron nitride (hBN) atomic crystals are excellent charge scattering screening interlayers for advanced electronic devices. Although wafer-scale single crystalline hBN monolayer films have been demonstrated on liquid Au and solid Cu (110) and (111) vicinal surfaces, their reproducible growth still remains challenging. Here, we report the facile self-aligned stitching growth of centimeter-scale quasi-single-crystalline hBN monolayer films through synergistic chemical vapor deposition growth kinetics and liquid Cu rheological kinetics control.

Lithium-Sulfur Batteries Meet Electrospinning: Recent Advances and the Key Parameters for High Gravimetric and Volume Energy Density.

Lithium-sulfur (Li-S) batteries have been regarded as a promising next-generation energy storage technology for their ultrahigh theoretical energy density compared with those of the traditional lithium-ion batteries. However, the practical applications of Li-S batteries are still blocked by notorious problems such as the shuttle effect and the uncontrollable growth of lithium dendrites. Recently, the rapid development of electrospinning technology provides reliable methods in preparing flexible nanofibers materials and is widely applied to Li-S batteries serving as hosts, interlayers, and separators, which are considered as a promising strategy to achieve high energy density flexible Li-S batteries.

Array-Structured Double-Ion Cooperative Adsorption Sites as Multifunctional Sulfur Hosts for Lithium-Sulfur Batteries with Low Electrolyte/Sulfur Ratio.

Low electrolyte/sulfur ratio (E/S) is a crucial factor that promotes the development of lithium-sulfur batteries (LSBs) with desired energy density. However, it causes multiple problems, including a strong "shuttle effect" during both the cycle and storage process, and limited sulfur utilization. Herein, we develop a NaTiO (NTO) nanowire array as a multifunctional sulfur host to simultaneously tackle both the above problems.

Synthesis of a Visible-Light-Responsive Perovskite SmTiO N Bifunctional Photocatalyst via an Evaporation-Assisted Layered-Precursor Strategy.

Development of visible-light-responsive oxynitride photocatalysts has been highly inspired for promising solar-to-chemical conversion, but the number of Ti-based oxynitrides is scarce because of the relatively low thermal stability of Ti ions under ammonia flow. Here, the feasible synthesis of a novel perovskite SmTiO N from the layered NaSmTiO precursor is demonstrated to exhibit wide visible-light response with a bandgap of ≈2.1 eV and to show effective water reduction and oxidation functionalities under visible-light irradiation.

Dynamic Reaction Mechanism of P-N-Switched H-Sensing Performance on a Pt-Decorated TiO Surface.

Pt decoration is known to be one of the most promising strategies to enhance the performance of TiO hydrogen gas sensors, while the effect of Pt-decorating concentration on the sensing performance of TiO and the specific interaction between Pt and TiO have not been fully investigated. Here, a series of TiO nanoarray thin films with differing amounts of Pt decorated (Pt/TiO) is fabricated, and the H-sensing performance is evaluated. A switch in the response from P-type to N-type is observed with increasing Pt decoration.

In Situ Electrochemical Intercalation-Induced Phase Transition to Enhance Catalytic Performance for Lithium-Sulfur Battery.

Accelerating the conversion of polysulfide to inhibit shutting effect is a promising approach to improve the performance of lithium-sulfur batteries. Herein, the hollow titanium nitride (TiN)/1T-MoS heterostructure nanospheres are designed with efficient electrocatalysis properties serving as a sulfur host, which is formed by in situ electrochemical intercalation from TiN/2H-MoS . Metallic, few-layered 1T-MoS nanosheets with abundant active sites decorated on TiN nanospheres enable fast electron transfer, high adsorption ability toward polysulfides, and favorable catalytic activity contributing to the conversion kinetics of polysulfides.