Mercury bio-concentration by Puffballs (Lycoperdon perlatum) and evaluation of dietary intake risks.

In the present study, Hg bioconcentration by Puffball (Lycoperdon perlatum) mushroom was investigated. Total Hg content of fruiting bodies and topsoil (0-10 cm layer) were determined by cold-vapour atomic absorption spectroscopy. For ten geographically distant sampling sites of Poland, Hg ranged from 0.

Concentrations and bioconcentration factors of minerals in yellow-cracking Bolete (Xerocomus subtomentosus) mushroom collected in Noteć Forest, Poland.

Unlabelled: Yellow-cracking Bolete (Xerocomus subtomentosus) mushrooms and soil were collected from Noteć Forest--a large forested enclave in western part of Poland. Mercury was determined by cold vapour atomic absorption spectroscopy and the other elements by inductively coupled plasma atomic emission spectroscopy. K, P, and Mg were particularly abundant, with mean values of 46000, 8400, and 1100 mg/kg dry weight (dw) in caps followed by Na, Rb, Zn, and Ca with mean concentrations of 580, 350, 200, and 170 mg/kg dw, respectively.

Mercury in Yellow-cracking Boletes Xerocomus subtomentosus mushrooms and soils from spatially diverse sites: assessment of bioconcentration potential by species and human intake.

This study investigated the Hg concentrations in Yellow-cracking Boletes Xerocomus subtomentosus mushrooms and beneath soils collected from the wild at twelve sites across Poland. This mushroom species has some potential to bioconcentrate Hg in the fruiting bodies, and the amount of Hg sequestered, depending on geographical location, can pose health risk to consumers. The values of Hg bioconcentration factor (BCF) varied for the sites between 0.

Mercury in fruiting bodies of dark honey fungus (Armillaria solidipes) and beneath substratum soils collected from spatially distant areas.

Background: This paper reports data on bioconcentration potential and baseline mercury concentrations of fruiting bodies of dark honey fungus (Armillaria solidipes) Peck and soil substrate layer (0-10 cm) from 12 spatially distant sites across Poland. Mercury content of caps, stipes and soil samples were determined using validated analytical procedure including cold-vapor atomic absorption spectroscopy after thermal decomposition of the sample matrix and further amalgamation and desorption of mercury from gold wool.

Results: Mean mercury concentrations ranged from 20 ± 8 to 300 ± 70 ng g(-1) dry weight (dw) in caps, from 20 ± 6 to 160 ± 40 ng g(-1) dw in stipes, and in underlying soil were from 20 ± 2 to 100 ± 130 ng g(-1) dw.

Occurrence and accumulation of mercury in two species of wild grown Pleurotus mushrooms from Southeastern Nigeria.

The aim of this study was to evaluate the degree of contamination and intake rates, as well as the risk of Hg contained in two wild species of Pleurotus mushrooms--Oyster Mushroom (P. ostreatus) and King Tuber Mushroom (P. tuber-regium)--which are widely consumed in southeastern Nigeria; and to also assess their potential to accumulate Hg.

Mercury in Red Aspen Boletes (Leccinum aurantiacum) mushrooms and the soils.

This communication reports data on the mercury contents of Red Aspen Boletes (Leccinum aurantiacum) mushrooms and the forest soils substrate layer (0-10 cm) underneath the fruit bodies collected from nine spatially distant sites across Poland. Total Hg concentration in soil substrate in seven of the nine sites studied varied from 0.0078 ± 0.

Comparison of two acid extraction methods for determination of minerals in soils beneath to Larch Bolete (Suillus grevillei) and aimed to estimate minerals sequestration potential in fruiting bodies.

In this study a two simple and one-step extraction methods were compared for the evaluation of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn accessibility in the soils to Larch Boletes (Suillus grevillei) mushrooms. Determination of chemical elements examined was by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The extractable amounts of minerals from soil when analyzed by both extraction methods (25 % nitric acid "v/v" and 0.

Mercury in Russula mushrooms: Bioconcentration by Yellow-ocher Brittle Gills Russula ochroleuca.

The purpose of this study was to examine the contamination and bioconcentration potential of mercury (Hg) in Yellow-ocher Brittle Gills known also as Yellow-ocher Brittle Gill or Common Russula (Russula ochroleuca) mushroom. Matured fruiting bodies of this fungus and soil samples were collected at ten spatially distant unpolluted sites in the northern part of Poland in 2004-2008. Total Hg content of fruiting bodies and soil were determined by cold-vapour atomic absorption spectroscopy (CV-AAS).

Metals in edible fish from Vistula River and Dead Vistula River channel, Baltic Sea.

Metals including Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Sr and Zn were determined in muscle tissue of 12 fish species by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and cold vapour-atomic absorption spectroscopy (CV-AAS). Fish were collected from Vistula River at lower course and Dead Vistula River channel in south of Baltic Sea in Poland. The fish species examined include Round Goby (Neogobius melanostomus), Crucian Carp (Carassius carassius), Bull-rout (Myoxocephalus scorpius), Tench (Tinca tinca), Bream (Abramis brama), Burbot (Lota lot), Perch (Perca perca), Roach (Rutilus rutilus), Silver Carp (Hypophthalmichthys molitrix), Pikeperch (Stizostediun lucioperca), Brown salmon (Salmo trutta m.

Mercury in European Blushers, Amanita rubescens, mushrooms and topsoils: bioconcentration potential and intake assessment.

Total mercury content has been determined in fruiting bodies of European Blushers and topsoils collected from 11 sites across Poland in 2006-2008. Mercury analysis was carried out using a validated analytical method and cold-vapour atomic absorption (CV-AAS). The European Blusher effectively accumulated mercury in fruiting bodies.

Levels and sources of planar and non-planar PCBs in pine needles across Poland.

Under a small project, one-year-old Scots Pine needles collected from 25 spatially distant sites were examined in monitoring the extent of environmental diffusion and possible sources of polychlorinated biphenyls (PCBs) in ambient air, their depositions and uptake by plants in Poland. The congener-specific determination of planar and non-planar chlorobiphenyls was achieved by isotope dilution HRGC-HRMS method after a highly refined extraction on multi-layer column of silica gel and alumina layer and clean-up, and fractionations, followed by Hypercarb-HPLC and PYE-HPLC sub-fractionation steps. Contents of 117 chlorobiphenyls determined in pine needles varied for the 25 sites studied and is between 2.

Determination of perfluorinated alkylated substances in sediments and sediment core from the Gulf of Gdańsk, Baltic Sea.

Perfluorinated alkylated substances (PFAS) have been determined in surface sediments and sediment core from Gulf of Gdańsk, Baltic Sea. Perfluorooctanesulphonate (PFOS), perfluorohexanesulphonate (PFHxS), perfluorodecanoate (PFDA), perfluoronanoate (PFNA), perfluorooctanoate (PFOA), perfluoroheptanoate (PFHpA), perfluoroundecanote (PFUnDA), perfluorododecanoate (PFDoDA) and perfluorohexanoate (PFHxA) were quantified after isotopic dilution ((13)C(4) PFOS and (13)C(4) PFOA), liquid-liquid extractions by methanol and acetonitrile, cleanup by Envi-Carb, OasisWAX and Envi-Carb and final measurement by HPLC-MS/MS. PFOS, PFHxS, PFUnDA, PFDA, PFNA and PFOA were found in Baltic Sea sediments in concentrations exceeding the method limit of quantification (LOQ) of 2 pg/g.

Temporal variability in 20 chemical elements content of Parasol Mushroom (Macrolepiota procera) collected from two sites over a few years.

Mature specimens of Parasol Mushroom were collected annually in the outskirts of the Siemiany (2000-2003) and Rafa (2001-2003) sites in the northern part of Poland to examine temporal variations and similarities in the composition of 20 chemical elements. Analysis was done under the same condition and using well-validated analytical methods. Elements were determined by inductively coupled plasma-atomic emission spectroscopy and cold vapour-atomic absorption spectroscopy (Hg).

Profile of trace elements in Parasol Mushroom (Macrolepiota procera) from Tucholskie Forest.

The aim of this study was to determine 19 elements contents and bioconcentration potential in fruiting bodies of Parasol Mushroom (Macrolepiota procera) collected from the Tucholskie Forest complex in Poland. Also discussed were Cd, Pb and Hg contents of edible caps in relation to the current regulatory standards. K, P and Mg were particularly abundant in caps and stipes, median values were 38-49, 13, and 1.

Multivariate analysis of mineral constituents of edible Parasol Mushroom (Macrolepiota procera) and soils beneath fruiting bodies collected from Northern Poland.

Caps and stipes of 141 fruiting bodies of Parasol Mushroom (Macrolepiota procera) and surface layer of soils collected from 11 spatially distant and background (pristine) areas in Northern Poland were analyzed for Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr, and Zn by inductively coupled plasma optical emission spectroscopy and cold vapor atomic absorption spectroscopy. In terms of bioconcentration and bioexclusion concept, K, Ag, Cu, Rb, and P were highly bioconcentrated in caps, and their bioconcentration factor values varied for the 11 sites between 120 and 500-67-420, 70-220, 10-170, and 45-100, respectively. Cd, Zn, Mg, and Na showed bioconcentration factors (BCFs) between 3.

Variations in metal levels accumulated in Poison Pax (Paxillus involutus) mushroom collected at one site over four years.

K, Ca, Mg, Na, Zn, Al, Fe, Mn, Rb, Cu, Sr, Ag, Ba, Pb, Ni, Cd, Co, Cr and Hg content have been examined in caps and stipes of mature fruiting bodies of Poison Pax (Paxillus involutus) collected from the same site over 4 years in 1999-2002. Cluster analysis (CA) did indicate on a different composition of these mineral constituents in fruiting bodies that emerged in 1999 and 2000, when compared to 2001 and 2002. In light of principal component analysis (PCA), the metals differentiating these two biannual sets of fruiting bodies were Mn (greatest load to PC1) together with Ca, Fe, Al, Cu, Cd and Hg; Ni (greatest load to PC2) together with Zn, Sr, Ba, Pb and Co, and Ag (greatest load to PC3) together with Na.

The determination of mercury in mushrooms by CV-AAS and ICP-AES techniques.

This research presents an example of an excellent applied study on analytical problems due to hazardous mercury determination in environmental materials and validity of published results on content of this element in wild growing mushrooms. The total mercury content has been analyzed in a several species of wild-grown mushrooms and some herbal origin certified reference materials, using two analytical methods. One method was commonly known and well validated the cold-vapour atomic absorption spectroscopy (CV-AAS) after a direct sample pyrolysis coupled to the gold wool trap, which was a reference method.

Survey on composition and bioconcentration potential of 12 metallic elements in King Bolete (Boletus edulis) mushroom that emerged at 11 spatially distant sites.

This paper provides data on baseline concentrations, interrelationships and bioconcentration potential of 12 metallic elements by King Bolete collected from 11 spatially distant sites across Poland. There are significant differences in concentrations of metals (Al, Ba, Ca, Cd, Cu, Fe, K, Mg, Mn, Na, Sr, Zn) and their bioconcentration potential in King Bolete Boletus edulis at 11 spatially distant sites surveyed across Poland. These have resulted from significant geographical differences in trace metal concentrations in a layer (0-10 cm) of organic and mineral soil underneath to fruiting bodies and possible local bioavailabilities of macro- (Ca, K, Mg, Na) and trace metals (Al, Ba, Cd, Cu, Fe, Mn, Sr, Zn) to King Bolete.

Selenium and 17 other largely essential and toxic metals in muscle and organ meats of Red Deer (Cervus elaphus)--consequences to human health.

Concentrations, composition and interrelationships of selenium and metallic elements (Ag, Ba, Cd, Co, Cr, Cs, Cu, Ga, Mn, Mo, Pb, Rb, Sb, Sr, Tl, V and Zn) have been examined in muscle and organ meats of Red Deer hunted in Poland. The analytical data obtained were also discussed in terms of Se supplementation and deficit to Deer as well as the benefits and risk to humans associated with the essential and toxic metals intake resulting from consumption of Deer meat and products. These elements were determined in 20 adult animals of both sexes that were obtained in the 2000/2001 hunting season from Warmia and Mazury in the north-eastern part of Poland.

[Mercury content of common chanterelle (Cantharellus cibarius) from four spatially distant sites in Poland].

Mercury content have been determined in 59 composite samples (from 3 to 6 fruit bodies per sample) of Common Chanterelle collected near the towns of Hel, Ciechocinek and Zakopane, and in Bialowieza Forest. Total mercury have been determined by cold-vapor atomic absorption spectrometry (CV-AAS) using validated analytical method with amalgamation on golden wool and further desorption of mercury (analyzer MA-2000). Mercury content of the dried fruit bodies of Common Chanterelle depending on the site ranged from 29 for the outskirts of the Ciechocinek to 46 ng/g for the area of Białowieska Forest.