China ranks 160 out of 180 countries in terms of ecological efficiency, with an EPI score of 28.40 and a 10-year average change in score of 11.40.
View Article and Find Full Text PDFHeterogeneous interfacial engineering has garnered widespread attention for optimizing polarization loss and enhancing the performance of electromagnetic wave absorption. A novel Kirkendall effect-assisted electrostatic self-assembly method is employed to construct a metal-organic framework (MOF, MIL-88A) decorated with Ni-Fe layered double hydroxide (LDH), forming a multilayer nano-cage coated with TiCT. By modulating the surface adsorption of TiCT on LDH, the heterointerfaces in MOF-LDH-MXene ternary composites exhibit excellent interfacial polarization loss.
View Article and Find Full Text PDFThe excellent performance of electromagnetic wave absorbers primarily depends on the coordination among components and the rational design of the structure. In this study, a series of porous fibers with carbon nanotubes uniformly distributed in the shape of pine leaves are prepared through electrospinning technique, one-pot hydrothermal synthesis, and high-temperature catalysis method. The impedance matching of the nanofibers with a porous structure is optimized by incorporating melamine into the spinning solution, as it undergoes gas decomposition during high-temperature calcination.
View Article and Find Full Text PDFDeveloping multifunctional materials which could simultaneously possess anti-bacterial ability and electromagnetic (EM) absorption ability during medical care is quite essential since the EM waves radiation and antibiotic-resistant bacteria are threatening people's health. In this work, the multifunctional carbon fiber/TiCT MXene (CM) were synthesized through repeated dip-coating and following in-situ growth method. The as-fabricated CF/MXene displayed outstanding EM wave absorption and highly efficient photothermal converting ability.
View Article and Find Full Text PDFCurrently, facing electromagnetic protection requirement under complex aqueous environments, the bacterial reproduction and organic dye corrosion may affect the composition and micro-structures of absorbers to weaken their electromagnetic properties. To address such problems, herein, a series of CoFeO@BCNPs (cobalt ferrite @ bio-carbon nanoparticles) composites are synthesized via co-hydrothermal and calcining process. The coupling of magnetic cobalt ferrite and dielectric bio-carbon derived from Apium can endow the composite multiple absorption mechanisms and matched impedance for effective microwave absorption, attaining a bandwidth of 8.
View Article and Find Full Text PDFThis paper considers the aperiodic intermittent control (AIC) for linear time-varying systems (LTVSs), where the occurrence instants are determined by an event triggering mechanism based on Lyapunov functions. For LTVSs, most of the existing results are demanded that the feedback controls are exerted all the time. In fact, in many practical applications, the applied controls are unnecessary/impossible to be imposed all the time.
View Article and Find Full Text PDFElectromagnetic wave (EMW) absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control. And in order to cope with the complex electromagnetic environment, the design of multifunctional and multiband high efficiency EMW absorbers remains a tremendous challenge. In this work, we designed a three-dimensional porous structure via the salt melt synthesis strategy to optimize the impedance matching of the absorber.
View Article and Find Full Text PDFLayered double hydroxides (LDHs) with unique layered structure and atomic composition are limited in the field of electromagnetic wave absorption (EMA) due to their poor electrical conductivity and lack of dielectric properties. In this study, the EMA performance and anticorrosion of hollow derived LDH composites are improved by temperature control and composition design using ZIF-8 as a sacrifice template. Diverse regulation modes result in different mechanisms for EMA.
View Article and Find Full Text PDFReasonable composition design and controllable structure are effective strategies for harmonic electromagnetic wave (EMW) adsorption of multi-component composites. On this basis, the hybrid MoS /CoS /VN multilayer structure with the triple heterogeneous interface is prepared by simple stirring hydrothermal, which can satisfy the synergistic interaction between different components and obtain excellent EMW absorption performance. Due to the presence of multiple heterogeneous interfaces, MoS /CoS /VN composites will produce strong interfacial polarization, while the defects in the sample will become the center of polarization, resulting in dipole polarization.
View Article and Find Full Text PDFThe development of wearable multifunctional electromagnetic protective fabrics with multifunctional, low cost, and high efficiency remains a challenge. Here, inspired by the unique flower branch shape of "Thunberg's meadowsweet" in nature, a nanofibrous composite membrane with hierarchical structure was constructed. Integrating sophisticated 0D@2D@1D hierarchical structures with multiple heterointerfaces can fully unleash the multifunctional application potential of composite membrane.
View Article and Find Full Text PDFIn the field of electromagnetic (EM) wave absorption, intrinsic conductive polymers with conjugated long-chain structures, such as polyaniline (PANI) and polypyrrole (PPy), have gained widespread use due to their remarkable electrical conductivity and loss ability. However, current research in this area is limited to macroscopic descriptions of the absorption properties of these materials and the contribution of various components to the absorption effect. There has been insufficient exploration of the impact mechanisms of polymer aggregation states on the material's absorption performance and mechanism.
View Article and Find Full Text PDFThe design of metal-organic frameworks (MOF) derived composites with multiple loss mechanisms and multi-scale micro/nano structures is an important research direction of microwave absorbing materials. Herein, multi-scale bayberry-like Ni-MOF@N-doped carbon composites (Ni-MOF@NC) are obtained by a MOF assisted strategy. By utilizing the special structure of MOF and regulating its composition, the effective improvement of Ni-MOF@NC's microwave absorption performance has been achieved.
View Article and Find Full Text PDFAlthough multifunctional aerogels are expected to be used in applications such as portable electronic devices, it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure. Herein, a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties, superhydrophobicity, and self-cleaning by water-induced NiCo-MOF self-assembly. Specifically, the impedance matching of the three-dimensional (3D) structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption.
View Article and Find Full Text PDFHarvesting largely ignored and wasted electromagnetic (EM) energy released by electronic devices and converting it into direct current (DC) electricity is an attractive strategy not only to reduce EM pollution but also address the ever-increasing energy crisis. Here we report the synthesis of nanoparticle-templated graphene with monodisperse and staggered circular nanopores enabling an EM-heat-DC conversion pathway. We experimentally and theoretically demonstrate that this staggered nanoporous structure alters graphene's electronic and phononic properties by synergistically manipulating its intralayer nanostructures and interlayer interactions.
View Article and Find Full Text PDFTunable designs of polymorphic structured transition metal dichalcogenide (TMDC) demonstrate promising applications in the field of electromagnetic wave absorption (EMW). However, it remains a technical challenge for achieving a balanced relationship between well-matched impedance characteristics and dielectric losses. Therefore, the co-modification strategies of polydopamine coating and wet impregnation are chosen to construct CoS magnetic double-shell microspheres with phase component modulation to achieve the optimized performance.
View Article and Find Full Text PDFApplication of novel radio technologies and equipment inevitably leads to electromagnetic pollution. One-dimensional polymer-based composite membrane structures have been shown to be an effective strategy to obtain high-performance microwave absorbers. Herein, we reported a one-dimensional N-doped carbon nanofibers material which encapsulated the hollow CoSnC nanocubes in the fiber lumen by electrospinning.
View Article and Find Full Text PDFIn order to achieve excellent electromagnetic wave (EMW) absorption properties, the microstructure design and component control of the absorber are critical. In this study, three different structures made of Mo C/C hollow spheres are prepared and their microwave absorption behavior is investigated. The Mo C/C double-shell hollow spheres consisting of an outer thin shell and an inner rough thick shell with multiple EMW loss mechanisms exhibit good microwave absorption properties.
View Article and Find Full Text PDFThree-dimensional (3D) graphene oxide aerogel (GOA) is one of the best fillers for composites for microwave absorption. However, its further development has been hindered by the poor mechanical properties. Methodology to improve the mechanical properties of the aerogel remains an urgent challenge.
View Article and Find Full Text PDFIn consideration of the growing electromagnetic wave (EMW) pollution and interference, it is of crucial and imperative significance to develop high-efficiency EMW absorption materials. Herein, hierarchical hybrid network of MoS@poly (3, 4-ethylenedioxythiophene) (PEDOT)/reduced graphene oxide (rGO) were successfully constructed and fabricated through the combination of oxidative polymerization and microwave-irradiated thermal reduction. The original defects in graphene oxide (GO) could be in situ repaired by introducing carbon source, and the rational regulation of polarization relaxation and conductivity of composites could be achieved.
View Article and Find Full Text PDFLithium metal batteries (LMBs) are promising next-generation battery technologies with high energy densities. However, lithium dendrite growth during charge/discharge results in severe safety issues and poor cycling performance, which hinders their wide applications. The rational design and application of functional polymer materials in LMBs are of crucial importance to boost their electrochemical performances, especially the cycling stability.
View Article and Find Full Text PDFLithium-metal batteries have attracted extensive research attention because of their high energy densities. Developing appropriate electrolytes compatible with lithium-metal anodes is of great significance to facilitate their practical application. Currently used electrolytes still face challenges of high production costs and unsatisfactory Coulombic efficiencies of lithium plating/stripping.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2022
Heterointerface design is an effective strategy to improve the effective absorption bandwidth in electromagnetic wave EMW absorbing materials. In this paper, honeycomb-like Fe-doped tremella carbide composites (FCT) with a large number of heterogeneous interfaces were obtained by in-situ construction of multiphase composite particles (FeC, FeO, and a-Fe) during the carbonization process. The effects of Fe doping on the phase, structure, morphology, and absorption properties of FCT were investigated.
View Article and Find Full Text PDFInterfacial polarization and geometrical morphology play a significant role in the attenuation of electromagnetic (EM) wave. Herein, the two-dimensional (2D)/2D heterojunction with flower-like geometrical morphology is proposed and produced, which may simultaneously provide a large contact area for achieving strong interfacial polarization and activates more sites for the possible multiple EM wave reflection and scattering. By adopting a simple two-step hydrothermal method, MoSe/MoSand MoS/MoSe inner and outer-interchangeable heterojunctions consisting of 2D MoSe and MoS nanosheets with flower-like geometrical morphology were successfully synthesized.
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