Flexible Fiber Shaped Self-Powered System Based on Conductive PANI for Signal Sensing and Energy Harvesting.

As science and technology advance, people are increasingly inclined to use sustainable and portable wearable electronic devices. The traditional supporting power source, batteries, suffers from issues of flexibility and lifespan, severely constraining the development of wearable devices. Alternatively, the self-powered system, serving as a power source, can effectively collect energy from the surrounding environment, achieving maintenance-free operation and high adaptability, which has attracted widespread research.

In-Sensor Organic Electrochemical Transistor for the Multimode Neuromorphic Olfactory System.

The olfactory system is one of the six basic sensory nervous systems. Developing artificial olfactory systems is challenging due to the complexity of chemical information decoding and memory. Conventional chemical sensors can convert chemical signals into electric signals to decode gas information but they lack memory functions.

Biomimetic Transparent Layered Tough Aerogels for Thermal Superinsulation and Triboelectric Nanogenerator.

Transparent aerogels are ideal candidates for thermally insulating windows, solar thermal receivers, electronics, etc. However, they are usually prepared via energy-consuming supercritical drying and show brittleness and low tensile strength, significantly restricting their practical applications. It remains a great challenge to prepare transparent aerogels with high tensile strength and toughness.

Flexible, Wash-Resistant Human Mechanical Energy Harvesting and Storage System for Monitoring Human Movement.

The rapid development of personal portable electronic devices has brought an increasingly urgent need for flexible and portable power sources. Herein, a low-cost, wearable, efficient, sustainable energy harvesting and storage system for human motion detection has been developed, based on a supercapacitor (SC) and triboelectric nanogenerator (TENG). Carbon cloth (CC)-loaded ZnO/ZnS nanoarrays and a PVD-treated polyurethane conductive sponge are employed as positive and negative triboelectric friction layers, respectively.

Bioinspired Gradient Stretchable Aerogels for Ultrabroad-Range-Response Pressure-Sensitive Wearable Electronics and High-Efficient Separators.

Broad-range-response pressure-sensitive wearable electronics are urgently needed but their preparation remains a challenge. Herein, we report unprecedented bioinspired wearable electronics based on stretchable and superelastic reduced graphene oxide/polyurethane nanocomposite aerogels with gradient porous structures by a sol-gel/hot pressing/freeze casting/ambient pressure drying strategy. The gradient structure with a hot-pressed layer promotes strain transfer and resistance variation under high pressures, leading to an ultrabroad detection range of 1 Pa-12.

Flexible Triboelectric Nanogenerators Based on Electrospun Poly(vinylidene fluoride) with MoS/Carbon Nanotube Composite Nanofibers.

With the miniaturization of wearable smart devices, the demand for portable and sustainable power sources is increasing. Herein, a flexible and lightweight triboelectric nanogenerator (PMC-TENG) was fabricated with MoS/carbon nanotube (MC)-doped PVDF as the friction substrate based on electrospinning for harvesting random body motion energy under complex mechanical deformations. The charge density on the friction surface of PVDF nanofibers was found to increase significantly as the introduced electron acceptor of the MC composite, and nylon as a clothing material for another friction layer simplifies the structure of the device.

Transparent, flexible, and multifunctional starch-based double-network hydrogels as high-performance wearable electronics.

To meet the increasing demands of sustainability and eco-friendliness, biopolymer-based hydrogels combining flexibility and ionic conductivity have drawn great attention for green and wearable sensors. However, the preparation of transparent, flexible, durable, and highly sensitive biopolymer hydrogel-based sensors for strain/pressure and humidity sensing remains a challenge. Herein, a facile one-step strategy is proposed to fabricate transparent, highly flexible, and multifunctional starch/polyacrylamide double-network hydrogels based on natural renewable starch.

High-Temperature Oxidation Behavior of a Cu-Bearing 17Cr Ferritic Stainless Steel.

The isothermal oxidation behavior of 17Cr-0.85Si-0.5Nb-1.

Superhydrophobic highly flexible doubly cross-linked aerogel/carbon nanotube composites as strain/pressure sensors.

We report novel superhydrophobic highly flexible composites based on a doubly cross-linked (DCL) aerogel and carbon nanotubes (CNTs) for strain/pressure sensing. The DCL aerogel/CNT composite is prepared by radical polymerization of vinylmethyldimethoxysilane and vinyldimethylmethoxysilane, respectively, followed by hydrolytic co-polycondensation of the obtained polyvinylmethyldimethoxysilane and polyvinyldimethylmethoxysilane, combined with the incorporation of CNTs. Benefiting from the flexible methyl-rich DCL structure of the aerogel and conductive CNTs, the resultant DCL aerogel/CNT composite combines superhydrophobicity, high compressibility, high bendability, high elasticity, and strain- and pressure-sensitive conductivity.

Superelastic Multifunctional Aminosilane-Crosslinked Graphene Aerogels for High Thermal Insulation, Three-Component Separation, and Strain/Pressure-Sensing Arrays.

Aerogels have attracted great interest for their unique properties, but their mechanical brittleness and poor functionality highly limit their practical applications. Herein, we report unprecedented superelastic multifunctional aminosilane-crosslinked reduced graphene oxide (ACrGO) aerogels that are prepared via a facile and scalable strategy involving simultaneous crosslinking and reducing of graphene oxide nanosheets with different kinds of aminosilanes via C-N coupling and hydrolytic polycondensation reactions. It is found that 3-aminopropyl(diethoxy)methylsilane (APDEMS) is the better choice to enhance hydrophobicity, elasticity, and other properties of the resulting aerogels compared with (3-aminopropyl)triethoxysilane.

Superflexible Multifunctional Polyvinylpolydimethylsiloxane-Based Aerogels as Efficient Absorbents, Thermal Superinsulators, and Strain Sensors.

Aerogels are porous materials but show poor mechanical properties and limited functionality, which significantly restrict their practical applications. Preparation of highly bendable and processable aerogels with multifunctionality remains a challenge. Herein we report unprecedented superflexible aerogels based on polyvinylpolydimethylsiloxane (PVPDMS) networks, PVPDMS/polyvinylpolymethylsiloxane (PVPMS) copolymer networks, and PVPDMS/PVPMS/graphene nanocomposites by a facile radical polymerization/hydrolytic polycondensation strategy and ambient pressure drying or freeze drying.

Transparent, Superflexible Doubly Cross-Linked Polyvinylpolymethylsiloxane Aerogel Superinsulators via Ambient Pressure Drying.

Aerogels have many attractive properties but are usually costly and mechanically brittle, which always limit their practical applications. While many efforts have been made to reinforce the aerogels, most of the reinforcement efforts sacrifice the transparency or superinsulating properties. Here we report superflexible polyvinylpolymethylsiloxane, (CHCH(Si(CH)O)), aerogels that are facilely prepared from a single precursor vinylmethyldimethoxysilane or vinylmethyldiethoxysilane without organic cross-linkers.

Silica-titania composite aerogel photocatalysts by chemical liquid deposition of titania onto nanoporous silica scaffolds.

Silica-titania composite aerogels were synthesized by chemical liquid deposition of titania onto nanoporous silica scaffolds. This novel deposition process was based on chemisorption of partially hydrolyzed titanium alkoxides from solution onto silica nanoparticle surfaces and subsequent hydrolysis and condensation to afford titania nanoparticles on the silica surface. The titania is homogeneously distributed in the silica-titania composite aerogels, and the titania content can be effectively controlled by regulating the deposition cycles.