In Situ Polymerization on a 3D Ceramic Framework of Composite Solid Electrolytes for Room-Temperature Solid-State Batteries.

Solid-state batteries (SSBs) are ideal candidates for next-generation high-energy-density batteries in the Battery of Things era. Unfortunately, SSB application is limited by their poor ionic conductivity and electrode-electrolyte interfacial compatibility. Herein, in situ composite solid electrolytes (CSEs) are fabricated by infusing vinyl ethylene carbonate monomer into a 3D ceramic framework to address these challenges.