Durable Cu/NiFe(OH) electrocatalyst was designed for hydrogen evolution reaction in alkaline media. The generated Cu nanodendrites protect the NiFe(OH) from being hydrogenated, giving it a > 1000 h lifetime for high-performance water splitting (1.51 V, 10 mA cm in 1 M KOH) when coupled with a NiFe-layered double hydroxide anode.
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