The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza-fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol-ecules and two water mol-ecules in the asymmetric unit. The 4,5-diaza-fluorene fragment is approximately planar, with r.m.
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May 2012
In the title compound, [Na(4)(C(15)H(9)N(4)O(4))(4)(CH(3)OH)(4)], the N(3)O(3) environment around the Na(+) ion is distorted octa-hedral. In the unit cell, four Na(+) ions are bridged by four Schiff base anions, leading to a tetra-nuclear complex with -4 symmetry. O-H⋯N hydrogen bonds between the methanol mol-ecule and the Schiff base anion stabilize the structural set-up.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
October 2011