Non-innocent ligand flavone and curcumin inspired ruthenium photosensitizers for solar energy conversion.

A series of ruthenium photosensitizers incorporating a β-diketonate non-innocent ligand were synthesized, characterized, and implemented in dye-sensitized solar cells. Electrochemical studies exhibited well behaved reversible oxidations and reductions for all β-diketonate complexes. The acac- and Ph2acac- based photosensitizers possess limited delocalization across the ligand π*-manifold, which is significant for exhibition of respectable power conversion efficiencies in a dye-sensitized solar cell (DSC) device.

Characterization of Triphenylamine and Ferrocenyl Donor-π-donor Vinyl BODIPY Derivatives as Photoacoustic Contrast Agents.

The photophysical and electrochemical properties for a series of BODIPY dyes with incremental 3- and 3,5-vinyl conjugation, as well as incremental electron-donating groups (anisole < triphenylamine < ferrocenyl), are presented. Insight into the influence of each vinyl-conjugated electron-donating group on both vis-NIR absorption and fluorescence emission properties is provided. These trends are further corroborated by density functional theory computational analysis.