Volatile organic compounds (VOCs) are considered a major public health concern in industrial location areas. The presence of exposure to (VOCs) has raised concern regarding the health effects caused by chronic human exposure as this will increase cancer diseases in the village. An analytical method has been developed and modified to help us detect 38 VOCs in the blood of 38 volunteers who are related to a carpentry shop at the parts-per-trillion level.
View Article and Find Full Text PDFWater purification from toxic metals was the main objective of this work. A composite in film form was prepared from the biomaterials hydroxyapatite, chitosan and glycerol using the dissolution/recrystallization method. A nanoparticle-based film with a homogenous and smooth surface was produced.
View Article and Find Full Text PDFThe expanding amount of remaining drug substances in wastewater adversely affects both the climate and human well-being. In the current investigation, we developed new cellulose acetic acid derivation/zeolite fiber as an effective technique to eliminate erythromycin (ERY) from wastewater. The number of interchangeable sites in the adsorbent structures and the ratio of ERY to the three adsorbents were identified as the main reasons for the reduction in adsorption as the initial ERY concentrations increased.
View Article and Find Full Text PDFThe goal of this work was to develop polymer-based heterocycle for water purification from toxic pesticides such as difenoconazole. The polymer chosen for this purpose was cellulose nanocrystalline (CNC); two cellulose based heterocycles were prepared by crosslinking with 2,6-pyridine dicarbonyl dichloride (Cell-X), and derivatizing with 2-furan carbonyl chloride (Cell-D). The synthesized cellulose-based heterocycles were characterized by SEM, proton NMR, TGA and FT-IR spectroscopy.
View Article and Find Full Text PDFIn this study, cellulose-based derivatives with heterocyclic moieties were synthesized by reacting cellulose with furan-2-carbonyl chloride (Cell-F) and pyridine-2,6-dicarbonyl dichloride (Cell-P). The derivatives were evaluated as adsorbents for the pesticide tetraconazole from aqueous solution. The prepared adsorbents were characterized by SEM, TGA, IR, and H NMR instruments.
View Article and Find Full Text PDFIn recent years, concerns have been raised about the occurrence of active raw materials and pharmaceutical ingredients that may be present in water, including wastewater, in the pharmaceutical industry. Wastewater treatment methods are not enough to completely remove active pharmaceuticals and other waste; thus, this study aims to assess the use of a multiwall carbon nanotube after derivatization and magnetization as a new and renewable absorbent for removing ibuprofen from an aqueous medium. The adsorbents were prepared by first oxidizing a multiwall carbon nanotube and then deriving the oxidized product with hydroxyl amine (m-MWCNT-HA), hydrazine (m-MWCNT-HYD), and amino acid (m-MWCNT-CYS).
View Article and Find Full Text PDFIn this study, we used a synthesized cross-linked magnetic chitosan with graphene oxide beads to study the removal of perchlorate from wastewater. The prepared complex was characterized using transmission electron microscopy (TEM), Fourier Transformation Infrared spectroscopy (FT-IR), vibrating sample magnetometry (VSM) and Thermal gravimetric analysis (TGA). Several parameters were studied including the effect of pH, contact time and the co-existing anions.
View Article and Find Full Text PDFPesticides and herbicides have been used extensively in agricultural practices to control pests and increase crop yields. Paraquat (PQT, 1,1-dimethyl-4,4-dipyridinium chloride) is one of the herbicide that belois classified as bipyridines and is used over the world. The objective of this study is to use ketoenol-pyrazole receptor functionalized silica hybrid as adsorbent for removal PQT from aqueous solution.
View Article and Find Full Text PDF