In the current context of complexity between climate change, environmental sustainability, resource scarcity, and geopolitical aspects of energy resources, a polygenerative system with a circular approach is considered to generate energy (thermal, electrical, and fuel), contributing to the control of CO emissions. A plant for the multiple productions of electrical energy, thermal heat, DME, syngas, and methanol is discussed and analyzed, integrating a chemical cycle for CO/HO splitting driven using concentrated solar energy and biomethane. Two-stage chemical looping is the central part of the plant, operating with the CeO/CeO redox couple and operating at 1.
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