We introduce a compressive sensing based approach for single pixel hyperspectral chemical imaging in a broad spectral range in the near-infrared. Fully integrated MEMS based Fabry-Pérot tunable filter spectrometers and a digital micro-mirror device were employed to achieve spectral and spatial resolution, respectively. The available spectral range from 1500 to 2200 nm covers molecular overtone vibrations enabling chemical identification.
View Article and Find Full Text PDFChemical mapping was demonstrated with a mid-infrared (MIR) microspectroscopy setup based on a supercontinuum source (SC) emitting in the spectral range from 1.55 to 4.5 µm and a MEMS-based Fabry-Pérot filter spectrometer.
View Article and Find Full Text PDFIn this Letter, we theoretically describe photoacoustic signal generation of molecules, for which triplet relaxation can be neglected, by considering the excited state lifetime, the fluorescence quantum yield, and the fast vibrational relaxation. We show that the phase response of the photoacoustic signal can be exploited to determine the excited state lifetime of dark molecules. For fluorescent molecules, the phase response can be used to determine the fluorescence quantum yield directly without the need of reference samples.
View Article and Find Full Text PDFMid-infrared (MIR) supercontinuum (SC) lasers are an attractive new option in the field of IR spectroscopy, especially for standoff detection. Supercontinuum radiation unites high brightness, high spatial coherence, and broadband spectral coverage, thereby surpassing thermal IR sources and challenging quantum cascade lasers. The employed SC source operates in the spectral region of 1.
View Article and Find Full Text PDFWe report on simultaneous frequency domain optical-resolution photoacoustic and fluorescence microscopy with sub-µm lateral resolution. With the help of a blood smear, we show that photoacoustic and fluorescence images provide complementary information. Furthermore, we compare theoretically predicted signal-to-noise ratios of sinusoidal modulation in frequency domain with pulsed excitation in time domain.
View Article and Find Full Text PDFWe demonstrate non-contact remote photoacoustic spectroscopy in the mid-infrared region. A room-temperature-operated pulsed external-cavity quantum cascade laser is used to excite photoacoustic waves within a semitransparent sample. The ultrasonic waves are detected remotely on the opposite side of the sample using a fiber-optic Mach-Zehnder interferometer, thereby avoiding problems associated with acoustic attenuation in air.
View Article and Find Full Text PDFWe investigate the optical properties of ordered Ge quantum dots (QDs) by means of micro-photoluminescence spectroscopy (PL). These were grown on pit-patterned Si(001) substrates with a wide range of pit-periods and thus inter QD-distances (425-3400 nm). By exploiting almost arbitrary inter-QD distances achievable in this way we are able to choose the number of QDs that contribute to the PL emission in a range between 70 and less than three QDs.
View Article and Find Full Text PDFFor a systematic approach to improve the reliability and the white light quality of phosphor converted light-emitting diodes (LEDs) it is imperative to gain a better understanding of the individual parameters that affect color temperature constancy and maintenance. By means of a combined optical and thermal simulation procedure, in this contribution we give a comprehensive discussion on the impact of different current driving schemes on the thermal load of the color conversion elements (CCEs) of phosphor converted LEDs. We show that on the one hand a decreasing duty cycle under pulse width modulation driving conditions may cause a notable temperature variation and on the other hand also effects due to the non-linearity between the blue radiant flux and the current have to be considered for the thermal load of the CCEs.
View Article and Find Full Text PDFIn the present paper we demonstrate the possibility to image dyed solids, i.e. Rhodamine B dyed polyethylene spheres, by means of two-photon absorption-induced photoacoustic scanning microscopy.
View Article and Find Full Text PDFBeam profiles are commonly measured with complementary metal oxide semiconductors (CMOS) or charge coupled devices (CCD). The devices are fast and reliable but expensive. By making use of the fact that the Bayer-filter in commercial webcams is transparent in the near infra-red (>800 nm) and their CCD chips are sensitive up to about 1100 nm, we demonstrate a cheap and simple way to measure laser beam profiles with a resolution down to around ±1 μm, which is close to the resolution of the knife-edge technique.
View Article and Find Full Text PDFWe identify the most important parameters for the growth of ordered SiGe islands on pit-patterned Si(001) substrates. From a multi-dimensional parameter space we link individual contributions to isolate their influence on ordered island growth. This includes the influences of: the pit size, pit depth and pit period on the Si buffer layer and subsequent Ge growth; the pit sidewall inclination on Ge island growth; the amount of Ge on island morphologies as well as the influences of the pit-size homogeneity, the pit period, the Ge growth temperature and rate on island formation.
View Article and Find Full Text PDFResearch into the integration of optical interconnects in printed circuit boards (PCBs) is rapidly gaining interest due to the increase in data transfer speeds now required along with the need for miniaturized devices with increased complexity and functionality. We present a method that involves embedding optoelectronic components in a polymeric material and fabricating optical waveguides in one step. A silanol-terminated polysiloxane cross-linked with an acryloxy functional silane is utilized as a matrix material into which the 3D optical waveguides are inscribed by two-photon-induced polymerization.
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