Publications by authors named "Guo-Qin Hu"
Article Synopsis
- Thioesters are crucial bioactive compounds often used in creating complex molecules, but traditional synthesis methods rely heavily on transition metals and harsh conditions.
- Recent advancements in photocatalysis have led to a new synthesis strategy using visible light-induced electron donor-acceptor (EDA) complex reactions.
- This study presents a sustainable technique for creating thioesters from aryl sulfonium salts without the need for transition metals.
Herein, we present a decarboxylative thiocarbonylation of aryl and alkenyl sulfonium salts with oxalic acid monothioethers (OAMs), which can be achieved by visible light-accelerated palladium catalysis. Sulfonium salts are widely available, and OAM is an easily accessible and stored reagent; this mild reaction method can also be used for the synthesis of different types of thioester compounds. The reaction represents a new application of visible light-accelerated palladium catalysis in catalytic decarboxylative cross-couplings.
View Article and Find Full Text PDFEpilepsy is the most common childhood neurologic disorder. Status epilepticus (SE), which refers to continuous epileptic seizures, occurs more frequently in children than in adults, and approximately 40-50% of all cases occur in children under 2 years of age. Conventional antiepileptic drugs currently used in clinical practice have a number of adverse side effects.
View Article and Find Full Text PDF[Laryngeal adenoid cystic carcinoma: case report].
Zhonghua Er Bi Yan Hou Tou Jing Wai Ke Za Zhi
August 2011