Combining sequential extraction and 3D fluorescence to investigate the behavior of antibiotic and polycyclic aromatic hydrocarbons during solar drying of sewage sludge.

Solar drying and liming are commonly used for sludge treatment, but little is known about their efficiency on antibiotics and Polycyclic Aromatic Hydrocarbons (PAHs) removal. This study aimed to investigate the removal of antibiotics and PAHs during solar drying of Limed Sludge (LS) and Non-Limed Sludge (NLS). Thus, organic matter fractionation and 3D fluorescence were used to assess the accessibility and the complexity of organic matter.

Assessment of the genotoxicity of antibiotics and chromium in primary sludge and compost using Vicia faba micronucleus test.

The objective of this study was to investigate chemical, biological and eco-toxicological parameters of a compost produced through the co-composting of dewatered primary sludge (DPS) and date palm waste to evaluate in which extent it can exploited as a bio-fertilizer. DPS and date palm waste were co-composted in aerobic conditions for 210 days. Physico-chemical parameters were evaluated during composting (total organic carbon, total nitrogen, pH, available forms of phosphorus).

Fate of antibiotics present in a primary sludge of WWTP during their co-composting with palm wastes.

Antibiotics persistence in the primary sludge can contribute to the emergence of these molecules in the environment and limit the agricultural recycling of sludge without any preliminary treatment. Composting is a widely used process for recycling sludges and then can contribute to the antibiotics removal. However, little interest is actually given to the evaluation of the persistence of some antibiotics families after the sludge co-composting and more particularly to the final compost valorization.

A pressurized liquid extraction approach followed by standard addition method and UPLC-MS/MS for a fast multiclass determination of antibiotics in a complex matrix.

In this work a fast analytical method for the determination of macrolides, tetracyclines and fluoroquinolones in a compost originating from a mixture of sewage sludge, palm waste and grass was developed by ultra-high performance liquid chromatography coupled to mass spectrometry (U-HPLC/MS). Antibiotics were extracted from compost by using the accelerated solvent extraction (ASE). The chromatographic separation was carried out on a T3 Cortecs C18 column using a mobile phase gradient mixture of water acidified with 1% of formic acid and acetonitrile.

Human and veterinary antibiotics during composting of sludge or manure: Global perspectives on persistence, degradation, and resistance genes.

Wastewater treatment plant effluent, sludge and manure are the main sources of contamination by antibiotics in the whole environment compartments (soil, sediment, surface and underground water). One of the major consequences of the antibiotics discharge into the environment could be the prevalence of a bacterial resistance to antibiotic. In this review, four groups of antibiotics (Tetracyclines, Fluoroquinolones, Macrolides and Sulfonamides) were focused for the background on their wide spread occurrence in sludge and manure and for their effects on several target and non-target species.

Evaluation of the antibiotics effects on the physical and chemical parameters during the co-composting of sewage sludge with palm wastes in a bioreactor.

The objective of this study was to investigate thermal and physicochemical parameters of sewage sludge-palm waste mixtures contaminated by different families of antibiotics (tetracyclines, macrolides and fluoroquinolones) during co-composting. Sludge was spiked with chlortetracycline (CTC), oxytetracycline (OTC), roxithromycin (RXY), enrofloxacin (ENR) and ciprofloxacin (CIP). Antibiotics were spiked at a low level, medium level, high level and a control without antibiotics was conducted.

Toxicity effects of an environmental realistic herbicide mixture on the seagrass Zostera noltei.

Worldwide seagrass declines have been observed due to multiple stressors. One of them is the mixture of pesticides used in intensive agriculture and boat antifouling paints in coastal areas. Effects of mixture toxicity are complex and poorly understood.

Evaluation of an aerobic treatment for olive mill wastewater detoxification.

Olive mill wastewater (OMWW) is a by-product of the olive oil extraction industry. Its dumping creates severe environmental problems in the Mediterranean countries. The phytoxicity of OMWW is due to the phenolic substances and is evaluated through a genotoxicity method.

New insight into pesticide partition coefficient Kd for modelling pesticide fluvial transport: application to an agricultural catchment in south-western France.

Pesticides applied on crops are leached with rainfall to groundwater and surface water. They threat the aquatic environment and may render water unfit for human consumption. Pesticide partitioning is one of the pesticide fate processes in the environment that should be properly formalised in pesticide fate models.

Occurrence of metolachlor and trifluralin losses in the Save river agricultural catchment during floods.

Rising pesticide levels in streams draining intensively managed agricultural land have a detrimental effect on aquatic ecosystems and render water unfit for human consumption. The Soil and Water Assessment Tool (SWAT) was applied to simulate daily pesticide transfer at the outlet from an agriculturally intensive catchment of 1110 km(2) (Save river, south-western France). SWAT reliably simulated both dissolved and sorbed metolachlor and trifluralin loads and concentrations at the catchment outlet from 1998 to 2009.

Can we predict community-wide effects of herbicides from toxicity tests on macrophyte species?

Macrophyte communities play an essential role in the way freshwater ecosystems function. It is thus of great concern to understand how environmental factors, especially anthropogenic ones, influence their composition and diversity. The aim of this study was to examine whether the effects of a herbicide mixture (50% atrazine, 35% isoproturon, 15% alachlor) on single macrophyte species can be used to predict its impact at a community level.

Influence of in situ biological activity on the vertical profile of pre-emergence herbicides in sediment.

The in situ effect of biological activity on herbicide degradation was studied in sediment. Early diagenesis indicators of organic matter (OM) was selected to provide information on the presence and the kinetics of the various biotic and abiotic processes involved in the degradation of fresh organic matter, the vector of herbicides in sediment. Two tandem-coring samples were taken in the Malause reservoir, one in the hyperoxic zone (Tarn confluence, MT core) and the other in the central part, under the exclusive influence of the Garonne River (MG core), after having crossed a zone where the high intensity of abiotic processes is proven.

Herbicide accumulation and evolution in reservoir sediments.

The aim of the present study was to understand the effect of reservoir configurations on sediment pesticide fate. Two dams were selected on the River Garonne, in southwest France: Carbonne and Golfech, both with reservoirs subject to accumulation of herbicide-contaminated sediment. They are situated upstream and downstream respectively of an agricultural and urban area: the Mid-Garonne.

Multi-residues analysis of pre-emergence herbicides in fluvial sediments: application to the mid-Garonne River.

Contamination of man and ecosystems by pesticides has become a major environmental concern. Whereas many studies exist on contamination from agriculture, the effects of urban sources are usually omitted. Fluvial sediment is a complex matrix of pollutants but little is known of its recent herbicide content.

Sequential extraction of heavy metals during composting of sewage sludge.

The major limitation of soil application of sewage sludge compost is the total heavy metal contents and their bioavailability to the soil-plant system. This study was conducted to determine the heavy metal speciation and the influence of changing the physico-chemical properties of the medium in the course of composting on the concentrations, bioavailability or chemical forms of Cu, Zn, Pb and Ni in sewage sludge. Principal physical and chemical properties and FTIR spectroscopical characterization of sludge compost during treatment show the stability and maturity of end product.