Deciphering the mineral code of urinary stones: A first look at zinc isotopes.

Zinc (Zn) is an essential element for all living organisms, and Zn isotopes play a key role in studying the formation of disease. Despite extensive studies on Zn isotopes in healthy and diseased human tissues, the role of Zn isotopes in urinary stones remains unexplored. This study investigates Zn isotopes in 37 urinary stones using multi-collector inductively coupled plasma mass spectrometry.

Distribution and controlling factors of dissolved inorganic carbon in urban rivers of a North China megacity: Insights from δC.

Transportation and transformation of the dissolved inorganic carbon (DIC) play a critical role in the regional carbon cycle. To clarify the natural and anthropogenic impacts on DIC, the concentration and isotopic composition of DIC (δC) in two typical urban rivers in northern China (Yongding River, YDR, and Chaobai River, CBR) were measured. Mass-balanced calculations were employed to quantify the impacts of different weathering processes.

Sources and health risks of heavy metals in kindergarten dust: The role of particle size.

Particle size effects significantly impact the concentration and toxicity of heavy metals (HMs) in dust. Nevertheless, the differences in concentrations, sources, and risks of HMs in dust with different particle sizes are unclear. Therefore, guided by the definition of atmospheric particulate matter, dust samples with particle sizes under 1000 μm (DT), 100 μm (DT), and 63 μm (DT) from Beijing kindergartens were collected.

The key role of major and trace elements in the formation of five common urinary stones.

Background: Urolithiasis has emerged as a global affliction, recognized as one of the most excruciating medical issues. The elemental composition of stones provides crucial information, aiding in understanding the causes, mechanisms, and individual variations in stone formation. By understanding the interactions between elements in various types of stones and exploring the key role of elements in stone formation, insights are provided for the prevention and treatment of urinary stone disease.

Significant influence of urban human activities and marine input on rainwater chemistry in a coastal large city, China.

The coastal urban region is generally considered an atmospheric receptor for terrestrial and marine input materials, and rainfall chemistry can trace the wet scavenging process of these materials. Fast urbanization in China's east coastal areas has greatly altered the rainwater chemistry. However, the chemical variations, determinants, and sources of rainfall are unclear.

Rare earth elements reveal the human health and environmental concerns in the largest tributary of the Mekong river, Northeastern Thailand.

The widespread application of rare earth elements (REEs) in contemporary industries and agriculture, has caused emerging contaminant accumulation in aquatic environments. However, there is a limited scope of risk assessments, particularly in relation to human health associated with REEs. This study investigated the provenance, and contamination levels of REEs, further evaluating their environmental and human health risks in river sediments from an agricultural basin.

Remarkable contamination characteristics, potential hazards and source apportionment of heavy metals in surface dust of kindergartens in a northern megacity of China.

It is essential to understand the impact of heavy metals (HMs) present in the surface dust (SD) of kindergartens on children, who are highly sensitive to contaminated dust in cities in their growth stage. A study was conducted on 11 types of HMs present in the SD of 73 kindergartens in Beijing. This study aims to assess the pollution levels and sources of eleven HMs in Beijing's kindergartens surface dust (KSD), and estimate the potential health risks in different populations and sources.

Chemical evolution of rainfall in China's first eco-civilization demonstration city: Implication for the provenance identification of pollutants and rainwater acid neutralization.

Rainfall chemistry is a vital indicator for reflecting anthropogenic/natural input on atmospheric quality, and the rainfall process is also the main sink of air contaminants, which has received widely concerns by all walks of life. However, the chemical compositions, sources of major solutes, historical evolution, and their determinants of rainwater in Chinese urban area, which is hotspot of atmospheric pollutant emission, are unclear under the dual background of fast economic development and eco-civilization construction. To decipher these issues, the latest year data of observation-based rainwater chemistry and the historical rainwater data, and air pollution data of China's first eco-civilization demonstration city were integrated and studied.

Effect of damming on hydrogeochemical characteristics and potential environmental risks in a large reservoir: Insights from different vertical layer sampling.

The water environment of large reservoirs is fragility due to effects from hydrological regulation of damming and anthropogenic inputs. As a critical path to quantify the natural chemical weathering and assess environmental risks, solute chemistry of river has been widely focused on. However, the complexed hydrological conditions of large reservoir affect the chemical compositions, and the significance of solute vertical geochemistry as an indicator of chemical weathering and water quality health remains explore.

Agricultural activity on the Mun River basin: insight from spatial distribution and sources of dissolved rare earth elements in northeast Thailand.

Rare earth elements (REE) are emerging pollutants of concern, impacted by intensive fertilizer use and discharge of human and animal waste into agricultural watersheds. However, the natural values and potential anthropogenic enrichment of REE in aqueous systems of the agricultural basins remain poorly understood. This study investigated the spatial variation of dissolved REE in a predominantly agricultural river (Mun River) in northeast Thailand.

Iron isotope fractionation of redox and geochemical cycling in the typical Gleysols in Mun River Basin, Northeast Thailand.

Iron (Fe) isotope is a potential tool for tracking redox process and geochemical cycling in terrestrial environment. In this study, Fe concentration and its isotopic composition (δFe) in two typical Gleysol profiles (M1 and M2) were investigated to distinguish the processes which influence the variation of Fe isotopic composition during redox regimes in the Mun River Basin (MRB). Under oxidizing condition, Fe(II) was oxidized and re-precipitated to form Fe(III) (hydr)oxides zone (Fe nodule-containing zone) in two Gleysol profiles, leading to extremely light Fe isotopes in these zones.

Preliminary investigation of soil organic carbon distribution and turnover patterns, and potential pollution sources in and around a typical coking plant in North China.

The variation characteristics of soil organic carbon (SOC) in and around the coking plant area are still unclear. In this work, the concentration and stable carbon isotope composition of SOC in coke plant soils were investigated to preliminarily identify the sources of SOC in and around the plant area, and to characterize soil carbon turnover. Meanwhile, the carbon isotopic technique was used to initially identify the soil pollution processes and sources in and around the coking plant area.

Strontium isotope ratios in kidney stones reveal the environmental implications for humans in Beijing, China.

Kidney stones are a common disease that threatens human health on a global scale and are closely related to the contemporary environment. The strontium isotope ratio (Sr/Sr) has been widely used to trace the migration of ancient humans through bones and teeth, which recorded their bioavailable Sr from the environment. However, no Sr/Sr data for kidney stones have been reported.

Land-use conversion controls on the mobility of Zn in paddy soils revealed by stable Zn isotopes.

Understanding Zn biogeochemical cycling is necessary for monitoring Zn supply for plants and life during land use conversion, which is critical for environmentally sustainable development. But little is known about how the conversion of paddy soil to abandoned land affects the Zn isotope signature. A comparative field observation was conducted in northeast Thailand to investigate the Zn isotope footprint of paddy soils and abandoned paddy soils (PL and NPL).

Alterations of ecosystem nitrogen status following agricultural land abandonment in the Karst Critical Zone Observatory (KCZO), Southwest China.

Background: Secondary succession after agricultural land abandonment generally affects nitrogen (N) cycle processes and ecosystem N status. However, changes in soil N availability and NO loss potential following secondary succession are not well understood in karst ecosystems.

Methods: In the Karst Critical Zone Observatory (KCZO) of Southwest China, croplands, shrub-grass lands, and secondary forest lands were selected to represent the three stages of secondary succession after agricultural land abandonment by using a space-for-time substitution approach.

Sources and geochemical behaviors of rare earth elements in suspended particulate matter in a wet-dry tropical river.

The processes of rock weathering and soil erosion, and hydrochemical characteristics are significantly affected by the climate in a basin. However, the sources of rare earth elements (REEs) in suspended particulate matter (SPM) under soil erosion, as well as the geochemical behaviors of REEs with changes in hydrochemical properties between seasons, have received little attention in the tropical monsoon zone. In this study, the temporal and spatial characteristics of the REEs in SPM were investigated in the Mun River (a wet-dry tropical river), Northeast Thailand.

Calcium isotope ratio in kidney stones: preliminary exploration of mechanism from the geochemical perspective.

Stable calcium (Ca) isotope ratios are sensitive and radiation-free biomarkers in monitoring biological processes in human bodies. Recently, the Ca isotope ratios of bone, blood, and urine have been widely reported to study bone mineral balance. However, as a pure Ca crystallization product, there is no report on the Ca isotope ratios of kidney stones, even though the prevalence of kidney stones is currently on the rise.

Nitrate dynamics and source identification of rainwater in Beijing during rainy season: Insight from dual isotopes and Bayesian model.

Anthropogenic reactive nitrogen emissions have a significant impact on atmospheric chemical composition and earth surface ecosystem. As one of the most important sinks of atmospheric nitrogen, the wet deposition of nitrate (rainwater NO) has been widely concerned. Yet, the sources and transformation processes of wet deposited NO were not well revealed in megacity during rainy season in the context of global climate change.

Environmental implications of agricultural abandonment on Fe cycling: Insight from iron forms and stable isotope composition in karst soil, southwest China.

Land-use change influences the fate of nutrient elements, including iron (Fe), and then threaten soil security. In this study, Fe forms and stable isotope composition (δFe) in soils were investigated to identify the variations in the processes of Fe cycling during agricultural abandonment in a karst region of Southwest China. Soil δFe compositions varied from -0.