Environmentally friendly natural polymer-based room temperature phosphorescence (RTP) materials exhibit promising applications in anti-counterfeiting and information encryption. However, the construction of natural polymer-based RTP materials with multicolor long afterglow and even persistent near-infrared (NIR) luminescence remains a tough challenge. Here, starch (S)-based ultralong RTP materials with wide color-tunability, persistent NIR luminescence are conveniently prepared through Förster resonance energy transfer (FRET) strategies.
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