Improving the high-temperature performance of polymer dielectrics is critical for the development of advanced electrical systems. The deterioration of the capacitive performance of polymer dielectrics at high electric fields and elevated temperatures is attributable to the exponentially increased conduction loss. Herein, a synergistic strategy of molecular trap and aggregation structure optimization is developed to suppress the conduction loss of polymer dielectrics.
View Article and Find Full Text PDFElectrostatic capacitors, with the advantages of high-power density, fast charging-discharging, and outstanding cyclic stability, have become important energy storage devices for modern power electronics. However, the insulation performance of the dielectrics in capacitors will significantly deteriorate under the conditions of high temperatures and electric fields, resulting in limited capacitive performance. In this paper, we report a method to improve the high-temperature energy storage performance of a polymer dielectric for capacitors by incorporating an extremely low loading of 0.
View Article and Find Full Text PDFConventional methods for fabricating multilayered ceramic membranes with ion conducting dense thin layers are often cumbersome, costly, and limited by poor adhesion between layers. Inspired by the architectural structure of the rooted grasses in soil, here, we report an interface-reaction-induced reassembly approach for the direct fabrication of Ce Gd O (CGO) thin layers rooted in the parent multilayered ceramic membranes by only one firing step. The CGO dense layers are very thin, and adhered strongly to the parent support layer, ensuring low ionic transport resistance and structural integrity of the multilayered membranes.
View Article and Find Full Text PDFAdv Sci (Weinh)
October 2022
Polymer dielectrics are attracting increasing attention for electrical energy storage owing to their advantages of mechanical flexibility, corrosion resistance, facile processability, light weight, great reliability, and high operating voltages. However, the dielectric constants of most dielectric polymers are less than 10, which results in low energy densities and limits their applications in electrostatic capacitors for advanced electronics and electrical power systems. Therefore, intensive efforts have been placed on the development of high-energy-density polymer dielectrics.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2021
Using oxygen permeable membranes (OPMs) to upgrade low-purity hydrogen is a promising concept for high-purity H production. At high temperatures, water dissociates into hydrogen and oxygen. The oxygen permeates through OPM and oxidizes hydrogen in a waste stream on the other side of the membrane.
View Article and Find Full Text PDFCoupling of two oxygen-involved reactions at the opposite sides of an oxygen transport membrane (OTM) has demonstrated great potential for process intensification. However, the current cobalt- or iron-containing OTMs suffer from poor reduction tolerance, which are incompetent for membrane reactor working in low oxygen partial pressure (pO). Here, we report for the first time a both Co- and Fe-free SrMgZrTiO (SMZ-Ti) membrane that exhibits both superior reduction tolerance for 100 h in 20 vol.
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