Laboratory studies of the diffusive transport of 137Cs and 60Co through potential waste repository soils.

Tests using reconstituted samples have been performed to assess the diffusive transport of (137)Cs and (60)Co through natural regolith materials from a region in South Australia being considered for a radioactive waste repository. A double diffusion cell apparatus made of polycarbonate resin was developed to estimate the effective diffusion (D(e)) and sorption coefficients (K(d)) that allowed large withdrawals from the source and collector cells and has enabled tests with low concentrations of radioactivity. An alternative to porous stainless steel filter plates has also been used to reduce uncertainty in test interpretation.

The effect of sulfate-reducing bacteria on adsorption of 137Cs by soils from arid and tropical regions.

Soils from different climatic regions of Australia were studied to determine their adsorption of (137)Cs, and the effect of microbial sulfate reduction on this adsorption. The soils consisted of a surface and regolith samples from the site of a proposed low and intermediate level radioactive waste repository in arid South Australia, and two red earth loam soils from an experimental plot in the tropical Northern Territory. The process of bacterial sulfate reduction substantially decreased the adsorption of (137)Cs to the arid and tropical soils, although extended incubation resulted in greater adsorption to the regolith sample.