Low-molecular weight organic acids can enhance the microbial reduction of iron oxide nanoparticles and pollutants by improving electrons transfer.

The combined application of dissimilatory iron-reducing bacteria (DIRB) and Fe(III) nanoparticles has garnered widespread interest in the contaminants transformation and removal. The efficiency of this composite system relies on the extracellular electron transfer (EET) process between DIRB and Fe(III) nanoparticles. While modifications to Fe(III) nanoparticles have demonstrated improvements in EET, enhancing DIRB activity also shows potential for further EET enhancement, meriting further investigation.

Current status and strategies for controlling hexachlorobutadiene from multiple perspectives of emission, occurrence, and disposal.

Hexachlorobutadiene (HCBD), as an emerging persistent organic pollutant, poses a pressing global environmental issue concerning its reduction and control. However, the lack of systematic studies on the sources and occurrence of HCBD hinders the development of effective disposal technologies. This study addresses HCBD prevention and treatment from multiple perspectives, including source emissions, environmental contamination distribution, and control technologies.

Environmental fate and transformation mechanisms of chlorinated organic pollutants from the petrochemical industry: Insights for pollution control and remediation.

Chlorinated organic pollutants (Cl-OPs), highly toxic and environmentally persistent, have become the spotlight, particularly from petrochemical industry. This study focuses on environmental fate of Cl-OPs from petrochemical industry, and transformation mechanisms in multi-media, aiming to enhance pollution control and remediation strategies. Emitted from leakage and waste discharge, Cl-OPs, encompassing chlorinated volatile organic compounds (Cl-VOCs), traditional and emerging persistent organic pollutants (POPs), were prevalent with average concentrations of 10-10 μg/m in the atmosphere, 10-10 μg/kg in soil and 10-10 μg/L in groundwater.

Super-exchange interaction enables FeMnO perovskite with excellent catalytic oxidation activity toward hexabromocyclododecane under humidity.

Although enhancing the catalytic oxidation activity is a hotspot in thermal-driven catalytic disposal of persistent organic pollutants, few studies have managed to improve catalysts' water-resistance properties. Herein, we developed FeMnO perovskite to boost the catalytic oxidation of hexabromocyclododecane under humidity by modulating its super-exchange interaction (SEI, Fe + Mn → Fe + Mn). FeMnO, with the strongest SEI, exhibits the biggest oxidation rate-constant, which is 3 times higher than that of commonly used FeO without SEI.

Recognition of screening out hierarchical toxic contaminants tuned by quantified pseudo-components from complex engineering co-combustion.

Co-combustion of industrial and municipal solid wastes has emerged as the most promising disposal technology, yet its effect on unknown contaminants generation remains rarely revealed due to waste complexity. Hence, six batches of large-scale engineering experiments were designed in an incinerator of 650 t/d, which overcame the inauthenticity and deviation of laboratory tests. 953-1772 non-targeted compounds were screened in fly ash.

Catalytic degradation of chlorinated volatile organic compounds (CVOCs) over Ce-Mn-Ti composite oxide catalysts.

Developing industrially moldable catalysts with harmonized redox performance and acidity is of great significance for the efficient disposal of chlorinated volatile organic compounds (CVOCs) in actual exhaust gasses. Here, commercial TiO, typically used for molding catalysts, was chosen as the carrier to fabricate a series of CeMnTiO materials with different Mn doping ratios and employed for chlorobenzene (CB) destruction. The introduction of Mn remarkedly facilitated the synergistic effect of each element via the electron transfer processes: Ce+Mn↔Ce+Mn and Mn+Ti↔Mn+Ti.

Source apportionment and suitability evaluation of seasonal VOCs contaminants in the soil around a typical refining-chemical integration park in China.

Accurate source apportionment of volatile organic compounds (VOCs) in soil nearby petrochemical industries prevailing globally, is critical for preventing pollution. However, in the process, seasonal effect on contamination pathways and accumulation of soil VOCs is often neglected. Herein, Yanshan Refining-Chemical Integration Park, including a carpet, refining, synthetic rubber, and two synthetic resin zones, was selected for traceability.

The main strategies for soil pollution apportionment: A review of the numerical methods.

Nowadays, a large number of compounds with different physical and chemical properties have been determined in soil. Environmental behaviors and source identification of pollutants in soil are the foundation of soil pollution control. Identification and quantitative analysis of potential pollution sources are the prerequisites for its prevention and control.

Ecological risks induced by consumption and emission of Pharmaceutical and personal care products in Qinghai-Tibet Plateau: Insights from the polar regions.

As the third pole of the world and Asia's water tower, the Tibetan Plateau experiences daily release of pharmaceutical and personal care products (PPCPs) due to increasing human activity. This study aimed to explore the potential relationship between the concentration and composition of PPCPs and human activity, by assessing the occurrence of PPCPs in areas of typical human activity on the Qinghai-Tibet Plateau and evaluating their ecological risk. The results indicate that 28 out of 30 substances were detected in concentrations ranging from less than 1 ng/L to hundreds of ng/L, with the average concentration of most PPCPs in the Tibet Autonomous Region being higher than that in Qinghai Province.

New insights into the distribution, potential source and risk of microplastics in Qinghai-Tibet Plateau.

Microplastics (MPs) as emerging contaminants have become a major global concern, however, the distribution and origin of MPs in Qinghai-Tibet Plateau (QTP) and their impacts on ecosystem are poorly known. Hence, we systematically evaluated the profile of MPs on the representative metropolitan locations of Lhasa and Huangshui Rivers and the scenic sites of Namco and Qinghai Lake. The average abundance of MPs in the water samples was 7020 items/m, which was 34 and 52 times higher than those for the sediment (206.

Application of a hybrid GEM-CMB model for source apportionment of PAHs in soil of complex industrial zone.

Accurate source apportionment is essential for preventing the contamination of pervasive industrial zones. However, a limitation of traditional receptor models is their negligence of transmission loss, which consequently reduces their accuracy. Herein, chemical mass balance (CMB) and generic environmental model (GEM) was fused into a new method, which was employed to determine the traceability of polycyclic aromatic hydrocarbons (PAHs) in a complex zone containing three coking plants, two steel plants, and one energy plant.

Metagenomic surveillance of antibiotic resistome in influent and effluent of wastewater treatment plants located on the Qinghai-Tibetan Plateau.

As hotspots for the dissemination of antibiotic resistance genes (ARGs), wastewater treatment plants (WWTPs) have attracted global attention. However, there lacks a sufficient metagenomic surveillance of antibiotic resistome in the WWTPs located on the Qinghai-Tibet Plateau. Here, metagenomic approaches were used to comprehensively investigate the occurrence, mobility potential, and bacterial hosts of ARGs in influent and effluent of 18 WWTPs located on the Qinghai-Tibet Plateau.

Insights into Chlorobenzene Catalytic Oxidation over Noble Metal Loading {001}-TiO: The Role of NaBH and Subnanometer Ru Undergoing Stable RuRu Circulation.

Catalytic combustion of ubiquitous chlorinated volatile organic compounds (CVOCs) encounters bottlenecks regarding catalyst deactivation by chlorine poisoning and generation of toxic polychlorinated byproducts. Herein, Ru, Pd, and Rh were loaded on {001}-TiO for thermal catalytic oxidation of chlorobenzene (CB), with Ru/{001}-TiO representing superior reactivity, CO selectivity, and stability in the 1000 min on-stream test. Interestingly, both acid sites and reactive active oxygen species (ROS) were remarkably promoted via adding NaBH.

PM2.5-mediated photochemical reaction of typical toluene in real air matrix with identification of products by isotopic tracing and FT-ICR MS.

The sight into photoconversion of toluene, a ubiquitous typical pollutant, attentively by the involvement of PM2.5 in the real air environment is crucial for controlling haze pollution. Compared with the large-size PM2.

Distribution, influence factors, and biotoxicity of environmentally persistent free radical in soil at a typical coking plant.

Environmentally persistent free radicals (EPFRs) are emerging pollutants in contaminated soils and have attracted significant attention. Chinese coke production making a great contribution to the globe is increasingly identified as the non-ignorable source of EPFRs. However, the distribution level, influence factors, and biotoxicity of EPFRs at coking sites remain poorly understood.

High-spatial-resolution VOCs emission from the petrochemical industries and its differential regional effect on soil in typical economic zones of China.

Volatile organic compounds (VOCs) are toxic to the ecological environment. The emission of VOCs into the atmosphere has already caused attention. However, few studies focus on their regional effects on soil.

Source apportionment and risk assessment for polycyclic aromatic hydrocarbons in soils at a typical coking plant.

Polycyclic aromatic hydrocarbons (PAHs) are widely present in the environment. The coking industry is an important industrial source of PAHs. Coke production in China accounts for 67.

[Sources and Distribution Characteristics of HCBD in Rapid Economic Development Areas].

In order to understand the sources and distribution characteristics of hexachlorobutadiene (HCBD) in the Yangtze River Delta (YRD), Beijing-Tianjin-Hebei (BTH), and Pearl River Delta (PRD), the emission sources, as well as their distribution in water and soil were analyzed based on the production levels of chlorinated hydrocarbons and wastewater discharge in the three regions. The results showed that the by-products of trichloroethylene (TCE) and tetrachloroethylene (PCE) and wastewater treatment plants were the main sources of HCBD in the three regions. In 2018, the total emissions of HCBD from by-products of TCE and PCE in the three regions were 498.

[VOCs Emission Inventory and Variation Characteristics of Artificial Sources in Hubei Province in the Yangtze River Economic Belt].

In this study, a 2018 anthropogenic volatile organic compounds (VOCs) emission inventory in Hubei Province was conducted using the emission factor method based on activity levels of five sources. The emission characteristics and variation trends of process sources from 2009 to 2018 were further analyzed. Total anthropogenic VOCs emissions were 6.

[Industrial Emission Characteristics and Control Countermeasures of VOCs in Chinese Rapid Economic Development Areas].

With the rapid development of China's economy, volatile organic compounds (VOCs) as the precursor of smog and ozone are of increasing concern, especially in rapidly developing areas. This paper is a systematic analysis of VOCs emissions and distribution trends in 12 typical industrial sectors, garbage and wastewater treatment plants, comprehensive industrial parks, and residential districts in Beijing-Tianjin-Hebei, Yangtze River Delta, and Pearl River Delta Regions. The results show that pharmacy, rubber producing, as well as paint spraying are the top three industries among the 12 typical industries with the highest average VOCs emission concentrations at 541, 499, and 450 mg·m, respectively.