Various photocatalytic nanomaterials for environmental remediation have been promoted due to the pollution caused by different organic pollutants. In this study, NbO nanofibers were obtained by electrospinning technique, presenting controlled crystallinity and high specific surface area to improve the photoactivity response. The structural characterization indicated NbO nanofibers with orthorhombic phase formation.
View Article and Find Full Text PDFA fast, efficient, and non-chromatographic method was presented in this study for nitrite, nitrate, and p-nitrophenol (N-compounds) extraction and speciation analysis of environmental samples. By applying ultrasound-assisted solid-liquid extraction (USLE), analytes were efficiently extracted from water, soil, or sediment collected in areas of environmental disaster. These analytes were selectively converted to NO through UV photolysis (NO), HO/UV photocatalysis (PNP), and direct conversion (NO).
View Article and Find Full Text PDFNanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (NbO) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFeO) or magnesium ferrite (MgFeO)) for atrazine photodegradation. Thus, the decorated NbO was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm.
View Article and Find Full Text PDFOne of the consequences of global mining is the exposure of metals into the environment, caused by the rupture of tailings dams. Excess of metals, such as aluminum (Al) and manganese (Mn) can cause serious damage to fauna and flora. The presence of these metals, associated with the temperature increase that occurs nowadays can potentially increase biochemical and metabolic rates in plant tissues and may affect growth.
View Article and Find Full Text PDFThe environmental disasters that occurred due to the leakage of mining waste in Mariana-MG (2015) and Brumadinho-MG (2019), located in Brazil, attracted the attention of the scientific community. This designated efforts to investigate the environmental consequences of toxic waste in the affected ecosystem. Therefore, a simple, easily executed and accessible method was presented for arsenic speciation [As(III), As(V), and DMA].
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
September 2017
This work presents an alternative method for arsenic speciation using the nano-TiO hydride generation photocatalytic hydride generation (PCHG) system, which is easily separated from the medium. Nano-TiO was studied as photocatalyst to reduction of arsenic species by UV-induced with formic acid and atomic absorption detection of different forms of arsenic [As (III), As (V), dimethylarsinic acid (DMA)] in environmental samples (water, sediment and plant). The effect of the average pH, the organic acid concentration, the ultraviolet irradiation time and their amount were investigated.
View Article and Find Full Text PDFA tungsten carbide coating on the integrated platform of a transversely heated graphite atomizer was used as a modifier for the direct determination of Se in soil extracts by graphite furnace atomic absorption spectrometry. Diethylenetriaminepentaacetic acid (0.0050 mol L(-1)) plus ammonium hydrogencarbonate (1.
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