Surface Morphology, Compressive Behavior, and Energy Absorption of Graded Triply Periodic Minimal Surface 316L Steel Cellular Structures Fabricated by Laser Powder Bed Fusion.

Laser powder bed fusion (LPBF) is an emerging technique for the fabrication of triply periodic minimal surface (TPMS) structures in metals. In this work, different TPMS structures such as Diamond, Gyroid, Primitive, Neovius, and Fisher-Koch S with graded relative densities are fabricated from 316L steel using LPBF. The graded TPMS samples are subjected to sandblasting to improve the surface finish before mechanical testing.

Nanoshaping of glass forming metallic liquids by stretching: evading lithography.

Lithography-free nanomanufacturing by elongation and fracture of glass forming metallic liquid is presented. The viscous metallic liquid confined in a cavity is laterally downsized to nanoscale by stretching. The extent of size-reduction can be controlled by tuning the active volume of liquid and the viscous and capillary stresses.

High-throughput drawing and testing of metallic glass nanostructures.

Thermoplastic embossing of metallic glasses promises direct imprinting of metal nanostructures using templates. However, embossing high-aspect-ratio nanostructures faces unworkable flow resistance due to friction and non-wetting conditions at the template interface. Herein, we show that these inherent challenges of embossing can be reversed by thermoplastic drawing using templates.

Shape-Controlled Metal-Metal and Metal-Polymer Janus Structures by Thermoplastic Embossing.

We report the fabrication of metal-metal and metal-polymer Janus structures by embossing of thermoplastic metallic glasses and polymers. Hybrid structures with controllable shapes and interfaces are synthesized by template-assisted embossing. Different manufacturing strategies such as co-embossing and additive embossing are demonstrated for joining the materials with diverse compositions and functionalities.

Thermomechanical Behavior of Molded Metallic Glass Nanowires.

Metallic glasses are disordered materials that offer the unique ability to perform thermoplastic forming operations at low thermal budget while preserving excellent mechanical properties such as high strength, large elastic strain limits, and wear resistance owing to the metallic nature of bonding and lack of internal defects. Interest in molding micro- and nanoscale metallic glass objects is driven by the promise of robust and high performance micro- and nanoelectromechanical systems and miniature energy conversion devices. Yet accurate and efficient processing of these materials hinges on a robust understanding of their thermomechanical behavior.

Functionalization of metallic glasses through hierarchical patterning.

Surface engineering over multiple length scales is critical for electronics, photonics, and enabling multifunctionality in synthetic materials. Here, we demonstrate a sequential embossing technique for building multi-tier patterns in metals by controlling the size-dependent thermoplastic forming of metallic glasses. Sub-100 nm to millimeter sized features are sculpted sequentially to allow an exquisite control of surface properties.

Metallic glass nanostructures: fabrication, properties, and applications.

Remarkable progress has been made in fabrication and characterization of metal nanostructures because of their crucial role in energy conversion, nanophotonics, nanoelectronics, and biodiagnostics. Less emphasis has been placed on the synthesis of nanostructures from metallic alloys, which are better suited than elemental metals for certain applications such as fuel-cell catalysts. The main challenges in fabrication of alloy nanostructures are controlling their chemical stoichiometry, crystal structures, and shapes because of anisotropic nucleation and growth rates.

Critical fictive temperature for plasticity in metallic glasses.

A long-sought goal in metallic glasses is to impart ductility without conceding their strength and elastic limit. The rational design of tough metallic glasses, however, remains challenging because of the inability of existing theories to capture the correlation between plasticity, composition and processing for a wide range of glass-forming alloys. Here we propose a phenomenological criterion based on a critical fictive temperature, T(fc), which can rationalize the effect of composition, cooling rate and annealing on room-temperature plasticity of metallic glasses.

Controllable nanoimprinting of metallic glasses: effect of pressure and interfacial properties.

The quantitative model proposed here for nanoimprinting by thermoplastic compression molding is focused on bulk metallic glasses (BMGs), but it is also applicable to polymers and other thermoplastic materials. In our model the flow and pressure fields are evaluated using the lubrication theory, and the effect of molding pressure, BMG viscosity, and capillary pressure on the spatial distribution of nanoimprinted features is determined. For platinum-based BMG the theory that takes into account capillary pressure but no other surface stresses agrees very well with experimental results.

Bulk metallic glass nanowire architecture for electrochemical applications.

Electrochemical devices have the potential to pose powerful solutions in addressing rising energy demands and counteracting environmental problems. However, currently, these devices suffer from meager performance due to poor efficiency and durability of the catalysts. These suboptimal characteristics have hampered widespread commercialization.

Bulk metallic glass: the smaller the better.

Bulk metallic glasses (BMGs) are strong, highly elastic, and resistant to wear but still find limited utility due to their macroscopic brittle nature, high costs, and difficulty of processing, particularly when complex shapes are desired. These drawbacks can be mitigated when BMGs are used in miniature parts (< 1 cm), an application which takes advantage of BMGs' enhanced plasticity at small length scales as well the insignificant material cost associated with such parts. As an alternative to traditional metal processing techniques, thermoplastic forming (TPF)-based microfabrication methods have been developed which can process some BMGs like plastics.

Nanomoulding with amorphous metals.

Nanoimprinting promises low-cost fabrication of micro- and nano-devices by embossing features from a hard mould onto thermoplastic materials, typically polymers with low glass transition temperature. The success and proliferation of such methods critically rely on the manufacturing of robust and durable master moulds. Silicon-based moulds are brittle and have limited longevity.