Plastic recycling rates are still low in the United States (U.S.), with less than 10% of municipal solid waste (MSW) plastic being recycled.
View Article and Find Full Text PDFPolypropylene (PP) is one of the most abundant plastics used due to its low price, moldability, temperature and chemical resistance, and outstanding mechanical properties. Consequently, waste from plastic materials is anticipated to rapidly increase with continually increasing demand. When addressing the global problem of solid waste generation, post-consumer recycled materials are encouraged for use in new consumer and industrial products.
View Article and Find Full Text PDFVarious testing methods and techniques have been used to identify and quantify per- and polyfluoroalkyl substances (PFAS) in food packaging. A common indirect measurement of PFAS is total fluorine (TF) and total organic fluorine (TOF). These methods are critical in rapidly screening food packaging materials for the >9000 PFAS and are often globally used for regulatory limits.
View Article and Find Full Text PDFThere has been a tremendous increase in demand for virgin and postconsumer recycled (PCR) polymers due to their wide range of chemical and physical characteristics. Despite the numerous potential benefits of using a data-driven approach to polymer design, major hurdles exist in the development of polymer informatics due to the complicated hierarchical polymer structures. In this review, a brief introduction on virgin polymer structure, PCR polymers, compatibilization of polymers to be recycled, and their characterization using sensor array technologies as well as factors affecting the polymer properties are provided.
View Article and Find Full Text PDFAs the demand for plastics only increases, new methods are required to economically and sustainably increase plastic usage without landfill and environmental accumulation. In addition, the use of biofillers is encouraged as a way to reduce the cost of the final resin by incorporating agricultural and industrial waste by-products, such as rice hulls and coffee chaff to further reduce waste being sent to landfills. Crystalline poly(ethylene terephthalate) (CPET) is a resin commonly used for microwave and ovenable food packaging containers that have not been fully explored for recycling.
View Article and Find Full Text PDFThis paper compiles polymer characterization data collected from polyethylene (PE) blends composed of different densities (low-density, LDPE, linear low-density, LLDPE, medium-density, MDPE, and high-density, HDPE) and post-consumer recycled polyethylene (PCRPE), as presented by Cecon et al. (2021). The data were collected from injection molded samples submitted to several physical, thermal, and mechanical characterization techniques, including density, melt flow rate (MFR), thermogravimetric analysis, mechanical testing, and Fourier transform infrared spectroscopy.
View Article and Find Full Text PDFIntegr Environ Assess Manag
January 2021
Food safety authorities and the food industry are focused on uses of perfluoroalkyl substances (PFAS) in various food-contact packaging applications. Not widely known until recently, certain PFAS occur in paper-based packaging materials typically at parts-per-billion to parts-per-million concentrations. These substances are nonintentionally added substances (NIAS) and are attributed to residues from recycled fiber and paperboard used in the manufacture of new food packaging products.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2019
A waterborne, UV-blocking, and visually transparent nanocomposite coating was formulated with ZnO nanoparticles and 2-hydroxyethyl cellulose (HEC). The coating is highly effective (<5% UV and ∼65% visible transmittance), and the film thickness (0.2-2.
View Article and Find Full Text PDFProtective coatings are often erroneously thought of as perfect environmental barriers for metal substrates; however, a host of corrosion inducing environmental contaminants permeate through defect-free coatings. Carbon nanotubes are high aspect ratio nanofillers with unique mechanical, electrical, and polymer interaction properties with well-established yet, for practical reasons, often unrealized potential. The research objective was to quantify and understand the influential effects and relationships between low concentration levels of multiwall carbon nanotubes (MWCNT) dispersed into epoxy-amine matrix materials and the different water hydrogen bonding interactions on corrosion rates of steel substrates.
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