Food Additives and Evolved Methods of Detection: A Review.

Food additives are essential constituents of food products in the modern world. The necessity of food processing went up rapidly as to meet requirements including, imparting desirable properties like preservation, enhancement and regulation of color and taste. The methods of identification and analysis of such substances are crucial.

Recent advances in electrochemical and optical sensing of the organophosphate chlorpyrifos: a review.

Chlorpyrifos (CP) is one of the most popular organophosphorus pesticides that is commonly used in agricultural and nonagricultural environments to combat pests. However, several concerns regarding contamination due to the unmitigated use of chlorpyrifos have come up over recent years. This has popularized research on various techniques for chlorpyrifos detection.

Fluorescein Based Fluorescence Sensors for the Selective Sensing of Various Analytes.

Fluorescein molecules are extensively used to develop fluorescent probes for various analytes due to their excellent photophysical properties and the spirocyclic structure. The main structural modification of fluorescein occurs at the carboxyl group where different groups can be easily introduced to produce the spirolactam structure which is non-fluorescent. The spirolactam ring opening accounts for the fluorescence and the dual sensing of analytes using fluorescent sensors is still a topic of high interest.

Unique Host Matrix to Disperse Pd Nanoparticles for Electrochemical Sensing of Morin: Sustainable Engineering Approach.

Biomass-based carbon nanospheres derived from (commonly called "Touch-me-not") smeared on carbon fiber paper have been used as a host matrix for electrochemical deposition of palladium nanoparticles. The physicochemical characterization of modified electrodes was performed by field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy techniques. Cyclic voltammetry and electrochemical impedance spectroscopy were used to study the electroanalytical properties of the electrodes.

Electrochemical sensing of vitamin B deficiency marker methylmalonic acid using PdAu-PPy tailored carbon fiber paper electrode.

Vitamin B is very important for human metabolism and its deficiency can cause anemia and the production of large red blood cells. An increased concentration of methylmalonic acid (MMA) is detected much before the transformation of blood cells, which thereby is an early indicator for mild or serious Vitamin B deficiency. A simple electrochemical sensor based on Palladium-Gold (PdAu) was developed by electrodeposition of PdAu nanoparticles on Polypyrrole (PPy) modified carbon fiber paper (CFP) electrode.

Electrocatalytic oxidation of morin on electrodeposited Ir-PEDOT nanograins.

Nanoclusters of Ir were electrochemically deposited on carbon fiber paper (CFP) substrate modified with poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer between the potential range 0.0 V and 0.6 V at 0.

Flavonol based surface modification of doped chalcogenide nanoflakes as an ultrasensitive fluorescence probe for Al ion.

A highly selective novel fluorescent probe was prepared by using surface modified ZnS:Mn nanoparticles, functionalized with morin, a flavonol. SEM investigations of the heterostructures prepared using wet chemical precipitation technique revealed a nanoflake type of morphology. HR-TEM and powder XRD analysis confirmed the crystalline planes corresponding to Wurtzite ZnS.

Study on Photophysical Properties of N-Arylphthalamic Acid Derivative Containing 1, 2, 4-Triazole Scaffold.

A novel N-arylphthalamic acid derivative, 2-({4-[(1H-1,2,4-triazol-1-yl)methyl]phenyl}carbamoyl)benzoic acid (TMPCB) was synthesized and their absorption and emission spectra were recorded in fifteen different solvents of varying polarities at room temperature. Ground state dipole moment of the derivative was calculated experimentally by Guggenheim method and solvatochromic approach proposed by Bilot-Kawski. The singlet excited state dipole moment of TMPCB were calculated experimentally based on different approaches of solvent polarity function proposed by Lippert-Mataga, Bakhshiev, Kawskii-Chamma-Viallet, Reichardt and Bilot-Kawski.

Estimation of Ground-State and Singlet Excited-State Dipole Moments of Substituted Schiff Bases Containing Oxazolidin-2-one Moiety through Solvatochromic Methods.

Absorption and fluorescence studies on novel Schiff bases (E)-4-(4-(4-nitro benzylideneamino)benzyl)oxazolidin-2-one (NBOA) and (E)-4-(4-(4-chlorobenzylidene amino)benzyl)oxazolidin-2-one (CBOA) were recorded in a series of twelve solvents upon increasing polarity at room temperature. Large Stokes shift indicates bathochromic fluorescence band for both the molecules. The photoluminescence properties of Schiff bases containing electron withdrawing and donating substituents were analyzed.

Simultaneous first order derivative spectrophotometric determination of vanadium and zirconium in alloy steels and minerals.

A simple, selective and sensitive spectrophotometric method has been developed for the individual and simultaneous determination of trace amounts of vanadium(V) and zirconium(IV) in acetic acid medium using a newly synthesised reagent diacetylmonoxime salicyloylhydrazone (DMSH), without any prior separation. The molar absorptivity and Sandell's sensitivity of the coloured species are 1.30 x 10(4) and 1.