Although nanozymes sensor arrays have the potential to recognize multiple target substances simultaneously, they currently rarely identify phenolic acids in food due to limited catalytic performance and complex preparation conditions of nanozymes. Here, inspired by the structure of polyphenol oxidase, we have successfully prepared a novel gallic acid-Cu (GA-Cu) nanozyme with laccase-like activity. Due to the different catalytic efficiency of GA-Cu nanozymes towards six common phenolic acids, a three-channel colorimetric sensor array was constructed using reaction kinetics as the sensing unit to achieve high-throughput detection and identification of six phenolic acids within a concentration range from 1 to 100 μM.
View Article and Find Full Text PDFLocalized surface plasmon resonance (LSPR) is well known for its unique ability to tune the reactivity of plasmonic materials via photoexcitation; however, it is still an open question as to whether plasmonic holes can be directly extracted to drive valuable chemical reactions. Herein we give an affirmative answer by reporting an illumination-enhanced oxygen evolution reaction (OER) using CuS nanodisks (NDs) alone as the electrocatalyst. Impressively, under 1221 nm laser or xenon lamp illumination, an unprecedented reduction of OER overpotential was observed on the CuS ND-coated electrodes.
View Article and Find Full Text PDFThe authors wish to make the following corrections to this article [1][...
View Article and Find Full Text PDFBenefiting from their ultra-small diameters and highly structural anisotropies, ultrathin semiconductor nanowires (USNWs) are well-known for their fascinating physical/chemical properties, as well as their promising applications in various fields. However, until now, it remains a challenge to synthesize high-quality USNWs with well-controlled diameters and lengths, let alone the exploration of their size-dependent properties and applications. To solve such a challenge, we report herein a ligand-induced low-temperature precursor thermolysis route for the controlled preparation of ultrathin ZnS nanowires, which is based on the oriented assembly of the in-situ formed ZnS clusters/tiny particles.
View Article and Find Full Text PDFAs crystalline semiconductor nanowires are thinned down to a single-unit-cell thickness, many fascinating properties could arise pointing to promising applications in various fields. A grand challenge is to be able to controllably synthesize such ultrathin nanowires. Herein, we report a strategy, which synergizes a soft template with oriented attachment (ST-OA), to prepare high-quality single-unit-cell semiconductor nanowires (SSNWs).
View Article and Find Full Text PDFWe report herein a heat-triggered precursor slow releasing route for the one-pot synthesis of ultrathin ZnSe nanowires (NWs), which relies on the gradual dissolving of Se powder into oleylamine containing a soluble Zn precursor under heating. This route allows the reaction system to maintain a high monomer concentration throughout the entire reaction process, thus enabling the generation of ZnSe NWs with diameter down to 2.1 nm and length approaching 400 nm.
View Article and Find Full Text PDFIn this work, we report on the synthesis of nitrogen doped SrTiO3 nanoparticles with efficient visible light driven photocatalytic activity toward Cr(VI) by the solvothermal method. The samples are carefully characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-Vis diffuse reflectance spectroscopy and photocatalytic test. It is found that nitrogen doping in SrTiO3 lattice led to an apparent lattice expansion, particle size reduction as well as subsequent increase of Brunner-Emmet-Teller surface area.
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