Halide Ordering Enables Superior Charge Transport in 3D (NMPDA)Pb I Br Perovskitoid Single Crystal.

Halide composition engineering has been demonstrated as an effective strategy for optical and electronic properties modulation in 3D perovskites. While the impact of halide mixing on the structural and charge transport properties of 3D perovskitoids remains largely unexplored. Herein, it is demonstrated that bromine (Br) mixing in 3D (NMPDA)Pb I (NMPDA = N-methyl-1,3-propane diammonium) perovskitoid yields stabilized (NMPDA)Pb I Br with specific ordered halide sites, where Br ions locate at the edge-sharing sites.

Asymmetric Diammonium Directed In-Plane Charge Transport Enhancement in Two-Dimensional Lead Bromide Perovskite for Weak-Light Detection.

Two-dimensional (2D) Dion-Jacobson (DJ) perovskites are drawing significant attention in optoelectronic fields because of their enhanced out-of-plane electron coupling and improved structure stability. However, the structural effects of organic cations on the in-plane charge transport properties of 2D DJ lead bromide perovskites have remained less explored. Herein, we adopt asymmetric 3-(dimethylamino)-1-propylammonium (DMPD) and symmetric butane-1,4-diammonium (BDA) to systematically investigate the influence of organic cations on the structural, optical, and in-plane charge transport properties of 2D lead bromide perovskites.

[Study on plasma temperature of a large area surface discharge by optical emission spectrum].

A large area surface discharge was realized in air/argon gas mixture by designing a discharge device with water electrodes. By using optical emission spectrum, the variations of the molecular vibrational temperature, the mean energy of electron, and the electronic excitation temperature as a function of the gas pressure were studied. The nitrogen molecular vibrational temperature was calculated according to the emission line of the second positive band system of the nitrogen molecule (C3 pi(u) --> B 3 pi(g)).

[Influence of pressure on plasma temperature of octagon structure in dielectric barrier discharge].

Octagon structure consisting of the spots and lines was firstly observed in discharge in argon and air mixture by using a dielectric barrier discharge device with water electrodes. Plasma temperatures of the spots and lines in octagon structure at different gas pressure were studied by using optical emission spectra. The emission spectra of the N2 second positive band (C3IIu-->B3IIg)were measured, and the molecule vibrational temperatures of the spots and lines were calculated by the emission intensities.

[Measurement of molecular vibrational temperature of the white-eye pattern in dielectric barrier discharge].

The white-eye pattern, whose cell is composed of a bright dot surrounded by a closed hexagon, was observed in air/ argon dielectric barrier discharge. It was found that the center dot, the vertex of hexagon and the center of hexagon side in a cell have different brightness. By using optical emission spectra, the vibrational temperature in the center dot, the vertex of hexagon and the center of hexagon side was measured, respectively.

[Spectra line profile and vibrational temperature of bright dot and dark dot discharge in a dielectric barrier discharge].

The emission spectrum line shift and vibrational temperature of the bright dot and dark dot discharges, which are observed in the argon and air dielectric barrier discharge at high temperature for the first time were measured and compared. The line shift of the spectral line of the Ar I (2P2-->1S5) is measured and the vibrational temperature was calculated using by the emission spectral lines of the N2 second positive band system (C3Pi(u)-->B3Pi(g)). The results show that the spectrum line shift of the bright dot discharge channel is larger than that of the dark dot channel, which indicates that the former has higher electron density compared to the latter, and the vibrational temperature of the dark dot discharge channel is higher than that of the bright dot discharge channel.

[Study on plasma parameters in diffuse discharge with semispherical electrod by optical emission spectrum].

The diffuse discharge plasma in air was observed in a dielectric barrier discharge with two semispherical water electrodes. The variations of vibration temperature, rotation temperature, and average electron energy as the function of the applied voltage were studied by emission spectroscopy. The vibration temperature and the rotation temperature were calculated through the second positive band system (C3Pi(u)-->B3Pi(g)) of N2+ and the first negative band system (B2 Sigma(u+)-->Chi2Sigma(g+)) of N(2+) respectively.