Janus nanoplates, -bowls, and -cups: controlling size and curvature terpolymer/homopolymer blending in 3D confinement.

The synthesis and properties of Janus nanoparticles with spherical, cylindrical, and disk-like shapes are nowadays rather well understood. Other topologies such as nanorings and bowl-shaped Janus nanoparticles are believed to show distinctly different solution behavior and interaction with interfaces, but limitations in their synthesis currently prevents a proper investigation of these properties. Especially the combination of shape- and surface-anisotropy of bowl-shaped Janus nanoparticles could result in enhanced selectivity in uptake of cargo and enhanced directional diffusion.

Fabrication of diverse multicompartment micelles by redispersion of triblock terpolymer bulk morphologies.

Redispersing block copolymer (BCP) bulk films in selective solvents is a simple and efficient method to prepare BCP micelles and polymersomes. While ABC triblock terpolymers are known to form multicompartment micelles (MCMs) with intricate nanoarchitecture, this is typically done by solvent exchange instead of redispersion of bulk films despite obvious advantages of greatly reduced solvent usage. Here, we provide guidelines on how to form MCMs with defined shapes and inner structure through direct redispersion of terpolymer bulk morphologies in selective plasticizing solvents.

Size-Controlled Formation of Polymer Janus Discs.

A straightforward method is presented for the preparation of nano- to micrometer-sized Janus discs with controlled shape, size, and aspect ratio. The method relies on cross-linkable ABC triblock terpolymers and involves first the preparation of prolate ellipsoidal microparticles by combining Shirasu porous glass (SPG) membrane emulsification with evaporation-induced confinement assembly (EICA). By varying the pore diameter of the SPG membrane, we produce Janus discs with controlled size distributions centered around hundreds of nanometers to several microns.

Supramolecular Modification of ABC Triblock Terpolymers in Confinement Assembly.

The self-assembly of AB diblock copolymers in three-dimensional (3D) soft confinement of nanoemulsions has recently become an attractive bottom up route to prepare colloids with controlled inner morphologies. In that regard, ABC triblock terpolymers show a more complex morphological behavior and could thus give access to extensive libraries of multicompartment microparticles. However, knowledge about their self-assembly in confinement is very limited thus far.