Isomeric diammonium passivation for perovskite-organic tandem solar cells.

In recent years, perovskite has been widely adopted in series-connected monolithic tandem solar cells (TSCs) to overcome the Shockley-Queisser limit of single-junction solar cells. Perovskite-organic TSCs, comprising a wide-bandgap (WBG) perovskite solar cell (pero-SC) as the front cell and a narrow-bandgap organic solar cell (OSC) as the rear cell, have recently drawn attention owing to the good stability and potential high power conversion efficiency (PCE). However, WBG pero-SCs usually exhibit higher voltage losses than regular pero-SCs, which limits the performance of TSCs.

Crowding-Induced Unconventional Phase Behaviors in Dendritic Rodlike Molecules via Side-Chain Engineering.

Dendritic molecules with a fanlike or conelike conformation are common molecular building blocks to construct supramolecular columnar or spherical phases. Although it is well-accepted that the preferred molecular conformation of dendritic molecules dictates their packing schemes, manipulation of this crucial parameter usually requires significant changes in molecular structures and tedious synthetic efforts. Herein, we report a simple yet highly efficient strategy to tune the molecular conformation of dendritic rodlike molecules by adjusting the length of alkyl side chains tethered to the rods.