Comprehensive review of dynamical simulation models of packed-bed systems for thermal energy storage applications in renewable power production.

The need for large-scale energy storage in the context of renewable electricity production worldwide is evident. Among the various energy storage methods, thermal energy storage stands out. It is independent of geographical location, allows high storage capacities, does not require scarce materials, and is cheaper than its direct competitors.

Thermodynamic performance of coupled enzymatic reactions: A chemical kinetics model for analyzing cotransporters, ion pumps, and ATP synthases.

Previous research has suggested that molecular energy converters such as ATP synthases, ion pumps, and cotransporters operate via spatially separate pathways for free energy donor and acceptor reactions linked by a protein molecule. We present a chemical kinetics model based on these works, with the basic assumption that all molecular energy converters can be thought of as linked enzymatic reactions, one running downhill the chemical potential gradient and driving the other uphill. To develop the model we first look at how an enzyme process can be forced to go backwards using a basic kinetic model.

Success versus failure: Efficient heat devices in thermodynamics.

Classical equilibrium thermodynamics provides, in a general way, upper Carnot bounds for the performance of energy converters. Nevertheless, to suggest lower bounds is a much more subtle issue, especially when they are related to a definition of convenience. Here, this issue is investigated in a unified way for heat engines, refrigerators, and heat pumps.

Thermodynamic Performance of a Brayton Pumped Heat Energy Storage System: Influence of Internal and External Irreversibilities.

A model for a pumped thermal energy storage system is presented. It is based on a Brayton cycle working successively as a heat pump and a heat engine. All the main irreversibility sources expected in real plants are considered: external losses arising from the heat transfer between the working fluid and the thermal reservoirs, internal losses coming from pressure decays, and losses in the turbomachinery.

Optimization, Stability, and Entropy in Endoreversible Heat Engines.

The stability of endoreversible heat engines has been extensively studied in the literature. In this paper, an alternative dynamic equations system was obtained by using restitution forces that bring the system back to the stationary state. The departing point is the assumption that the system has a stationary fixed point, along with a Taylor expansion in the first order of the input/output heat fluxes, without further specifications regarding the properties of the working fluid or the heat device specifications.

Thermodynamic optimization subsumed in stability phenomena.

In the present paper the possibility of an energetic self-optimization as a consequence of thermodynamic stability is addressed. This feature is analyzed in a low dissipation refrigerator working in an optimized trade-off regime (the so-called Omega function). The relaxation after a perturbation around the stable point indicates that stability is linked to trajectories in which the thermodynamic performance is improved.

Energetic Self-Optimization Induced by Stability in Low-Dissipation Heat Engines.

The local stability of a weakly dissipative heat engine is analyzed and linked to an energetic multi-objective optimization perspective. This constitutes a novel issue in the unified study of cyclic energy converters, opening the perspective to the possibility that stability favors self-optimization of thermodynamic quantities including efficiency, power and entropy generation. To this end, a dynamics simulating the restitution forces, which mimics a harmonic potential, bringing the system back to the steady state is analyzed.

Optimization induced by stability and the role of limited control near a steady state.

A relationship between stability and self-optimization is found for weakly dissipative heat devices. The effect of limited control on operation variables around an steady state is such that, after instabilities, the paths toward relaxation are given by trajectories stemming from restitution forces which improve the system thermodynamic performance (power output, efficiency, and entropy generation). Statistics over random trajectories for many cycles shows this behavior as well.

Optimization and Stability of Heat Engines: The Role of Entropy Evolution.

Local stability of maximum power and maximum compromise (Omega) operation regimes dynamic evolution for a low-dissipation heat engine is analyzed. The thermodynamic behavior of trajectories to the stationary state, after perturbing the operation regime, display a trade-off between stability, entropy production, efficiency and power output. This allows considering stability and optimization as connected pieces of a single phenomenon.

Ecological efficiency of finite-time thermodynamics: A molecular dynamics study.

We present a molecular dynamics simulation of a two-dimensional Carnot engine. The optimization of this engine is achieved through the velocity of the piston, allowing not only the optimization of power output but also some other figures of merit involving entropy production. The maximum power and maximum ecological efficiencies are computed.

Entropy generation and unified optimization of Carnot-like and low-dissipation refrigerators.

The connection between Carnot-like and low-dissipation refrigerators is proposed by means of their entropy generation and the optimization of two unified, compromise-based figures of merit. Their optimization shows that only a limited set of heat transfer laws in the Carnot-like model are compatible with the results stemming from the low-dissipation approximation, even though there is an agreement of the related physical spaces of variables. A comparison between two operation regimes and relations among entropy generation, efficiency, cooling power.

Local-stability analysis of a low-dissipation heat engine working at maximum power output.

In this paper we address the stability of a low-dissipation (LD) heat engine (HE) under maximum power conditions. The LD system dynamics are analyzed in terms of the contact times between the engine and the external heat reservoirs, which determine the amount of heat exchanged by the system. We study two different scenarios that secure the existence of a single stable steady state.

From maximum power to a trade-off optimization of low-dissipation heat engines: Influence of control parameters and the role of entropy generation.

For a low-dissipation heat engine model we present the role of the partial contact times and the total operational time as control parameters to switch from maximum power state to maximum Ω trade-off state. The symmetry of the dissipation coefficients may be used in the design of the heat engine to offer, in such switching, a suitable compromise between efficiency gain, power losses, and entropy change. Bounds for entropy production, efficiency, and power output are presented for transitions between both regimes.

Restrictions on linear heat capacities from Joule-Brayton maximum-work cycle efficiency.

This paper discusses the possibility of using the Joule-Brayton cycle to determine the accessible value range for the coefficients a and b of the heat capacity at constant pressure C(p), expressed as C(p) = a + bT (with T the absolute temperature) by using the Carnot theorem. This is made for several gases which operate as the working fluids. Moreover, the landmark role of the Curzon-Ahlborn efficiency for this type of cycle is established.

Connection between maximum-work and maximum-power thermal cycles.

A new connection between maximum-power Curzon-Ahlborn thermal cycles and maximum-work reversible cycles is proposed. This linkage is built through a mapping between the exponents of a class of heat transfer laws and the exponents of a family of heat capacities depending on temperature. This connection leads to the recovery of known results and to a wide and interesting set of results for a class of thermal cycles.

Evaluation of antihypoxemic maneuvers before tracheal aspiration in mechanically ventilated newborns.

Periodical tracheal aspiration in mechanically ventilated patients is necessary to remove mucus from the airways. In children and adults, this procedure causes transient hypoxemia, which may be prevented by hyperoxia and/or hyperventilation. These findings, however, have not been sufficiently assessed in newborn infants.