Publications by authors named "Gladis J Labrada-Delgado"

The synthesis and characterization of a hydrochar/CeO composite along with its evaluation in methylene blue degradation under visible light are presented. The methodology consisted of a single-pass hydrothermal method, having as synthesis conditions 9 h of reaction time, 210 °C, autogenous pressure, and a biomass/CeO ratio of 100:1. The composite characterization revealed good dispersion of CeO in the carbonaceous matrix and significant synergy in the composite activation using visible irradiation.

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Cobalt, nickel, manganese and zinc vanadates were synthesized by a hydrometallurgical two-phase method. The extraction of vanadium (V) ions from alkaline solution using Aliquat 336 was followed by the production of metal vanadates through precipitation stripping. Precipitation stripping was carried out using solutions of the corresponding metal ions (Ni (II), Co (II), Mn (II) and Zn (II), 0.

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The present work studied individual and binary adsorption of fluorides and As(V) in water on pleco fish bone chars (BC), as well as the effect of BC mass variation on the adsorption capacity of fluoride and As(V) in water for human consumption. The results of individual adsorption indicated that the adsorption of fluoride and As(V) on BC depends on solution pH. The adsorption capacity of fluorides at an initial concentration of 30 mg L increases approximately 3 times, from 5.

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In this work, the extraction of vanadium (V) ions from an alkaline solution using a commercial quaternary ammonium salt and the production of metal vanadates through precipitation stripping were carried out. The crystallization of copper vanadates from the extracts was performed using a solution containing a copper(II) source in concentrated chloride media as a stripping agent. In an attempt to control growth, a stabilizing polymer (polyvinylpyrrolidone, PVP) was added to the stripping solution.

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This work characterizes two alternative materials to substitute the most expensive microbial fuel cells (MFCs) components: proton exchange membrane (PEM) and cathode. Crude glycerol biodegradation was studied in MFCs using a clay cup as a PEM and activated carbon and camphor carbon mixture (CAC) as a cathode. The cathode performance was compared with Platinum on carbon cloth.

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The search for adsorbent materials with a certain chemical inertness, mechanical resistance, and high adsorption capacity, as is the case with alumina, is carried out with structural or surface modifications with the addition of additives or metallic salts. This research shows the synthesis, characterization, phase evolution and Cd(II) adsorbent capacity of α-AlO/Ba-β-AlO spheres obtained from α-AlO nanopowders by the ion encapsulation method. The formation of the Ba-β-AlO phase is manifested at 1500 °C according to the infrared spectrum by the appearance of bands corresponding to AlO bonds and the appearance of peaks corresponding to Ba-O bonds in Raman spectroscopy.

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In this work, the synthesis of crosslinked chitosan hydrogels was performed by ionic and covalent interactions using tripolyphosphate (TPP) and formaldehyde (CHO), respectively. The hydrogels synthesis was performed using a D-Optimal combined experiment design with two mixing variables, A and B representing the TPP weight fraction (slack variable) and CHO weight fraction, respectively, and three (3) process variables C-chitosan concentration, D-cross-linker concentration, and E-Contact time. The response variables studied were the point of zero charge (pH), the swelling ratio (SW), and the equilibrium water content (EWC), which are relevant physicochemical properties in applications such as the pollutant removal from water.

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Ibuprofen degradation and energy generation in a single-chamber Microbial Fuel Cell (MFC) were evaluated using a bioanode fabricated from devil fish bone char (BCA) synthesized by calcination in air atmosphere. Its performance was compared with conventional carbon felt (CF). Bone char textural properties were determined by nitrogen adsorption.

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Air pollution exposure is a risk factor for arrhythmia. The atrioventricular (AV) conduction axis is key for the passage of electrical signals to ventricles. We investigated whether environmental nanoparticles (NPs) reach the AV axis and whether they are associated with ultrastructural cell damage.

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Article Synopsis
  • - Iron nanoparticles (Fe3O4 NPs), primarily found in heavily trafficked areas, may enter the brain via the olfactory nerve or bloodstream, potentially leading to neurodegenerative effects.
  • - The study aimed to analyze the toxicity and interaction of these particles with primary rat brain microvascular endothelial cells (rBMECs), which are crucial for in vitro blood-brain barrier models.
  • - Findings revealed that synthetic pollution-derived Fe3O4 NPs could be internalized by rBMECs and cross the cell layer, with lower concentrations causing mid-level cytotoxic effects on cell membrane integrity and metabolic activity.
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Chili seeds (CS) represent one of the most abundant residues in Mexico due to the high production and consumption. In this work, CS were used as raw material for the production of low-cost adsorbents for the removal of methylene blue from water. The adsorbents were synthesized from a hydrothermal treatment (based on a surface response experiment design) and characterized texturally by assessing changes in their properties.

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In this study, bone char (BC) from pleco fish (Pterygoplichthys spp.) was synthesized, and their textural and physicochemical properties, as well as its adsorption capacity towards fluoride and Cd(II) from single and binary aqueous solutions, were determined. The results showed that the properties of the BCs were independent of the type of bone used and the surface areas were close to 110 m g.

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