Glassy dynamics of polymers confined to nanoporous glasses revealed by relaxational and scattering experiments.

The glassy dynamics of poly(propylene glycol) (PPG) and poly(dimethyl siloxane) (PDMS) confined to a nanoporous host system revealed by dielectric spectroscopy, temperature-modulated DSC and neutron scattering is compared. For both systems the relaxation rates estimated from dielectric spectroscopy and temperature-modulated DSC agree quantitatively indicating that both experiments sense the glass transition. For PPG the segmental dynamics is determined by a counterbalance of adsorption and confinement effect.

Protein adsorption, lymphocyte adhesion and platelet adhesion/activation on polyurethane ureas is related to hard segment content and composition.

Segmented polyurethane ureas with different hard segment content and composition were synthesized using 4,4'-diphenylmethane diisocyanate and polytetramethylene glycols. Using polyols with different molecular weights, it was possible to synthesize polyurethane ureas with either: (i) a constant ratio of urethane to urea bonds; (ii) a constant urethane content; or (iii) a constant urea content. Bulk properties were assessed by dynamic mechanical analysis.

Utilization of energy and nitrogen by yearling Holstein cattle fed direct-cut alfalfa or orchardgrass ensiled with formic acid plus formaldehyde.

First-growth orchardgrass and alfalfa were harvested at two stages of maturity, treated with formic acid plus formaldehyde, and ensiled as direct-cut silage during 1978 and 1979. The 1978 silages were fed to eight yearling Holstein heifers (average BW 273 kg), and the 1979 silages were fed to eight yearling Holstein steers (average BW 264 kg) in replicated 4 x 4 Latin square experiments to measure total energy and N balance using the Beltsville open-circuit respiration calorimeters. Silage was offered daily at 70 g of DM/kg.

Voluntary intake, growth rate, and tissue retention by Holstein steers fed formaldehyde- and formic acid-treated alfalfa and orchardgrass silages.

Alfalfa and orchardgrass herbages of similar digestibility were harvested at early and late maturity from primary growth and conserved as direct-cut silage using formic acid and formaldehyde simultaneously. Major compositional differences between the silages were lower NDF (principally hemicellulose) and a greater N content in alfalfa than in orchardgrass. An initial group of eight steers was slaughtered with a mean BW of 222 kg, and each of the four silages was fed to comparable groups of eight Holstein steers.

Composition of formaldehyde- and formic acid-treated alfalfa and orchardgrass silages harvested at two maturities and their effects on intake and growth by Holstein heifers.

Alfalfa and orchardgrass herbages were each harvested at two maturities (May 22 to 25 vs June 5 to 7) in primary growth and directly ensiled with 5 kg of a mixture of 30% formic acid and 25% formaldehyde per metric ton of fresh herbage in upright conventional silos. Alfalfa silage contained less NDF (71%) and more N (150%) and hot-water-insoluble N (117%) than orchardgrass silage did. Major differences between silages were that orchardgrass contained 20.

[Gamma globulin administration in pollinosis?].

Eight patients with pollinosis over many years were treated with gammaglobulin (Sandoglobin). All patients had in the past not any success with hyposensitization. The results (symptom-score and requirement of concomitant symptomatic medicaments) are encouraging.

Effects of diet nitrogen and forage nitrogen insolubility on performance of cows in early lactation.

Thirty-six Holsteins were allotted at parturition to six treatments to measure effects of diet nitrogen and increased insolubility of silage nitrogen on performance and ruminal, plasma, and milk constituents during the first 100 d of lactation. Diets contained 40% concentrate and 60% silage in dry matter. The six silage treatments were untreated corn silage (low nitrogen); untreated corn silage and untreated alfalfa silage (1:1); untreated corn silage and formaldehyde and formic acid-treated alfalfa silage (1:1); ammonia-treated corn silage (low nitrogen); treated corn silage and untreated alfalfa silage (1:1); or treated corn silage and treated alfalfa silage (1:1).

Effect of fiber from fruits and vegetables on metabolic responses of human subjects: fiber intakes, fecal excretions, and apparent digestibilities.

Intakes and excretions of fiber were determined for 12 men consuming controlled diets containing fruits and vegetables (high fiber diet) or fruit and vegetable juices (low fiber diet) for periods of 26 days. The fiber in the low fiber diet appeared to be mostly hemicellulose, with an apparent digestibility of 95%. Apparent digestibilities of hemicellulose, cellulose, and lignin in the high fiber diet were 88, 42, and 18%, respectively.

Feeding polyunsaturated vegetable oils to lactating cows.

Holstein cows fed concentrate:hay diets also were fed for 14 days supplements of soybean oil plus casein, soybean oil protected from ruminal hydrogenation by encapsulation in a casein-formaldehyde matrix, cottonseed oil plus casein, or cottonseed oil protected with casein formaldehyde. The supplements were fed at rates to give a linoleic acid (18:2) intake of 225 g/day. Yields of milk and milk protein were not affected by treatment.