Here we introduce a metal-free, catalytic and enantioselective strategy from α,β-unsaturated 2-acyl imidazoles to the chiral phosphorous 2-acyl imidazoles. Interestingly, this methodology was catalyzed by the classical and commercial oxazaborolidine under mild conditions. This strategy features a wide range of substrates scope with good yields and excellent enantioselectivities.
View Article and Find Full Text PDFThis paper studies the fuel supply offset of diesel engines based on the crankshaft segment signal. Engine nonuniformity refers to the crankshaft torque fluctuation caused by cylinder-to-cylinder differences caused by misfiring or differences in the fuel supply or air supply. Fuel injection offset can reduce the nonuniformity between cylinders to realize high-efficiency and low pollution combustion.
View Article and Find Full Text PDFA system for assessing the ecological security of Lhaze County in China's Tibetan Autonomous Region was developed using a pressure-state-response model and the analytic hierarchy process. We then used this model to comprehensively evaluate the status of ecological security in Lhaze County. Our results showed that the ecological environment in Lhaze County has deteriorated from an 'early stages of damage status' in the 1980s to 'moderately damaged status' today.
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